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Establishment of combinatorial high temperature durability evaluation method and elucidation of dissolved hydrogen embrittlement mechanism for hydrogen separation membranes

Research Project

Project/Area Number 24560865
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionOita National College of Technology

Principal Investigator

MATSUMOTO Yoshihisa  大分工業高等専門学校, 機械工学科, 教授 (40219522)

Co-Investigator(Kenkyū-buntansha) YUKAWA Hiroshi  名古屋大学, 大学院工学研究科, 助教 (50293676)
NAMBU Tomonori  鈴鹿工業高等専門学校, 材料工学科, 准教授 (10270274)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords水素透過膜 / バナジウム合金 / ニオブ合金 / タンタル合金 / 小型パンチ試験 / 小型パンチクリープ試験 / 耐水素脆性 / 固溶水素濃度 / 合金設計 / 水素透過能 / 水素 / 新エネルギー / 燃料電池 / 金属物性 / 構造・機能材料 / 水素透過 / 水素脆化
Outline of Final Research Achievements

The combinatorial high temperature durability evaluation method which fused the in-situ small punch (SP) test in hydrogen environment and SP creep (SPC) test was established in this study. Also, it focused on the elucidation of the ductile-to-brittleness transition hydrogen concentration (DBTC) analyses and the appearance mechanisms for hydrogen permeable membrane alloys.
As a result, it was shown that the resistance on fracture may have been reduced by dissolved hydrogen being trapped by defects, such as a structure discontinuous region or dislocation in a matrix. The V-M system alloy membrane originated with new design / evaluation guideline showed that it could operate as hydrogen separation equipment under the conditions which do not show any embrittlement.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (48 results)

All 2015 2014 2013 2012 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 3 results) Presentation (25 results) (of which Invited: 2 results) Book (5 results) Remarks (3 results) Patent(Industrial Property Rights) (6 results)

  • [Journal Article] Alloying effects on hydrogen permeability of V without catalytic Pd overlayer2015

    • Author(s)
      Y.Nakamura, H.Yukawa, A.Suzuki, T.Nambu, Y.Matsumoto and Y.Murata
    • Journal Title

      J. Alloys and Compounds

      Volume: in press Pages: S275-S279

    • DOI

      10.1016/j.jallcom.2014.12.242

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Analysis of hydrogen mobility in Nb-based alloy membranes in view of new description of hydrogen permeability based on hydrogen chemical potential2015

    • Author(s)
      A.Suzuki, H.Yukawa, T.Nambu, Y.Matsumoto and Y.Murata
    • Journal Title

      J. Alloys and Compounds

      Volume: in press Pages: S107-S111

    • DOI

      10.1016/j.jallcom.2014.12.265

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Consistent description of hydrogen permeability through metal membrane based on hydrogen chemical potential2014

    • Author(s)
      A.Suzuki, H.Yukawa, T.Nambu, Y.Matsumoto and Y.Murata
    • Journal Title

      Int’l J. Hydrogen Energy

      Volume: 39 Issue: 15 Pages: 7919-7924

    • DOI

      10.1016/j.ijhydene.2014.03.123

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Determination of Ductile-to-Brittle Transition Hydrogen Concentrations (DBTC) for Group 5 Hydrogen Permeable Membranes Using <i>In-Situ</i> Small Punch Test2013

    • Author(s)
      松本佳久, 湯川宏, 南部智憲
    • Journal Title

      Journal of the Japan Institute of Metals and Materials

      Volume: 77 Issue: 12 Pages: 585-592

    • DOI

      10.2320/jinstmet.JC201313

    • NAID

      130004456372

    • ISSN
      0021-4876, 1880-6880, 2433-7501
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Design of Nb-W-Mo Alloy Membrane for Hydrogen Separation and Purification2013

    • Author(s)
      K.Tsuchimoto, H.Yukawa, T.Nambu, Y.Matsumoto, Y.Murata
    • Journal Title

      J. Alloys and Compounds

      Volume: 580 Pages: S391-S396

    • DOI

      10.1016/j.jallcom.2013.03.143

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hydrogen Solubility and Permeability of V–W–Mo Alloy Membrane for Hydrogen Separation and Purification2013

    • Author(s)
      H.Yukawa, C.Tsukada, T.Nambu, Y.Matsumoto
    • Journal Title

      J. Alloys and Compounds

      Volume: 580 Pages: S386-S390

    • DOI

      10.1016/j.jallcom.2013.03.144

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Design and development of Nb-W-Mo alloy membrane for hydrogen separation and purification2013

    • Author(s)
      H.Yukawa, T.Nambu, Y.Matsumoto
    • Journal Title

      Defect and Diffusion Forum

      Volume: 333 Pages: 61-71

    • DOI

      10.4028/www.scientific.net/ddf.333.61

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Alloying Effects of Tungsten and Molybdenum on the Compressive Deformation Properties of Niobium2012

    • Author(s)
      土本憲太郎, 湯川宏, 南部智憲, 松本佳久, 湯川伸樹, 石黒太浩, 村田純教
    • Journal Title

      Journal of the Japan Institute of Metals and Materials

      Volume: 76 Issue: 10 Pages: 587-590

    • DOI

      10.2320/jinstmet.76.587

    • NAID

      130004456264

    • ISSN
      0021-4876, 1880-6880, 2433-7501
    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Alloying Effects of Group 5 and 6 Metals on the Durability for Palladium Based Hydrogen Permeable Membrane2012

    • Author(s)
      木村彩香, 有馬義貴, 南部智憲, 湯川宏, 松本佳久
    • Journal Title

      Journal of the Japan Institute of Metals and Materials

      Volume: 76 Issue: 10 Pages: 607-613

    • DOI

      10.2320/jinstmet.76.607

    • NAID

      130004456267

    • ISSN
      0021-4876, 1880-6880, 2433-7501
    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] バナジウム合金膜を用いた水素分離装置の運転条件設定方法2014

    • Author(s)
      松本佳久
    • Organizer
      高専-技科大新技術説明会(エネルギー)
    • Place of Presentation
      科学技術振興機構東京本部別館(東京都千代田区)
    • Year and Date
      2014-12-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pd-Ag系水素透過合金膜の膜劣化防止に及ぼすWコーティングの効果2014

    • Author(s)
      南部智憲,平岡孝由貴,湯川宏,松本佳久
    • Organizer
      日本金属学会2014年秋期(第155回)大会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県名古屋市)
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Boundary Determination for Ductile-to-Brittle Transition of Group 5 Metals in Hydrogen Environment2014

    • Author(s)
      Yoshihisa Matsumoto, Hiroshi Yukawa and Tomonori Nambu
    • Organizer
      3rd International Conference SSTT 2014, Determination of Mechanical Properties of Materials by Small Punch and Other Miniature Testing Techniques
    • Place of Presentation
      Seggauberg (Austria)
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Alloying effects on hydrogen permeability of V without Pd overlayer2014

    • Author(s)
      Yuki Nakamura, Hiroshi Yukawa, Asuka Suzuki, Tomonori Nambu, Yoshihisa Matsumoto and Yoshinori Murata
    • Organizer
      14th International Symposium on Metal-Hydrogen Systems (MH 2014)
    • Place of Presentation
      Manchester (UK)
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Analysis of hydrogen mobility in Nb-based alloy membrane in view of new description of hydrogen permeability based on hydrogen chemical potential2014

    • Author(s)
      Asuka Suzuki, Hiroshi Yukawa, Tomonori Nambu, Yoshihisa Matsumoto and Yoshinori Murata
    • Organizer
      14th International Symposium on Metal-Hydrogen Systems (MH 2014)
    • Place of Presentation
      Manchester (UK)
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] High hydrogen flux through bare vanadium membrane without Pd overlayer2014

    • Author(s)
      Hiroshi Yukawa, Tomonori Nambu and Yoshihisa Matsumoto
    • Organizer
      14th International Symposium on Metal-Hydrogen Systems (MH 2014)
    • Place of Presentation
      Manchester (UK)
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] High hydrogen permeability through bare V membranes without Pd overlayer2014

    • Author(s)
      Hiroshi Yukawa, Tomonori Nambu and Yoshihisa Matsumoto
    • Organizer
      11th Asia-Pacific Conference on Materials Processing (APCMP 2014)
    • Place of Presentation
      Auckland (New Zealand)
    • Year and Date
      2014-07-06 – 2014-07-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 中温域におけるV水素透過膜の延性-脆性遷移水素濃度解析2014

    • Author(s)
      松本佳久,佐保慶太朗,御堂俊哉,湯川宏,南部智憲
    • Organizer
      日本金属学会・日本鉄鋼協会・軽金属学会九州支部共催平成26年度合同学術講演大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2014-06-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Hydrogen Pearmeability of Pure V and its Alloy Membranes without Pd Overlayer (A6)2013

    • Author(s)
      H. Yukawa, Y. Nakamura, T. Nambu, Y. Matsumoto
    • Organizer
      8th Pacific Rim International Conference on Advanced Materials and Processing (PRICM-8)
    • Place of Presentation
      Hilton Waikoloa Villege, Waikoloa, Hawaii, U.S.A.
    • Related Report
      2013 Research-status Report
  • [Presentation] 水素の化学ポテンシャルに基づくニオブ系合金膜の水素移動度の定量評価2013

    • Author(s)
      湯川宏,南部智憲,松本佳久
    • Organizer
      日本金属学会2013年春期(第152回)大会講演概要(34)
    • Place of Presentation
      東京理科大学神楽坂キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] タンタル水素透過膜の延性-脆性遷移水素濃度(DBTC)解析2013

    • Author(s)
      松本佳久,湯川宏,南部智憲
    • Organizer
      日本金属学会2013年春期(第152回)大会講演概要(38)
    • Place of Presentation
      東京理科大学神楽坂キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Analysis of hydrogen diffusivity during hydrogen permeation through Nb-W-Mo alloy membrane2012

    • Author(s)
      H. Yukawa, T. Nambu, Y. Matsumoto
    • Organizer
      Proc. of 8th International Conference on Diffusion in Solids and Liquids - DSL-2012
    • Place of Presentation
      Kalyon Hotel, Istanbul, Turkey
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Pdコーティングフリー V-W合金膜の水素透過能2012

    • Author(s)
      湯川宏,南部智憲,松本佳久
    • Organizer
      日本金属学会2012年秋期(第151回)大会講演概要(33)
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] バナジウム膜の水素透過能に及ぼす表面酸化被膜の影響2012

    • Author(s)
      南部智憲,湯川宏,松本佳久
    • Organizer
      日本金属学会2012年秋期(第151回)大会講演概要(34)
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Effect of Surface State on Hydrogen Permeation Flux of Pure Niobium Membrane2012

    • Author(s)
      Y. Matsumoto, H. Yukawa and T. Nambu
    • Organizer
      Materials Science and Engineering 2012 (MSE2012)
    • Place of Presentation
      TU Darmstadt, Darmstadt, Germany
    • Related Report
      2012 Research-status Report
  • [Presentation] Determination of Ductile to Brittle Transition Hydrogen Concentrations for V and Nb Alloys Using in-situ Small Punch Test2012

    • Author(s)
      Yoshihisa Matsumoto, Hiroshi Yukawa and Tomonori Nambu
    • Organizer
      Proc. of 2nd International Conference SSTT, Determination of Mechanical Properties of Materials by Small Punch and Other Miniature Testing Techniques, (SSTT2012)
    • Place of Presentation
      Park Inn Ostrava, Ostrava, Czech Republic
    • Related Report
      2012 Research-status Report
  • [Presentation] Hydrogen Solubility and Permeability of V-W-Mo Alloy Membrane for Hydrogen Separation and Purification (WeP-62, A3)2012

    • Author(s)
      H. Yukawa, C. Tsukada, T. Nambu, Y. Matsumoto
    • Organizer
      Proc. of International Symposium on Metal-Hydrogen Systems, - Fundamentals and Applications -
    • Place of Presentation
      Kyoto TERRSA, Kyoto, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Design of Nb-W-Mo Alloy Membrane for Hydrogen Separation and Purification (WeP-65, A3)2012

    • Author(s)
      K. Tsuchimoto, H. Yukawa, T. Nambu, Y. Matsumoto, Y. Murata
    • Organizer
      Proc. of International Symposium on Metal-Hydrogen Systems, - Fundamentals and Applications -
    • Place of Presentation
      Kyoto TERRSA, Kyoto, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] 水素エネルギー社会の実現を目指して -新しい水素分離・精製技術の開発-2012

    • Author(s)
      松本佳久
    • Organizer
      大分高専テクノフォーラム第17回技術講演会
    • Place of Presentation
      大分工業高等専門学校
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] バナジウム膜の耐久性に及ぼす表面処理プロセスの影響

    • Author(s)
      南部智憲,湯川宏,松本佳久
    • Organizer
      日本金属学会2014年春期(第154回)大会講演概要(398)
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 高機能水素透過合金の設計開発と水素製造技術への展開

    • Author(s)
      南部智憲,湯川宏,松本佳久
    • Organizer
      日本金属学会2013年秋期(第153回)大会講演概要(S5・24)
    • Place of Presentation
      金沢大学角間キャンパス(石川県金沢市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Ta水素透過膜の延性-脆性遷移水素濃度解析と合金設計への展開

    • Author(s)
      松本佳久,湯川宏,南部智憲
    • Organizer
      日本金属学会・日本鉄鋼協会・軽金属学会九州支部共催平成25年度合同学術講演大会講演概要集(A13)
    • Place of Presentation
      くまもと県民交流館パレア(熊本県熊本市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Nb水素透過膜の高温強度に及ぼす添加元素の効果

    • Author(s)
      佐保慶太朗,湯川宏,南部智憲,松本佳久
    • Organizer
      日本金属学会・日本鉄鋼協会・軽金属学会九州支部共催平成25年度合同学術講演大会講演概要集(A14)
    • Place of Presentation
      くまもと県民交流館パレア(熊本県熊本市)
    • Related Report
      2013 Research-status Report
  • [Presentation] SP試験法によるNb合金膜の水素雰囲気in-situ高温強度特性評価

    • Author(s)
      御堂俊哉,湯川宏,南部智憲,松本佳久
    • Organizer
      日本金属学会・日本鉄鋼協会・軽金属学会九州支部共催平成24年度合同学術講演大会講演概要集(P46)
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2012 Research-status Report
  • [Presentation] 水素透過膜のin-situ耐久性評価方法の確立と水素透過能低下要因の解析

    • Author(s)
      飛田聡兵,湯川宏,南部智憲,松本佳久
    • Organizer
      日本金属学会・日本鉄鋼協会・軽金属学会九州支部共催平成24年度合同学術講演大会講演概要集(P47)
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2012 Research-status Report
  • [Book] Advances in Hydrogen Production, Storage and Distribution, 1st Edition2014

    • Author(s)
      Y. Matsumoto, H. Yukawa and T. Nambu
    • Total Pages
      574
    • Publisher
      Woodhead Publishing, UK
    • Related Report
      2014 Annual Research Report
  • [Book] Advances in Hydrogen Production, Storage and Distribution, 1st Edition2014

    • Author(s)
      H. Yukawa, T. Nambu and Y. Matsumoto
    • Total Pages
      574
    • Publisher
      Woodhead Publishing, UK
    • Related Report
      2014 Annual Research Report
  • [Book] Niobium-based Alloys as Hydrogen Permeable Membrane for Hydrogen Separation and Purification2013

    • Author(s)
      H. Yukawa, T. Nambu and Y. Matsumoto
    • Total Pages
      152
    • Publisher
      Nova Science Publishers
    • Related Report
      2013 Research-status Report 2012 Research-status Report
  • [Book] Advances in hydrogen production, storage and utilization: Ch18. Quantitative evaluation of hydrogen embrittlement for group 5 metals2013

    • Author(s)
      Y. Matsumoto, H. Yukawa and T. Nambu
    • Publisher
      Woodhead Publishing
    • Related Report
      2012 Research-status Report
  • [Book] Advances in hydrogen production, storage and utilization: Ch19. Hydrogen permeable metal membrane for hydrogen separation and purification2013

    • Author(s)
      H. Yukawa, T. Nambu and Y. Matsumoto
    • Publisher
      Woodhead Publishing
    • Related Report
      2012 Research-status Report
  • [Remarks] 大分高専松本研究室 研究業績 ホームページ

    • URL

      http://www.oita-ct.ac.jp/kikai/matumoto/sub7.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 大分高専 松本研究室 研究業績

    • URL

      http://www.oita-ct.ac.jp/kikai/matumoto/sub7.html

    • Related Report
      2013 Research-status Report
  • [Remarks] 大分高専 松本研究室 研究業績

    • URL

      http://www.oita-ct.ac.jp/kikai/matumoto/sub7.html

    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] 水素分離装置および水素分離方法2014

    • Inventor(s)
      松本佳久,湯川宏,南部智憲,鈴木飛鳥,黒川英人,白木正浩
    • Industrial Property Rights Holder
      国立高等専門学校機構,名古屋大学,東京瓦斯(株)
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-191939
    • Filing Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 水素分離装置及びその運転条件設定方法2014

    • Inventor(s)
      松本佳久,湯川宏,南部智憲,白木正浩,黒川英人
    • Industrial Property Rights Holder
      国立高等専門学校機構,名古屋大学,東京瓦斯(株)
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-061961
    • Filing Date
      2014-03-25
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 水素分離膜の処理方法,水素分離方法及び水素分離膜2014

    • Inventor(s)
      松本佳久,湯川宏,南部智憲,白木正浩,黒川英人
    • Industrial Property Rights Holder
      国立高等専門学校機構,名古屋大学,東京瓦斯(株)
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-056759
    • Filing Date
      2014-03-19
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 水素分離膜及び水素分離方法2013

    • Inventor(s)
      松本佳久,南部智憲,湯川宏,黒川英人,金子祐大,白木正浩
    • Industrial Property Rights Holder
      国立高等専門学校機構,名古屋大学,東京瓦斯(株)
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-046770
    • Filing Date
      2013-03-08
    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] 水素分離方法2013

    • Inventor(s)
      松本佳久,南部智憲,湯川宏,鈴木飛鳥,黒川英人,白木正浩
    • Industrial Property Rights Holder
      国立高等専門学校機構,名古屋大学,東京瓦斯(株)
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-049020
    • Filing Date
      2013-03-12
    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] Nb-W系合金膜からなる水素分離膜及び水素分離法2012

    • Inventor(s)
      松本佳久,南部智憲,湯川宏,森永正彦,他4名
    • Industrial Property Rights Holder
      名古屋大学,東京瓦斯(株)
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-167840
    • Filing Date
      2012-07-06
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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