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Analyses of proton behavior in solid oxide fuel cells using neutron diffraction

Research Project

Project/Area Number 24560866
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

IGAWA Naoki  独立行政法人日本原子力研究開発機構, 原子力科学研究部門 量子ビーム応用研究センター, 研究主幹 (60354833)

Co-Investigator(Kenkyū-buntansha) KODAMA Katsuaki  独立行政法人日本原子力研究開発機構, 原子力科学研究部門 量子ビーム応用研究センター, 研究主幹 (10313115)
TAGUCHI Tomitsugu  独立行政法人日本原子力研究開発機構, 原子力科学研究部門 量子ビーム応用研究センター, 研究主幹 (50354832)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords燃料電池 / 中性子散乱 / 水素 / プロトン伝導体 / リートベルト解析 / MEM解析
Outline of Final Research Achievements

For the improvement of functional performance of solid oxide fuel cells, we analyzed the proton behavior and atomic-disorder in the crystal structure by the combination of neutron diffraction, Rietveld/ maximum entropy method and the atomic pair distribution function (PDF) method.
We determined 3-dimensional nuclear density distribution of La-Ce oxide compound. We found the oxygen atom-disorder in the material using neutron PDF method. The low hydrogen density distribution was found and the diffuse pathway of hydrogen was determined in Ba-Sn-In oxide compound. We also found the local structural disorder caused by hydrogen.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (12 results)

All 2014 2013 2012

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 2 results) Presentation (6 results)

  • [Journal Article] Weak Ferromagnetic Ordering Disordered by Rh3+ Ions for LaCo0.8Rh0.2O32014

    • Author(s)
      Shinichiro Asai, Ryuji Okazaki, Ichiro Terasaki, Yukio Yasui, Naoki Igawa, and Kazuhisa Kakurai
    • Journal Title

      JPS Conference Proceedings

      Volume: 3 Pages: 014034-014034

    • DOI

      10.7566/jpscp.3.014034

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Local Structural Analysis by using Atomic Pair Distribution Function on Mixed Valence Compound2014

    • Author(s)
      K. Kodama, N. Igawa, S. Shamoto, K. Ikeda, H. Oshita, N. Kaneko, T. Otomo, K. Suzuya,
    • Journal Title

      JPS Conference Proceedings

      Volume: 3 Pages: 013012-013012

    • DOI

      10.7566/jpscp.3.013012

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Protonic Conduction, Crystal and Electronic Structures of La1-xBa1+xGa1-yMgyO4-δ2013

    • Author(s)
      N. Hamao, N. Kitamura, T. Itoh, N. Igawa, Y. Idemoto
    • Journal Title

      Solid State Ionics

      Volume: 253 Pages: 123-129

    • DOI

      10.1016/j.ssi.2013.09.021

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Local Lattice Distortion Caused by Short Range Charge Orderng in LiMn2O42013

    • Author(s)
      K. Kodama, N. Igawa, S. Shamoto, K. Ikeda, H. Ohshita, N. Kaneko, T. Otomo, and K. Suzuya
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 82 Issue: 9 Pages: 094601-094601

    • DOI

      10.7566/jpsj.82.094601

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 155Gd Mossbauer Spectroscopic and Powder X-ray Diffraction Study of CeO2-GdO1.5 Solid Solution2012

    • Author(s)
      A. Nakamura, K. Imai, N. Igawa, Y. Okamoto, E. Yamamoto, S. Matsukawa, M. Takahashi
    • Journal Title

      Hyperfine Interactions

      Volume: 207 Issue: 1-3 Pages: 67-71

    • DOI

      10.1007/s10751-011-0419-0

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Characteristics of Layered Li_<1.95> Mn_<0.9> Co_<0.15> O_3(C2/m) as a Lithium-Battery Cathode2012

    • Author(s)
      K. Ozawa, Y. Nakao. T. Mochiku, Z. Cheng, L. Wang, H. Iwai, Y. Tsuchiya, H. Fujii, N. Igawa
    • Journal Title

      Journal of the Electrochemimcal Society

      Volume: 159 Issue: 3 Pages: A300-A304

    • DOI

      10.1149/2.079203jes

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Crystal Structure and Electron Density Distribution Analyses of NdxCe1-xO2-δ for Electrolyte by Rietveld/ Maximum Entropy Method2014

    • Author(s)
      T. Taguchi, N. Igawa, S. Miwa, A. Birumachi, H. Asaoka, M. Osaka
    • Organizer
      7th International Symposium on Surface Science
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Nuclear and Electron Density Distributions of LiMn2O4 Analyzed by Combination of Rietveld/ Maximum Entropy Method2014

    • Author(s)
      N. Igawa, K. Kodama, A. Birumachi, T. Taguchi
    • Organizer
      7th International Symposium on Surface Science
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Local Lattice Distortion Caused by Short-range Charge Ordering in Transition Metal Oxides2014

    • Author(s)
      K. Kodama, N. Igawa, S. Shamoto, K. Ikeda, H. Ohshita, N. Kaneko, T. Otomo, K. Suzuya, A. Hoshikawa, T. Ishigaki
    • Organizer
      2nd International Symposium on Science at J-PARC
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2014-07-12 – 2014-07-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] プロトン伝導性酸化物BaSn0.5In0.5O2.75の結晶構造の静的な乱れ(2)2014

    • Author(s)
      長崎 正雅, 山田 智明, 吉野 正人, 井川 直樹
    • Organizer
      第52回セラミックス基礎科学討論会
    • Place of Presentation
      ウインクあいち(愛知県)
    • Related Report
      2013 Research-status Report
  • [Presentation] スピネル化合物LiMn2O4における電荷の短距離秩序による局所構造歪み2014

    • Author(s)
      樹神 克明, 井川 直樹, 社本 真一, 池田 一貴, 大下 英敏, 金子 直勝, 大友 季哉, 鈴谷 賢太郎, 星川 晃範, 石垣 徹
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパス(神奈川県)
    • Related Report
      2013 Research-status Report
  • [Presentation] プロトン伝導性酸化物BaSn0.5In0.5O2.75 の結晶構造の静的な乱れ2012

    • Author(s)
      早川 和孝, 長崎 正雅, 山田 智明, 吉野正人, 井川 直樹, 星川 晃範, 石垣 徹
    • Organizer
      日本セラミックス協会 第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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