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Fabrication and application of self-organized nano structured films by bi-layer agglomeration phenomena

Research Project

Project/Area Number 24560874
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Material processing/treatments
Research InstitutionThe University of Tokyo

Principal Investigator

KAMIKO MASAO  東京大学, 生産技術研究所, 助教 (80334366)

Research Collaborator HA Jae-Geun  
KYUNO Kentaro  
SUENAGA Ryo  
KOO Jung-Woo  
NOSE Kenji  
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsナノ材料 / 自己組織化 / 微細加工 / 脱濡れ / 熱凝集 / 結晶成長 / マイクロ・ナノデバイス / ナノデバイス / 局在表面プラズモン共鳴
Outline of Final Research Achievements

We have fabricated self-organized nano-structured metallic films using bilayer (or seed layer assisted) agglomeration (BLA or SLAA) phenomena by sputtering. We demonstrated that the insertion of a thin seed layer (Ti, Fe, etc.) between a substrate and a Au or Ag layer promoted agglomeration and generated good-quality nanostructured films, such as nanodot or nanorod. A summary of this studies reveals that applying the BLA to the fabrication of nanodots resulted in (1) a manufactured film that has strong adhesion to the substrate, (2) a decrease in the agglomeration temperature, (3) enhancement of the epitaxial growth, and (4) formation of a nanostructure that reflects the surface symmetry of the substrate.
Based on the studies, we concluded that the mechanism of the BLA is based on the reduction in the surface energy in the film system and the enhancement of the thermal stress generated in the film. Typical optical absorbance spectra of the nanodots fabricated by BLA were also obtained.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (22 results)

All 2015 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 2 results) Presentation (15 results) (of which Invited: 2 results)

  • [Journal Article] Fabrication of self-organized epitaxial fcc-Ag(110) oriented nanorods by a Ti seed-layer-assisted thermal agglomeration method2015

    • Author(s)
      Masao Kamiko, Ryo Suenaga, Jung-Woo Koo, Kenji Nose, Kentaro Kyuno and Jae-Geun Ha
    • Journal Title

      Applied Physics Express

      Volume: 8 Issue: 3 Pages: 035503-035503

    • DOI

      10.7567/apex.8.035503

    • NAID

      210000137438

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of seed layers on structure of self-organized Ag nanodots on MgO substrates2015

    • Author(s)
      Masao Kamiko, Ryo Suenaga, Jung-Woo Koo, Kenji Nose, Kentaro Kyuno, Yoshitaka Mitsuda and Jae-Geun Ha
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54

    • NAID

      210000145254

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Epitaxial growth of fcc-Ag(001) nanodot on MgO(001) substrate via Ti seed layer assisted agglomeration2013

    • Author(s)
      Masao Kamiko, Ryo Suenaga, Jung-Woo Koo, Kenji Nose, Kentaro Kyuno, Jae-Geun Ha
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 46 Issue: 50 Pages: 505304-505304

    • DOI

      10.1088/0022-3727/46/50/505304

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Ti seed layers on structure of self-organized epitaxial face-centered-cubic -Ag(001) oriented nanodots2013

    • Author(s)
      M. Kamiko, R. Suenaga, J.-W. Koo, K. Nose, K. Kyuno, J.-G. Ha
    • Journal Title

      Journal of Applied Physics

      Volume: 114 Issue: 24 Pages: 244307-244307

    • DOI

      10.1063/1.4856975

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Atomic force microscopy and x-ray diffraction studies on agglomeration phenomena of ultrathin Au/Fe bilayers2012

    • Author(s)
      Masao Kamiko, Jung-Woo Koo, Jae-Min Kin, Jae-Geun Ha
    • Journal Title

      Journal of Vacuum Science and Technology

      Volume: A30

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Study on Effect of Various Underlayer on Bilayer Agglomerlation2012

    • Author(s)
      J. H. Ha, D. H. Ryu, H. W. Im, J. M. Jung, H. J. Choi, I. G. Hong, J. H. Koh, S. M. Koo, M. Kamiko, J. G. Ha
    • Journal Title

      Journal of the Korean Vacuum Society

      Volume: 21 Pages: 233-241

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of Ta Underlayers on Structure of TiO2 Thin Films Deposited on Unheated Glass Substrate2012

    • Author(s)
      Masao Kamiko, Kazuaki Aotani, Ryo Suenaga, Jung-Woo Koo, Kenji Nose, Kentaro Kyuno, Jae-Geun Ha
    • Journal Title

      Applied Surface Science

      Volume: 258 Pages: 8764-8768

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 5.Effect of seed layers on structure of self-organized Ag nanodots on MgO substrates2014

    • Author(s)
      M. Kamiko, R. Suenaga, J.-W. Koo, K. Nose, K. Kyuno, Y. Mitsuda and J.-G. Ha
    • Organizer
      27th International Microprocesses and Nanotechnology Conference (MNC2014)
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] 脱濡れ(凝集)現象を用いた自己組織化(Au、Ag)/Ti 薄膜のナノ構造2014

    • Author(s)
      神子公男、野瀬健二、光田好孝、河在浩、河在根
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 自己組織化Ag、Au薄膜のナノ構造におけるTiシード層の効果2014

    • Author(s)
      神子公男、野瀬健二、光田好孝、河在浩、河在根
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学
    • Year and Date
      2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属薄膜の脱濡れ(熱凝集)現象を用いた自己組織化2014

    • Author(s)
      神子公男
    • Organizer
      東京大学数物フロンティアチュートリアルシンポジウム「表面・界面ダイナミックス数理Ⅶ」
    • Place of Presentation
      東京大学
    • Year and Date
      2014-04-24
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 自己組織化Ag/Tiナノ構造薄膜の光学特性2013

    • Author(s)
      神子 公男, 末永 亮, 野瀬 健二, 具 正祐, 弓野 健太郎, 光田 好孝, 河 在根
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 二層凝集現象を用いた自己組織化Ag薄膜の微細構造制御2012

    • Author(s)
      神子 公男, 末永 亮, 野瀬 健二, 具 正祐, 弓野 健太郎, 光田 好孝, 河 在根
    • Organizer
      第73 回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 二層凝集現象を用いた自己組織化Agナノロッドの作製2012

    • Author(s)
      神子 公男, 末永 亮, 野瀬 健二, 具 正祐, 弓野 健太郎, 光田 好孝, 河 在根
    • Organizer
      第73 回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 二層凝集現象を用いたMgO基板上の自己組織化エピタキシャルAgナノドットの作製2012

    • Author(s)
      神子 公男, 末永 亮, 野瀬 健二, 具 正祐, 弓野 健太郎, 光田 好孝, 河 在根
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 二層凝集現象を用いて作製した自己組織化Agナノドット薄膜の光学特性2012

    • Author(s)
      神子 公男, 末永 亮, 野瀬 健二, 具 正祐, 弓野 健太郎, 光田 好孝, 河 在根
    • Organizer
      日本物理学会2012年秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Novel Fabrication Process for Epitaxial Ag Nanostructure via Ti Seed Layer Mediated Bi-Layer Agglomeration Phenomenon2012

    • Author(s)
      M. Kamiko, R. Suenaga, K. Nose, J.-W. Koo, K. Kyuno, Y. Mitsuda, and J.-G. Ha
    • Organizer
      IUMRS-International Conference on Electronic Materials (IUMRS-ICEM 2012)
    • Place of Presentation
      Pacifico Yokohama, Yokohama, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] α-Al2O3(0001)単結晶基板上Ni薄膜の脱濡れ過程

    • Author(s)
      神子公男、福原智、野瀬健二、光田好孝
    • Organizer
      2014年第61回応用物理学会春期学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 熱凝集現象を用いた自己組織化金属ナノ構造薄膜の作製

    • Author(s)
      神子公男
    • Organizer
      第8回「結晶成長の数理」研究会(平成25年度学習院大学計算機センター研究会)
    • Place of Presentation
      学習院大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Tiシード層促進凝集過程を用いた自己組織化Agナノ構造の基板依存性

    • Author(s)
      神子公男、末永亮、野瀬健二、具正祐、弓野健太郎、光田好孝、河在根
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Tiシード層による自己組織化Ag薄膜の凝集過程

    • Author(s)
      神子公男、末永亮、野瀬健二、具正祐、弓野健太郎、光田好孝、河在根
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Research-status Report
  • [Presentation] A Novel Fabrication Process of Self-organized Epitaxial Ag Nanodods: Ti seed layer Mediated Bilayer agglomeration Phenomenon

    • Author(s)
      M. Kamiko, R. Suenaga, K. Nose, J.-W. Koo, K. Kyuno, Y. Mitsuda, J.-G. Ha
    • Organizer
      19th International Vacuum Congress (IVC-19)
    • Place of Presentation
      Paris, France
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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