• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Composition Optimization of Silicate Slag for Rare-earth Recycling

Research Project

Project/Area Number 24560911
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Metal making engineering
Research InstitutionEhime University

Principal Investigator

TAKEBE Hiromichi  愛媛大学, 理工学研究科, 教授 (90236498)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsケイ酸塩スラグ / リン酸 / レアアース回収 / 光学特性 / 組成 / 溶出試験 / 赤外分光 / リン酸塩 / 熱処理 / ガラス構造 / 吸収特性
Outline of Final Research Achievements

In phospho-silicate slags, the composition condition, at which rare-earth elements are bonded selectively with PO4 tetrahedra, is [R2O+R'O]/[P2O5]≦1 in molar ratio, where R is the alkali metal and R' is the alkaline-earth metal. The structure of PO4 networks was characterized by infrared spectroscopy for optimized slag compositions. ICP-MS analysis revealed that rare-earth element and phosphate species were selectively dissolved into ultra-pure water by elution tests.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (27 results)

All 2015 2014 2013 Other

All Journal Article (9 results) (of which Peer Reviewed: 8 results,  Open Access: 3 results) Presentation (15 results) (of which Invited: 1 results) Remarks (3 results)

  • [Journal Article] Effect of B2O3/P2O5 substitution on the properties and structure of tin boro-phosphate glasses2015

    • Author(s)
      A. Saitoh, G. Tricot, P. Rajbhandari, S. Anan, H. Takebe
    • Journal Title

      Mat. Chem. Phys.

      Volume: 149-150 Pages: 648-656

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thermal properties, density and structure of percalcic and peraluminus CaO-Al2O3-SiO2 glasses2015

    • Author(s)
      S. Takahashi, D.R. Neuville, H. Takebe
    • Journal Title

      J. Non-Cryst. Solids

      Volume: 411 Pages: 5-12

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] The effects of B2O3 and Al2O3 additions on the structure of phosphate glasses2014

    • Author(s)
      H. Takebe, Y. Suzuki, T. Uemura
    • Journal Title

      Eur. J. Glass Sci. Technol. B

      Volume: 55 Pages: 207-210

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Red fluorescence lamellae in calcitic prismatic layer of Pinctada vulgaris shell (Mollusc, bibalvia)2014

    • Author(s)
      L. H. Arma, A. Saitoh, Y. Ishibashi, T. Asahi, Y. Sueoka, M. Sakakibara, H. Takebe
    • Journal Title

      Optical Materials Express

      Volume: 4 Pages: 1813-1823

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dissolution behaviour of SnO-P2O5 and SnO-P2O5-B2O3 glasses in water2013

    • Author(s)
      Hiromichi Takebe, Takuya Kobatake, Akira Saitoh
    • Journal Title

      Physics and Chemistry of Glasses: European Journal of Glass Science and Technology B

      Volume: 54 Pages: 182-186

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermal properties and crystallization behaviour in ZnO-SnO-P2O5 glasses2013

    • Author(s)
      Akira Saitoh, Shoji Anan, Hiromichi Takebe
    • Journal Title

      Physics and Chemistry of Glasses: European Journal of Glass Science and Technology B

      Volume: 54 Pages: 177-181

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] リンケイ酸塩ガラスにおけるレアアース濃縮のための組成条件2013

    • Author(s)
      中村洋貴、斎藤全、武部博倫
    • Journal Title

      Journal of MMIJ

      Volume: 129 Pages: 591-595

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] リン酸塩ガラスの特徴的な構造と機能およびその応用2013

    • Author(s)
      武部博倫、斎藤全
    • Journal Title

      セラミックス

      Volume: 48 Pages: 927-930

    • Related Report
      2013 Research-status Report
  • [Journal Article] Preparation of Porous Glass Films Using Phase Separation Phenomenon and Growth Behavior of Phase-separated Structure2013

    • Author(s)
      C. Hwang, J. Kim, B. K. Ryu, H. Takebe
    • Journal Title

      Journal of Materials Science

      Volume: 48 Pages: 8068-8076

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Rare-earth Recycling in Silicate Slag Melts by P2O5 Addition2015

    • Author(s)
      Hiromichi Takebe
    • Organizer
      ルーヴァン・カトリック大学, Department of Materials Engineeringでのミーティング
    • Place of Presentation
      ルーヴァン、ベルギー
    • Year and Date
      2015-02-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] CaO-Al2O3-SiO2ガラスの耐アルカリ性に及ぼすAl2O3の添加効果2015

    • Author(s)
      髙橋尚志、武部博倫
    • Organizer
      第53回セラミックス基礎科学討論会
    • Place of Presentation
      京都テルサ・京都
    • Year and Date
      2015-01-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Properties and Structure of Multi-component Oxide Slag Melts and Glasses Containing Iron Oxide2014

    • Author(s)
      Hiromichi Takebe
    • Organizer
      ユーリッヒ総合研究機構 (FZJ), Institute of Energy Researchでのミーティング
    • Place of Presentation
      ユーリッヒ、ドイツ
    • Year and Date
      2014-11-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] CaO-FeOx-SiO2ガラスにおけるFeの存在状態とガラス構造2014

    • Author(s)
      岡田明子, 武部博倫
    • Organizer
      第55回ガラス及びフォトニクス材料討論会
    • Place of Presentation
      東京工業大学(東京都目黒区)・東京
    • Year and Date
      2014-11-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Density, thermal properties and chemical durability of percalcic and peraluminus CaO-Al2O3-SiO2 glasses2014

    • Author(s)
      Hiromichi Takebe, Shoji Takahashi, Daniel R. Neuville
    • Organizer
      1st Joint Meeting of DGG - ACerS GOMD
    • Place of Presentation
      アーヘン、ドイツ
    • Year and Date
      2014-05-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 白金板とスラグ融体の界面相互作用2014

    • Author(s)
      武部博倫、道上聖史、森安諒
    • Organizer
      資源・素材学会春季大会
    • Place of Presentation
      東京大学生産技術研究所、東京
    • Related Report
      2013 Research-status Report
  • [Presentation] Mixed Network Structure of Tin Boro-phosphate Glasses by Advanced 1D/2D Solid State NMR and Infrared Spectroscopy2013

    • Author(s)
      Hiromichi Takebe, Akira Saitoh, Gregory Tricot
    • Organizer
      23rd International Congress on Glass
    • Place of Presentation
      Prague, Czech Republic
    • Related Report
      2013 Research-status Report
  • [Presentation] Effects of Al2O3 on the thermal properties and structure of CaO-Al2O3-SiO2 glasses2013

    • Author(s)
      Shoji Takahashi, Hiromichi Takebe
    • Organizer
      23rd International Congress on Glass
    • Place of Presentation
      Prague, Czech Republic
    • Related Report
      2013 Research-status Report
  • [Presentation] マグネシウム-クロム質耐火物の微細組織とスラグ融体の界面反応2013

    • Author(s)
      武部博倫、福井智也、森安諒
    • Organizer
      資源・素材2013(札幌)
    • Place of Presentation
      北海道大学、札幌
    • Related Report
      2013 Research-status Report
  • [Presentation] 乾式製錬小委員会の立ち上げに向けて

    • Author(s)
      武部博倫
    • Organizer
      素材プロセシング第69委員会 第4分科会(産学連携促進)〔第10回〕研究会
    • Place of Presentation
      東京大学本郷キャンパス、東京
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] CaO-Al2O3-SiO2ガラスの熱的特性と構造に及ぼすAl2O3の添加効果

    • Author(s)
      高橋尚志、武部博倫
    • Organizer
      第53回ガラス及びフォトニクス材料討論会
    • Place of Presentation
      北海道大学
    • Related Report
      2012 Research-status Report
  • [Presentation] リン酸塩ガラスの耐水性に及ぼす組成の影響

    • Author(s)
      武部博倫、斎藤全
    • Organizer
      第53回ガラス及びフォトニクス材料討論会
    • Place of Presentation
      北海道大学
    • Related Report
      2012 Research-status Report
  • [Presentation] リンケイ酸塩系模擬スラグにおけるレアアース濃縮のための組成条件

    • Author(s)
      中村洋貴、武部博倫
    • Organizer
      平成24年度 資源・素材関係学協会合同秋季大会
    • Place of Presentation
      秋田大学 手形キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] カルシウムアルミノケイ酸塩スラグ固化体の熱的特性の組成依存性

    • Author(s)
      高橋尚志、武部博倫
    • Organizer
      日本鉄鋼協会・日本金属学会 中国四国支部 日本鉄鋼協会第55回・日本金属学会第52回講演大会
    • Place of Presentation
      鳥取大学 鳥取キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] カルシウムアルミノケイ酸塩スラグ融体の粘度特性

    • Author(s)
      徳永亮太、中川皓介、武部博倫
    • Organizer
      日本鉄鋼協会・日本金属学会 中国四国支部 日本鉄鋼協会第55回・日本金属学会第52回講演大会
    • Place of Presentation
      鳥取大学 鳥取キャンパス
    • Related Report
      2012 Research-status Report
  • [Remarks] 愛媛大学 材料プロセス工学研究室 ホームページ

    • URL

      http://mpel.jp

    • Related Report
      2014 Annual Research Report
  • [Remarks] 愛媛大学材料プロセス工学研究室HP

    • URL

      http://mpel.jp

    • Related Report
      2013 Research-status Report
  • [Remarks] 愛媛大学 材料プロセス工学研究室

    • URL

      http://www.mat.ehime-u.ac.jp/takebe/index.html

    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi