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Synthesis of new temperature-responsive separation membrane -Control of permeable molecular size by temperature-

Research Project

Project/Area Number 24560916
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionAkita University

Principal Investigator

MURAKAMI Kenji  秋田大学, 工学(系)研究科(研究院), 教授 (10272030)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords温度応答材料 / 感温性高分子 / 分離膜 / 有機無機複合体 / 架橋剤 / 膜透過係数 / 温度応答性膜 / 分子ふるい / 温度応答性
Outline of Final Research Achievements

The purpose of this study is to synthesize the temperature-responsive membrane by covering the temperature-responsive polymer (poly(N-isopropylacrylamide), PNIPAM) onto the inorganic porous membrane. The membrane covered with N, N'-methylenebisacrylamide-crosslinked PNIPAM was also prepared in order to change the transition temperature. When the methyl orange (MO) was used as a guest molecule for the membrane permeation experiment, it was found that the permeation rate of MO molecule above the transition temperature was much faster than that below the transition temperature. Moreover, when the amount of added BIS was increased, it was clarified that the MO molecule did not pass through the membrane below the transition temperature at all. In this way, we succeeded that the synthesis of temperature-responsive membrane in which the permeation rate of molecule changed by changing the solution temperature.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (10 results)

All 2014 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (7 results) Remarks (1 results)

  • [Journal Article] Transition temperature control of adsorption-desorption property of PNIPAM/ mesoporous silica composite by addition of crosslinking agent2013

    • Author(s)
      Kenji Murakami, Shinichi Watanabe, Takahiro Kato, Katsuyasu Sugawara
    • Journal Title

      Colloids Surfaces A: Physicochemical and Engineering Aspects

      Volume: 419 Pages: 223-227

    • DOI

      10.1016/j.colsurfa.2012.11.074

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of Amount of Thermosensitive Polymer on Anion-Exchange Properties of Thermosensitive Polymer/Mesoporous Silica Composite2013

    • Author(s)
      村上賢治,加藤貴宏,菅原勝康
    • Journal Title

      KAGAKU KOGAKU RONBUNSHU

      Volume: 39 Issue: 3 Pages: 206-212

    • DOI

      10.1252/kakoronbunshu.39.206

    • NAID

      10031188050

    • ISSN
      0386-216X, 1349-9203
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 温度応答性分離膜の合成とその分離特性の評価2014

    • Author(s)
      澤田俊一,木村瑠璃子,村上賢治
    • Organizer
      平成26年度化学系学協会東北大会
    • Place of Presentation
      山形大学米沢キャンパス
    • Year and Date
      2014-09-20 – 2014-09-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 感温性高分子/メソポーラスシリカ複合体の陰イオン交換特性の温度応答性の制御2014

    • Author(s)
      佐藤安斗,村上賢治
    • Organizer
      平成26年度化学系学協会東北大会
    • Place of Presentation
      山形大学米沢キャンパス
    • Year and Date
      2014-09-20 – 2014-09-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 感温性高分子被覆メソポーラスシリカ吸着剤の温度応答性の制御2014

    • Author(s)
      村上賢治,佐藤安斗
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation of PNIPAM/silica membrane and its separation characteristics2013

    • Author(s)
      Ruriko Kimura, Kenji Murakami
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      東北大学(仙台)
    • Related Report
      2013 Research-status Report
  • [Presentation] Control of temperature responsivity of anion exchange property of thermosensitive polymer/mesoporous silica composite2013

    • Author(s)
      Yasuto Sato, Ruriko Kimura, and Kenji Murakami
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      東北大学(仙台)
    • Related Report
      2013 Research-status Report
  • [Presentation] 温度応答性分離膜の調製およびその分離特性2013

    • Author(s)
      木村瑠璃子,村上賢治
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 感温性ゲートを有するメソポーラスシリカの合成と分離膜への応用2012

    • Author(s)
      木村瑠璃子,村上賢治,加藤貴宏,菅原勝康
    • Organizer
      平成24年度化学系学協会東北大会
    • Place of Presentation
      秋田大学
    • Related Report
      2012 Research-status Report
  • [Remarks] 秋田大学大学院工学資源学研究科 環境応用化学専攻 村上研究室

    • URL

      http://www.gipc.akita-u.ac.jp/~physchem/

    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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