Application of zeolite membranes for environmental friendly processes

• Project/Area Number: 24560927
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Properties in chemical engineering process/Transfer operation/Unit operation
• Research Institution: Yamaguchi University
• Principal Investigator: KUMAKIRI Izumi 山口大学, 理工学研究科, 准教授 (20618805)
• Co-Investigator(Kenkyū-buntansha): TANAKA Kazuhiro 山口大学, 大学院理工学研究科, 准教授 (30188289)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
• Keywords: ゼオライト膜 / 水熱合成 / 結晶成長 / 溶液分離 / ガス分離 / 非水系分離 / 膜分離法 / 脱水 / エステル交換反応 / 反応分離 / 分離 / エタノール / 共沸混合物 / メタノール / 水熱合成法 / 液分離 / マイクロ波加熱 / パームポロメトリー

Outline of Final Research Achievements

Zeolites membranes are expected to show separation abilities based on their ordered sub-micron meter sized zeolitic pores. In this study, influences of the preparation conditions on the membrane morphology and on the perm-selectivity were studied. Application of zeolite membranes to solvent separations and to trans-esterification reaction were examined with FAU type zeolite membranes.

Research Products

• [Journal Article] Application of FAU zeolite membranes to alcohol/acrylate mixture systems (2014)
  • Author(s): I. Kumakiri, K. Hashimoto, Y. Nakagawa, Y. Inoue, Y. Kanehiro, K. Tanaka, H. Kita
  • Journal Title: Catalysis today Volume: 236 Pages: 86-91
  • DOI: 10.1016/j.cattod.2013.11.064
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] NaY Zeolite Membranes with 1 High Performance Prepared by a Variable-temperature Synthesis (2013)
  • Author(s): Zhenzhuo Wang, Izumi Kumakiri, Kazuhiro Tanaka, Xiangshu Chen and Hidetoshi Kita
  • Journal Title: Microporous and Mesoporous Materials Volume: 182 Pages: 250-258
  • DOI: 10.1016/j.micromeso.2013.05.002
  • Peer Reviewed
• [Journal Article] Preparation of Low Silica X-type Zeolite Membranes on Porous Support by Microwave Heating (2013)
  • Author(s): Zhenzhuo Wang, Izumi Kumakiri, Kazuhiro Tanaka, and Hidetoshi Kita
  • Journal Title: Membrane Volume: 38(2) Pages: 97-100
  • NAID: 10031165415
  • Peer Reviewed
• [Presentation] Influence of the operation conditions on the CH4/H2 and CO2/H2 separation properties of MFI zeolite membranes (2015)
  • Author(s): I. Kumakiri, Y. Yamashita, L. Qui, K. Tanaka, H. Kita, F. Cacho, S. Sorribas, C. Tellez, J. Corronas
  • Organizer: International Symposium on Zeolite and Microporous Crystals
  • Place of Presentation: 札幌コンベンションセンター（札幌市）
  • Year and Date: 2015-06-28 – 2015-07-02
• [Presentation] Pore-plugging法により製膜したMFI型ゼオライト膜の透過分離性能 (2015)
  • Author(s): 山下祐太，熊切 泉，田中一宏，喜多英敏
  • Organizer: 化学工学会第80年会
  • Place of Presentation: 芝浦工業大学(江東区）
  • Year and Date: 2015-03-19 – 2015-03-21
• [Presentation] 種結晶がMFI型ゼオライト膜の透過特性に与える影響 (2014)
  • Author(s): 山下裕太，熊切 泉，田中一宏，喜多英敏
  • Organizer: 化学工学会第46回秋季大会
  • Place of Presentation: 九州大学（福岡市）
  • Year and Date: 2014-09-17 – 2014-09-19
• [Presentation] Influence of post-modification on the gas separation performance of MFI zeolite membranes (2014)
  • Author(s): I. Kumakiri,T. Yamamoto, K. Hashimoto, K. Tanaka, H. Kita, F. Cacho, S. Sorribas, C. Tellez, J. Coronas
  • Organizer: 10th International Congress on Membranes and Membrane Processes (ICOM 2014)
  • Place of Presentation: Ｓｕｚｈｏｕ （中国）
  • Year and Date: 2014-07-20 – 2014-07-25
• [Presentation] Improvement of CO2/CH4 selectivity of zeolite membranes by post-treatment (2014)
  • Author(s): I.Kumakiri, T.Yamamoto, K. Hashimoto, K. Tanaka, H. Kita, F. Cacho, S. Sorribas, C. Tellez, J. Coronas
  • Organizer: 13th International Coference on Inorganic Membranes (ICIM)
  • Place of Presentation: Ｂｒｉｓｂａｎｅ （オーストラリア ）
  • Year and Date: 2014-07-06 – 2014-07-09
• [Presentation] 二次成長法による親水性MFI型ゼオライト膜の合成 (2014)
  • Author(s): 山下裕太，熊切 泉，田中一宏，喜多英敏
  • Organizer: 日本膜学会第36年会
  • Place of Presentation: 早稲田大学（新宿区）
  • Year and Date: 2014-05-12 – 2014-05-13
• [Presentation] MFIゼオライト膜の水･アルコール分離性能に与える種結晶の影響 (2014)
  • Author(s): 山下 裕太、山本琢也、熊切 泉、田中 一宏、喜多 英敏
  • Organizer: 化学工学会学生発表会
  • Place of Presentation: 大阪府立大学中百舌鳥キャンパス（大阪府堺市）
• [Presentation] Application of FAU zeolite membranes to alcohol/acrylate mixture systems (2013)
  • Author(s): Izumi Kumakiri, Zhenzhuo Wang, Kouji Hashimoto, Yushihiko Nakagawa, KazuhiroTanaka, Hidetoshi Kita
  • Organizer: International conference on catalysis and membrane reactors
  • Place of Presentation: ポルト（ポルトガル）
• [Presentation] Zeolite membranes; from bio-alcohol purification to membrane reactors (2013)
  • Author(s): Izumi Kumakiri, Kazuhiro Tanaka, Hidetoshi Kita
  • Organizer: 2nd Japanese-Norwegian Workshop, Membranes for Sustainable Energy Technology
  • Place of Presentation: オスロ（ ノルウェー）
• [Presentation] Zeolite membranes, Preparation and application as separators, membrane reactors (2013)
  • Author(s): Izumi Kumakiri, Kazuhiro Tanaka, Hidetoshi Kita
  • Organizer: 1st symposium on membranes and sustainable technologies
  • Place of Presentation: サラゴサ（スペイン）
• [Presentation] ゼオライト膜の分離透過性能に与える後処理の影響 (2013)
  • Author(s): 橋本 康司、熊切泉、田中 一宏、喜多 英敏
  • Organizer: 化学工学会秋季大会
  • Place of Presentation: 岡山大学津島キャンパス（岡山市）
• [Presentation] Pore-Plugging法によるMFIゼオライト膜の透過物性 (2013)
  • Author(s): 山下 裕太、熊切 泉、田中 一宏、喜多 英敏
  • Organizer: 膜シンポジウム
  • Place of Presentation: 京都府立医科大学附属図書館ホール（京都）
• [Presentation] FAU型ゼオライト膜の有機溶媒分離への適用 (2013)
  • Author(s): 熊切 泉、橋本 康司、Zhenzhuo Wang、中川 慶彦、井上 優子、兼弘 洋平、田中 一宏、喜多 英敏
  • Organizer: 膜シンポジウム
  • Place of Presentation: 同志社大学寒梅館（京都市）
• [Presentation] ゼオライト膜の合成条件と分離特性の関係 (2013)
  • Author(s): 橋本 康司、熊切 泉、田中 一宏、喜多 英敏
  • Organizer: 日本膜学会年会
  • Place of Presentation: 東京早稲田大学理工学部（東京都新宿区）
• [Presentation] 結晶成長によるゼオライト膜の合成 (2013)
  • Author(s): 熊切泉,橋本康司,田中一宏,喜多英敏
  • Organizer: 化学工学第78年会
  • Place of Presentation: 大阪大学 （大阪）
• [Presentation] Dehydration of acetic acid and esterification product by ZSM-5membrane (2012)
  • Author(s): Meihua Zhu, Izumi Kumakiri, Kazuhiro Tanaka, Hidetoshi Kita
  • Organizer: nternational Symposium on Zeolite and MicroPorous Crystals (ZMPC2012)
  • Place of Presentation: アスタープラザ （広島）
• [Presentation] Preparation of SDA-free MFI membranes for liquid separations (2012)
  • Author(s): Zhenzhuo Wang, Izumi Kumakiri, Kazuhiro Tanaka, Xiangshu Chen, Hidetoshi Kita
  • Organizer: International Symposium on Zeolite and MicroPorous Crystals (ZMPC2012)
  • Place of Presentation: アスタープラザ （広島）
• [Presentation] Preparation of SDA-free MFI membranes for liquid separations (2012)
  • Author(s): Izumi Kumakiri, Meihua Zhu, Shoichiro Sasamoto, KazuhiroTanaka, Hidetoshi Kita, Yukichi Sasaki
  • Organizer: Pre-symposium of International Symposium on Zeolite and MicroPorous Crystals (ZMPC2012)
  • Place of Presentation: コープイン京都 （京都）
• [Presentation] Hydrophilic MFI membranes for dehydration applications (2012)
  • Author(s): Izumi Kumakiri, Meihua Zhu, Shoichiro Sasamoto, KazuhiroTnaka, Hidetoshi Kita,Yukichi Sasaki
  • Organizer: 12th International Conference on Inorganic Membranes (ICIM12)
  • Place of Presentation: Enschede （オランダ）
• [Presentation] Application of hydrophilic MFI membranes in liquid separations (2012)
  • Author(s): Izumi Kumakiri, Meihua Zhu, Shoichiro Sasamoto, KazuhiroTanaka, Hidetoshi Kita, Yukchi Sasaki
  • Organizer: The 7th conference of Aseanian Membrane Society
  • Place of Presentation: Haeundae （韓国）