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Development of hydrogen selective membranes for sustainable hydrogen production

Research Project

Project/Area Number 24560928
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionYamaguchi University

Principal Investigator

TANAKA Kazuhiro  山口大学, 理工学研究科, 准教授 (30188289)

Co-Investigator(Kenkyū-buntansha) KUMAKIRI Izumi  山口大学, 大学院理工学研究科, 准教授 (20618805)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords水素製造 / 水素分離膜 / ポリイミド膜 / 炭化膜 / 光触媒 / 水素製造法 / 光触媒水素製造
Outline of Final Research Achievements

In this study, we have developed hydrogen selective gas separation membranes which can be used for the separation of hydrogen over oxygen in an atmospheric temperature and pressure. The goal performance was the separation factor of 100 and the hydrogen permeance of 100 [1E-10 mol/(m2 s Pa)]. We selected three kind of membrane materials: a crosslinked polyimide, a carbon prepared from Kapton polyimide, and a silica to fabricate composite hydrogen selective membranes. The highest performance of the membrane prepared from each material is as follow. The separation factor and hydrogen permeance are 77 and 6 for the crosslinked polyimide membrane, 26 and 35 for the carbon membrane, respectively. Hydrogen selective silica membrane was not successfully fabricated. The performance for crosslinked polyimide and carbon membranes may be improved to some extent by optimizing fabrication conditions.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (6 results)

All 2015 2014 2013 2012

All Presentation (6 results)

  • [Presentation] 光触媒水素製造に用いる光架橋ポリイミド複合膜の作製条件の検討2015

    • Author(s)
      林 健太郎、熊切 泉、田中 一宏、喜多 英敏
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 多孔質セラミックス支持体へのポリイミド薄膜の作製2014

    • Author(s)
      林 健太郎、香河 憲成、松永 理光、熊切 泉、田中 一宏、喜多 英敏
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学柳戸キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 水素分離用ポリイミド複合膜の作製と性能評価2013

    • Author(s)
      田中一宏、松永理光、林 健太郎、古賀智子、飯田高史、熊切 泉、喜多英敏
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] ポリイミド複合膜に用いる多孔質セラミックス支持体への中間層の作製2013

    • Author(s)
      松永 理光、林 健太郎、熊切 泉、田中 一宏、喜多 英敏
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学津島キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 高分子複合膜用の多孔質セラミックス支持層の作製条件の検討2013

    • Author(s)
      松永 理光、熊切 泉、田中 一宏、喜多 英敏
    • Organizer
      化学工学会中国四国支部大会
    • Place of Presentation
      山口大学常盤キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 膜分離を複合化した光触媒水素製造に用いるシリカ膜の作製2012

    • Author(s)
      田中一宏
    • Organizer
      化学工学会高松大会
    • Place of Presentation
      サンポートホール高松(高松市)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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