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Optimal Design of Particle Deposition Thin Film for Electrode of Dye-Sensitized Solar Cells

Research Project

Project/Area Number 24560932
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionDoshisha University

Principal Investigator

MORI Yasushige  同志社大学, 理工学部, 教授 (60127149)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords色素増感太陽電池 / チタニア粒子 / 電極構造 / 薄膜作製プロセス / 電気泳動堆積法 / 分散状態 / 膜内空隙率 / 粒子形状 / 電気泳動集積法
Outline of Final Research Achievements

Titania nanoparticle films which are used for an electrode of dye sensitized solar cells (DSSCs) have a key role of the photoelectric conversion. This film is usually fabricated by doctor blade method or screen printed method, but the attempt to control the structure of the films was not carried out so much. In this study, the fabrication methods of the film and the evaluation methods for the film structure was investigated. And the optimal condition of the fabrication of the film including the effect of particle shape was found.
The electrophoretic deposition method was suitable formation method of the film. The deposition speed can be estimated by the operation conditions. The influence of the film structure on the performance of DSSCs was carried out using particles with four kinds of different shape. It was found that the suitable porosity of particle film and the mixing ratio of these particles to achieve high photoelectric conversion of DSSCs.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (17 results)

All 2015 2014 2013 2012

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (13 results) (of which Invited: 1 results)

  • [Journal Article] Titania Nanoparticle Film Prepared by Electrophoretic Deposition under DC Constant-Current Condition2015

    • Author(s)
      Yasushige Mori, Kenta Yamada, Yuya Hattori, Yuuki Sato, Shinzo Yoshikado, Katsumi Tsuchiya
    • Journal Title

      Key Engineering Materials

      Volume: 654 Pages: 208-212

    • DOI

      10.4028/www.scientific.net/kem.654.208

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Composite thin films prepared by electrophoresis using two types of TiO<sub>2</sub> nanoparticles2014

    • Author(s)
      Ryo KAWAKAMI, Yuuki SATO, Yasushige MORI, Shinzo YOSHIKADO
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 122 Issue: 1426 Pages: 436-442

    • DOI

      10.2109/jcersj2.122.436

    • NAID

      130004480257

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Verification of necessity of one-dimensional titania nanoscale materials2013

    • Author(s)
      Motonari Adachi, Ryo Tanino, Jun Adachi, Yasushige Mori, Katsumi Tsuchiya, Seiji Isoda
    • Journal Title

      Journal of Power Sources

      Volume: 226 Pages: 94-100

    • DOI

      10.1016/j.jpowsour.2012.10.024

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Stripe and Network Formation of Particle Arrays Fabricated by Convective Self-assembly2012

    • Author(s)
      Ryuichi Sakamoto, Yoshiki Hataguchi, Ryosuke Kimura, Katsumi Tsuchiya, and Yasushige Mori
    • Journal Title

      Chemistry Letters

      Volume: 41 Issue: 10 Pages: 1207-1209

    • DOI

      10.1246/cl.2012.1207

    • NAID

      10031120633

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 色素増感太陽電池の光電変換特性に及ぼすチタニア粒子電極構造の影響2015

    • Author(s)
      荒谷心,羽田野兼資,土屋活美,森康維
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学 (東京都)
    • Year and Date
      2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 定電流直流電場下での粒子集積膜の作製2014

    • Author(s)
      安田武史,横手敦美,土屋活美,森康維
    • Organizer
      粉体工学会2014年度秋期研究発表会
    • Place of Presentation
      東京ビックサイト(東京都)
    • Year and Date
      2014-11-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Titania Nanoparticle Film Prepared by Electrophoretic Deposition with DC Constant Current Condition2014

    • Author(s)
      Yasushige Mori, Kenta Yamada, Yuya Hattori, Katsumi Tsuchiya
    • Organizer
      International Conference on Electrophoretic Deposition V: Fundamentals and Applications (EPD 2014)
    • Place of Presentation
      Hernstein (Austria)
    • Year and Date
      2014-10-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] Stripe- and network-patterned structures of silica submicrometer particles prepared by convective self-assembly method2014

    • Author(s)
      Y. Mori, R. Sakamoto, K. Tsuchiya
    • Organizer
      CHISA 2014
    • Place of Presentation
      Prague (Czech Republic)
    • Year and Date
      2014-08-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 色素増感太陽電池のチタニア電極作製方法の検討と効率測定2014

    • Author(s)
      荒谷 心,横山 大幸,土屋 活美,森 康維
    • Organizer
      粉体工学会2014年度春期研究発表会
    • Place of Presentation
      メルパルク京都(京都市)
    • Year and Date
      2014-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Formation of Stripe Structures of Silica Particles by Convective Self-Assembly Method2014

    • Author(s)
      R. Kitagawa, R. Sakamoto, K. Tsuchiya, Y. Mori
    • Organizer
      6th Asian Coating Workshop (ACW2014)
    • Place of Presentation
      神戸大学(兵庫県,神戸市)
    • Year and Date
      2014-05-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Formation of Stripe and Network Structures of Silica Particles by Convective Self-Assembly2013

    • Author(s)
      Ryuichi Sakamoto, Ryosuke Kimura, Katsumi Tsuchiya, Yasushige Mori
    • Organizer
      9th World Congress of Chemical Engineering
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2013 Research-status Report
  • [Presentation] Titania Nanoparticle Film Prepared by Electrophoretic Deposition2013

    • Author(s)
      Kenta Yamada, Ryosuke Kimura, Katsumi Tsuchiya, Yasushige Mori
    • Organizer
      9th World Congress of Chemical Engineering
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2013 Research-status Report
  • [Presentation] 色素増感太陽電池におけるチタニア材料形状の電極構造への影響2013

    • Author(s)
      横山 大幸,荒谷 心,森 康維,土屋 活美,足立 基齊,内田 文生
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Stripe and Network Formation of Particle Arrays Fabricated by Convective Self-Assembly2012

    • Author(s)
      Ryuichi Sakamoto, Yoshiki Hataguchi, Ryosuke Kimura, Katsumi Tsuchiya, Yasushige Mori
    • Organizer
      IACIS (International Association of Colloid and Interface Scientists) Conference 2012
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Nanoparticles for Use in New Generation Solar Cells2012

    • Author(s)
      Yasushige Mori
    • Organizer
      The 5th Asian Particle Technology Symposium (APT2012)
    • Place of Presentation
      Singapore
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Evaluation of Nanoparticle Arrays Fabricated by Electrophoretic Deposition2012

    • Author(s)
      Ryosuke Kimura, Katsumi Tsuchiya, and Yasushige Mori
    • Organizer
      The 5th Asian Particle Technology Symposium (APT2012)
    • Place of Presentation
      Singapore
    • Related Report
      2012 Research-status Report
  • [Presentation] Formation of Nanoparticles for Dye-Sensitized Solar Cells2012

    • Author(s)
      Yasushige Mori
    • Organizer
      KIFFE Symposium 2012
    • Place of Presentation
      Trondheim, Norway
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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