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Optimized method of the separation field in mesoporous materials

Research Project

Project/Area Number 24560933
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKansai University

Principal Investigator

MIYAKE Yoshikazu  関西大学, 環境都市工学部, 教授 (70111995)

Research Collaborator KOLEV Spas. D.  School of Chemisty, The University of Melbourne
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords擬二次吸着モデル / メソポーラスシリカ粒子 / 拡散係数 / 破過曲線 / Overshoot現象 / 吸着速度 / 擬二次動力学モデル / 拡散律速過程 / メソ構造吸着剤 / ZIF-8 / 金属イオン / 擬二次動力学モデル過程
Outline of Final Research Achievements

Adsorption rates of some metal ions in the aqueous phase were measured by using the spherical mesoporous silica particles in the batch reactor. The adsorption rates can be correlated by the pseudo-second adsorption model, and the apparent diffusion coefficient in the mesoporous silica particles can be evaluated by the rate parameters in this model. This model can be also applied to the adsorption rate for metal ions with the spherical chelating agents and for the alcohol with ZIF-8. Furthermore, the breakthrough curves for the packed column of the adsorption process of metal ions with the spherical chelating agents can be evaluated with the pseudo-second adsorption model. We have been observed the overshoot phenomena for two metal ions by the packed column experiments. The quantitative calculation will be studied by the use of this model proposed in the study.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (8 results)

All 2014 2013 2012

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (6 results) Book (1 results)

  • [Journal Article] Theoretical analysis of the pseudo-second order kinetic model of adsorption. Application to the adsorption of Ag(I) to mesoporous silica microspheres functionalized with thiol groups2013

    • Author(s)
      Yoshikazu Miyake, Hiroya Ishida, Shunsuke Tanaka, Spas D. Kolev
    • Journal Title

      Chemical Engineering Journal

      Volume: 218 Pages: 350-357

    • DOI

      10.1016/j.cej.2012.11.089

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Mechanochemcial synthesis of polycrystalline zeolitic imizolate frameworks2014

    • Author(s)
      S.Tanaka, K. Kida, T. Nagaoka, Y.Miyake
    • Organizer
      6th FEZA Conference
    • Place of Presentation
      Leibzigh(ドイツ)
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Exposed crystal face controlled synthesis of zeolitic imidazolate framework-82014

    • Author(s)
      K. Fujita, S. Tanaka, Y. Miyake
    • Organizer
      6th FEZA Conference
    • Place of Presentation
      Leibzig(ドイツ)
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Adsorption properties of polycrystalline zeolitic imidazolate frameworks2014

    • Author(s)
      A. Yasuyoshi, K. Kida, T. Nagaoka, T.Nishiyama, R. Konishi, S. Tanaka, Y.Miyake
    • Organizer
      6th FEZA Conference
    • Place of Presentation
      Leipzig(ドイツ)
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Physical Meaning of "Pseudo-Second Order Kinetic Model" for Chemisorptions2013

    • Author(s)
      Y.Miyake, S.Yamamura, M.Yoshizawa,S.Tanaka, S.D.Kolev
    • Organizer
      Chemeca 2013
    • Place of Presentation
      Brisbane (Australia)
    • Related Report
      2013 Research-status Report
  • [Presentation] Adsorption Behavior for Pseudo-second Order Kinetic Model2013

    • Author(s)
      Y.Miyake, J. Kawai, S. Yamamura, S.Tanaka,S.D.Kolev
    • Organizer
      ISChE2013
    • Place of Presentation
      Busan (Korea)
    • Related Report
      2013 Research-status Report
  • [Presentation] 化学吸着における「擬二次動力学モデル」の物理的意味について2012

    • Author(s)
      三宅義和、石田大也、田中俊輔、Spas D. Kolev
    • Organizer
      分離技術会年会2012
    • Place of Presentation
      関西大学
    • Related Report
      2012 Research-status Report
  • [Book] 分離技術のシーズとライセンス技術の実用化2014

    • Author(s)
      来田康司、田中俊輔、三宅義和
    • Total Pages
      166
    • Publisher
      分離技術会編
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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