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Development of a Micro Reactor for Continuous Flow Demulsification of an Emulsion by an Alternating Electric Field

Research Project

Project/Area Number 24560943
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionOsaka Prefecture University

Principal Investigator

Muto Akinori  大阪府立大学, 工学(系)研究科(研究院), 教授 (00174243)

Co-Investigator(Kenkyū-buntansha) HAYATO TOKUMOTO  大阪府立大学, 工学研究科, 講師 (70405348)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords交流電場 / 周波数 / 電解質 / 誘電率 / 界面活性剤 / W/O型エマルジョン / 溶媒 / 比誘電率 / 有機溶媒 / イオン強度 / W/Oエマルション / 誘起電荷 / マイクロリアクター / 解乳化 / エマルジョン / 電場 / 交流電流 / マイクロ流路 / エマルション
Outline of Final Research Achievements

Emulsions are often generated as unwanted byproducts from the treatment of oil and aqueous solutions. In this study, we investigated the demulsification oby the application of an alternating current (AC) electric field. A fluorocarbon tube of 1 mm diameter was used for the emulsion flow. The emulsion was smoothly separated into clear water and the organic solvent.Ethylbenzene, toluene, o-xylene, m-xylene, p-xylene, cyclohexane, and n-hexane were employed as organic solvents. Sorbitan monooleate (Span80) was used as a surfactant. The following conclusions could be made from the study: (1) the square waveform alternating electric field was more effective than the sine waveform; (2) in all organic solvents, the demulsification rate varied significantly with changes in the oil phase volume fraction; (3) a greater relative permittivity promoted demulsification; (4) demulsification rates varied with the ionic strength of the aqueous phase.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (11 results)

All 2016 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (6 results) (of which Invited: 2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Continuous Flow Demulsification of a Water-in-Toluene Emulsion by an Alternating Electric Field2015

    • Author(s)
      Akinori Muto, Tomoyuki Matsumoto, Hayato Tokumoto
    • Journal Title

      Separation and Purification Technology

      Volume: 156 Pages: 175-182

    • DOI

      10.1016/j.seppur.2015.09.071

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Demulsification of Emulsion Containing SPAN80 as a Stabilizer by an Alternating Electric Field2015

    • Author(s)
      武藤明徳
    • Journal Title

      Japan Journal of Food Engineering

      Volume: 16 Issue: 2 Pages: 177-180

    • DOI

      10.11301/jsfe.16.177

    • NAID

      130005109621

    • ISSN
      1345-7942, 1884-5924
    • Related Report
      2015 Annual Research Report
    • Open Access
  • [Journal Article] Continuous demulsification of water and toluene emulsion using electric field in a mm-order diameter tube2014

    • Author(s)
      A. Muto, T. Matsumoto, and H. Tokumoto
    • Journal Title

      Proceedings of the 10th International Conference on Separation Science and Technology (ICSST14)

      Volume: 10

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] O/W型エマルジョンの電場印加法による解乳化2016

    • Author(s)
      衣川康一朗,武藤明徳,徳本勇人
    • Organizer
      第18回化学工学会学生発表会(福岡大会)
    • Place of Presentation
      福岡大学七隈キャンパス(福岡市城南区)
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 安定なエマルジョンを連続・迅速・低コストで 解乳化する装置の開発.2015

    • Author(s)
      武藤明徳
    • Organizer
      イノベーション・ジャパン2015
    • Place of Presentation
      東京ビッグサイト(東京都江東区)
    • Year and Date
      2015-08-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機合成反応の周辺操作への マイクロリアクターの応用.2015

    • Author(s)
      武藤明徳
    • Organizer
      京都大学マイクロ化学生産研究コンソーシアム 「2015 年度第1回年度全体会議および講演会」
    • Place of Presentation
      京都大学桂キャンパス(京都市西区)
    • Year and Date
      2015-04-20
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] SPAN80を安定剤とするエマルジョンの 電場印加法による解乳化2015

    • Author(s)
      武藤明徳
    • Organizer
      食品新技術研究会第17回例会
    • Place of Presentation
      東京海洋大学(東京都港区)
    • Year and Date
      2015-04-17
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] マイクロ流路中のエマルジョンの電場印加による解乳化におよぼす有機相の種類ならびに水相中の電解質の影響2015

    • Author(s)
      武藤明徳、松本朋之、平口悠一、徳本勇人
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス(東京都江東区)
    • Year and Date
      2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] マイクロ流路に発生させた高電場によるトルエン―水系エマルジョンの解乳化

    • Author(s)
      松本朋之, 徳本勇人, 武藤明徳
    • Organizer
      化学工学会第45回秋季大会(2013年9月, 岡山)
    • Place of Presentation
      岡山市
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 解乳化装置及び解乳化方法2016

    • Inventor(s)
      武藤明徳
    • Industrial Property Rights Holder
      武藤明徳
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-040330
    • Filing Date
      2016-03-02
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 解乳化装置および解乳化方法2013

    • Inventor(s)
      武藤 明徳
    • Industrial Property Rights Holder
      大阪府立大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-02-04
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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