| Project/Area Number |
24560944
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | University of Yamanashi |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
HIGASHIYAMA Kazutoshi 山梨大学, 総合研究部, 教授 (10530090)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
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| Keywords | 暴走抑制 / 一酸化炭素メタン化反応 / 二酸化炭素メタン化反応 / 選択性制御 / ニッケル系触媒 / メソポーラスシリカ被覆 / 固体高分子形燃料電池 / 燃料改質反応 / 選択性の制御 / 熱暴走の抑制 / 一酸化炭素のメタン化 / 二酸化炭素のメタン化 / 一酸化炭素選択メタン化 / 燃料改質器 / 家庭用燃料電池 / 熱暴走反応抑止 / 担持ニッケル触媒 / バナジウム添加物 / CO水素化 / CO2水素化 / 水素製造精製反応 / CO水素化反応 / CO2水素化反応 / 担持金属触媒 / 添加物 / 熱暴走反応抑制 |
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| Outline of Final Research Achievements |
In order to avoid a thermal runaway of a catalytic reaction, a catalyst with self-controlling function for the suppression of undesired reaction was investigated. Residual chlorine on alumina-supported nickel catalysts significantly suppressed CO2 methanation and the reverse water gas-shift reaction in the course of selective CO methanation. FT-IR measurements revealed that chlorine suppressed the dissociation of CO2 on the catalyst surface. Also, vanadium was effective for the selectivity control. A mesoporous silica-coated Ni/alumina-based catalyst was developed for the further development of the suppression of the thermal runaway reaction. The catalytic activity and CO removal ability of the Ni/AlVOx catalyst were significantly improved by the coating of mesoporous silica on the Ni/AlVOx. The Ni-V species transported from the Ni/AlVOx to the coating layer may also act as active sites for CO methanation.
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