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Catalysis mechanisms of solid acids in water

Research Project

Project/Area Number 24560949
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionKochi University

Principal Investigator

ONDA Ayumu  高知大学, 教育研究部総合科学系, 講師 (80335918)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords固体酸 / 加水分解 / 多糖 / 単糖 / 水中 / 水熱反応 / スルホ基 / 炭素 / 固体酸触媒 / バイオマス / 強酸性イオン交換樹脂 / 水溶媒 / 1固体酸触媒 / セルロース
Outline of Final Research Achievements

The purpose of this study was to clarify the catalysis mechanism of carbon solid acid catalysts with sulfo groups in hot water. And, based on the obtained results, it was aimed new design of the higher active catalysts than previous catalysts. We examined the relationships between structure and catalytic properties of various solid acids with sulfo groups and sulfonic acid compounds. The results implied that carbonaceous materials are appropriate as the supports and chain sulfonic acid compound groups are effective in hydrolysis of polysaccharides in hot water.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (24 results)

All 2014 2013 2012

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (13 results) (of which Invited: 1 results) Book (1 results)

  • [Journal Article] New extraction procedure for protonated polyoxometalates prepared in aqueous-organic solution and characterisation of their catalytic ability2014

    • Author(s)
      Ueda, T., Yamashita, K., Onda, A.
    • Journal Title

      Appl. Catal., A

      Volume: 485 Pages: 181-187

    • DOI

      10.1016/j.apcata.2014.07.032

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrolysis of green-tide forming Ulva spp. by microwave irradiation with polyoxometalate2014

    • Author(s)
      Tsubaki, S., Oono K., Ueda, T., Onda, A., Yanagisawa, K., Azuma, J.
    • Journal Title

      Green Chem.

      Volume: 16 Issue: 4 Pages: 2227-2233

    • DOI

      10.1039/c3gc42027b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective conversion of lactic acid into acrylic acid over hydroxyapatite catalysts2014

    • Author(s)
      Matsuura, Y., Onda, A., Yanagisawa, K.
    • Journal Title

      Catal. Comm.

      Volume: 48 Pages: 5-10

    • DOI

      10.1016/j.cattod.2013.10.031

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Acrylic acid synthesis from lactic acid over hydroxyapatite catalysts with various cations and anions2014

    • Author(s)
      Matsuura, Y., Onda, A., Ogo, S., Yanagisawa, K.
    • Journal Title

      Catal. Today

      Volume: 226 Pages: 192-197

    • DOI

      10.1016/j.catcom.2014.01.009

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microwave-assisted hydrolysis of polysaccharides over polyoxometalate clusters2013

    • Author(s)
      Tsubaki, S., Oono, K., Ueda, T., Onda, A., Yanagisawa, K., Mitani, T., Azuma, J.
    • Journal Title

      Bioresour. Technol.

      Volume: 144 Pages: 67-73

    • DOI

      10.1016/j.biortech.2013.06.092

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Comparative decomposition kinetics of neutral monosaccharides by microwave and induction heating treatments2013

    • Author(s)
      Tsubaki, S., Oono, K., Onda, A., Yanagisawa, K., Azuma, J.
    • Journal Title

      Crobohydr. Res.

      Volume: 375 Pages: 1-4

    • DOI

      10.1016/j.carres.2013.04.013

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Comparison of Chemical Interactions with Li+ and Catalytic Reactivity of Electrochemically Generated [FeIClL]2- and [CoIL]- Complexes (L = salen or salophen)2013

    • Author(s)
      Ueda, T., Inazuma, N., Yasuzawa, H., Komatsu, D., Yasuzawa, K., Onda, A., Guo, S. Bond, A.M.
    • Journal Title

      Dalton Trans.

      Volume: 42 Issue: 31 Pages: 11146-11154

    • DOI

      10.1039/c3dt50233c

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] ゼオライト触媒によるバイオマス由来化合物の変換2013

    • Author(s)
      恩田歩武
    • Journal Title

      工業材料

      Volume: 61 Pages: 26-29

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Selective Hydrolysis of Cellulose and Polysaccharides into Sugars by Catalytic Hydrothermal Method Using Sulfonated Activated-carbon2012

    • Author(s)
      Onda, Ayumu
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 55 Issue: 2 Pages: 73-86

    • DOI

      10.1627/jpi.55.73

    • NAID

      10030934578

    • ISSN
      1346-8804, 1349-273X
    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Microwave-assisted hydrothermal hydrolysis of cellobiose and effects of additions of halide salts2012

    • Author(s)
      Tsubaki, Shuntaro; Oono, Kiriyo; Onda, Ayumu; Yanagisawa, Kazumichi; Azuma, Jun-ichi
    • Journal Title

      Bioresource Technology

      Volume: 123 Pages: 703-706

    • DOI

      10.1016/j.biortech.2012.07.086

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 大型緑藻類からの硫酸化多糖のマイクロ波支援抽出2014

    • Author(s)
      椿俊太郎, 平岡雅規, 恩田歩武
    • Organizer
      第8回日本電磁波エネルギー応用学会シンポジウム
    • Place of Presentation
      高知会館, 高知
    • Year and Date
      2014-11-17 – 2014-11-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] A noble ceramics powder prepration technique in super heated water vapor2014

    • Author(s)
      Yanagisawa, K., Kozawa, T., Onda, A.
    • Organizer
      The 4thInternational Solvothermal and Hydrothermal Association Conference
    • Place of Presentation
      Bordeaux, France
    • Year and Date
      2014-10-26 – 2014-10-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ハイドロキシアパタイト表面の酸塩基性評価2014

    • Author(s)
      恩田歩武,別宮恭平,松浦由美子,小河脩平,柳澤和道
    • Organizer
      第24回無機リン化学討論会
    • Place of Presentation
      高知会館, 高知
    • Year and Date
      2014-09-25 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Microwave-assisted hydrothermal hydrolysis of algal biomass2014

    • Author(s)
      Tsubaki, S., Hiraoka, M., Onda, A., Ueda, T.
    • Organizer
      Gordon Research Conference (Green Chemistry, 2014)
    • Place of Presentation
      Hong Kong, China
    • Year and Date
      2014-07-27 – 2014-08-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] Acrylic acid production from lactic acid by gas phase dehydration using hydroxyapatite catalysts2014

    • Author(s)
      Onda, A., Matsuura Y., Ogo, S., Yanagisawa, K.
    • Organizer
      TOCAT 7
    • Place of Presentation
      京都テルサ, 京都
    • Year and Date
      2014-07-01 – 2014-07-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Acrylic acid production from lactic acid over hydroxyapatite catalysts2013

    • Author(s)
      Onda, A.
    • Organizer
      The 15th Asian Chemical Congress
    • Place of Presentation
      Singapore, Singapore
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Conversion of ethanol into 1-butanol over strontium phosphate apatite catalysts2013

    • Author(s)
      Onda, A., Ogo, S., Iwasa, Y., Matsuura, Y., Yanagisawa, K.
    • Organizer
      7 th International Symposium on Acid-Base Catalysis
    • Place of Presentation
      Shinagawa Goos, Tokyo
    • Related Report
      2013 Research-status Report
  • [Presentation] Selective Conversion of Lactic acid into Acrylic acid over Hydroxyapatite Catalysts2013

    • Author(s)
      Matsuura, Y., Onda, A., Ogo, S., Yanagisawa, K.
    • Organizer
      7 th International Symposium on Acid-Base Catalysis
    • Place of Presentation
      Shinagawa Goos, Tokyo
    • Related Report
      2013 Research-status Report
  • [Presentation] Lactic Acid Conversion into Acrylic Acid over Sodium Nitrate Supported Catalysts2013

    • Author(s)
      Matsuura, Y., Onda, A., Yanagisawa, K.
    • Organizer
      The 14 th Japan-Korea Symposium on Catalysis
    • Place of Presentation
      Winc Aichi, Ngoya
    • Related Report
      2013 Research-status Report
  • [Presentation] Rapid hydrolysis of Ulva spp. by microwave irradiation with polyoxometalate cluster2013

    • Author(s)
      Tsubaki, S., Hiraoka, M., Ueda, T., Onda A., Azuma, J.
    • Organizer
      3rd International Conference on Algal Biomass, Biofuels & Bioproducts
    • Place of Presentation
      Toronto, Canada
    • Related Report
      2013 Research-status Report
  • [Presentation] Selective hydrolysis of cellulose into glucose by new methods using water vapor2012

    • Author(s)
      Onda, A., Iida, Y., Yanagisawa, K.
    • Organizer
      The 15th International Conference on Catalysis
    • Place of Presentation
      Munich, Germany
    • Related Report
      2012 Research-status Report
  • [Presentation] Hydration of microcrystalline cellulose into glucose under steam with vapor catalysts2012

    • Author(s)
      Onda, A., Iida, Y., Yamada, T., Tsubaki, S., Yanagisawa, K.
    • Organizer
      CAT4BIO post-satellite conference of the 15th International Congress on Catalysis 2012
    • Place of Presentation
      Thessaloniki, Grece
    • Related Report
      2012 Research-status Report
  • [Presentation] スルホ基を有する固体酸の水溶液中での触媒活性比較2012

    • Author(s)
      恩田歩武, 中村慎二郎, 山川晃弘, 柳澤和道
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学(福岡県)
    • Related Report
      2012 Research-status Report
  • [Book] “Application of Hydrothermal Reactions to Biomass Conversions, Chapter 4: Production of Lactic acid from Sugars by Homogeneous and Heterogeneous Catalysts”, Ed. F. Jin2014

    • Author(s)
      Onda, A.
    • Total Pages
      409
    • Publisher
      Springer
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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