Catalysis mechanisms of solid acids in water

• Project/Area Number: 24560949
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Catalyst/Resource chemical process
• Research Institution: Kochi University
• Principal Investigator: ONDA Ayumu 高知大学, 教育研究部総合科学系, 講師 (80335918)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000); Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: 固体酸 / 加水分解 / 多糖 / 単糖 / 水中 / 水熱反応 / スルホ基 / 炭素 / 固体酸触媒 / バイオマス / 強酸性イオン交換樹脂 / 水溶媒 / 1固体酸触媒 / セルロース

Outline of Final Research Achievements

The purpose of this study was to clarify the catalysis mechanism of carbon solid acid catalysts with sulfo groups in hot water. And, based on the obtained results, it was aimed new design of the higher active catalysts than previous catalysts. We examined the relationships between structure and catalytic properties of various solid acids with sulfo groups and sulfonic acid compounds. The results implied that carbonaceous materials are appropriate as the supports and chain sulfonic acid compound groups are effective in hydrolysis of polysaccharides in hot water.

Research Products

• [Journal Article] New extraction procedure for protonated polyoxometalates prepared in aqueous-organic solution and characterisation of their catalytic ability (2014)
  • Author(s): Ueda, T., Yamashita, K., Onda, A.
  • Journal Title: Appl. Catal., A Volume: 485 Pages: 181-187
  • DOI: 10.1016/j.apcata.2014.07.032
  • Peer Reviewed
• [Journal Article] Hydrolysis of green-tide forming Ulva spp. by microwave irradiation with polyoxometalate (2014)
  • Author(s): Tsubaki, S., Oono K., Ueda, T., Onda, A., Yanagisawa, K., Azuma, J.
  • Journal Title: Green Chem. Volume: 16 Issue: 4 Pages: 2227-2233
  • DOI: 10.1039/c3gc42027b
  • Peer Reviewed
• [Journal Article] Selective conversion of lactic acid into acrylic acid over hydroxyapatite catalysts (2014)
  • Author(s): Matsuura, Y., Onda, A., Yanagisawa, K.
  • Journal Title: Catal. Comm. Volume: 48 Pages: 5-10
  • DOI: 10.1016/j.cattod.2013.10.031
  • Peer Reviewed
• [Journal Article] Acrylic acid synthesis from lactic acid over hydroxyapatite catalysts with various cations and anions (2014)
  • Author(s): Matsuura, Y., Onda, A., Ogo, S., Yanagisawa, K.
  • Journal Title: Catal. Today Volume: 226 Pages: 192-197
  • DOI: 10.1016/j.catcom.2014.01.009
  • Peer Reviewed
• [Journal Article] Microwave-assisted hydrolysis of polysaccharides over polyoxometalate clusters (2013)
  • Author(s): Tsubaki, S., Oono, K., Ueda, T., Onda, A., Yanagisawa, K., Mitani, T., Azuma, J.
  • Journal Title: Bioresour. Technol. Volume: 144 Pages: 67-73
  • DOI: 10.1016/j.biortech.2013.06.092
  • Peer Reviewed
• [Journal Article] Comparative decomposition kinetics of neutral monosaccharides by microwave and induction heating treatments (2013)
  • Author(s): Tsubaki, S., Oono, K., Onda, A., Yanagisawa, K., Azuma, J.
  • Journal Title: Crobohydr. Res. Volume: 375 Pages: 1-4
  • DOI: 10.1016/j.carres.2013.04.013
  • Peer Reviewed
• [Journal Article] Comparison of Chemical Interactions with Li+ and Catalytic Reactivity of Electrochemically Generated [FeIClL]2- and [CoIL]- Complexes (L = salen or salophen) (2013)
  • Author(s): Ueda, T., Inazuma, N., Yasuzawa, H., Komatsu, D., Yasuzawa, K., Onda, A., Guo, S. Bond, A.M.
  • Journal Title: Dalton Trans. Volume: 42 Issue: 31 Pages: 11146-11154
  • DOI: 10.1039/c3dt50233c
  • Peer Reviewed
• [Journal Article] ゼオライト触媒によるバイオマス由来化合物の変換 (2013)
  • Author(s): 恩田歩武
  • Journal Title: 工業材料 Volume: ６１ Pages: 26-29
  • Peer Reviewed
• [Journal Article] Selective Hydrolysis of Cellulose and Polysaccharides into Sugars by Catalytic Hydrothermal Method Using Sulfonated Activated-carbon (2012)
  • Author(s): Onda, Ayumu
  • Journal Title: Journal of the Japan Petroleum Institute Volume: 55 Issue: 2 Pages: 73-86
  • DOI: 10.1627/jpi.55.73
  • NAID: 10030934578
  • ISSN: 1346-8804, 1349-273X
  • Peer Reviewed
• [Journal Article] Microwave-assisted hydrothermal hydrolysis of cellobiose and effects of additions of halide salts (2012)
  • Author(s): Tsubaki, Shuntaro; Oono, Kiriyo; Onda, Ayumu; Yanagisawa, Kazumichi; Azuma, Jun-ichi
  • Journal Title: Bioresource Technology Volume: 123 Pages: 703-706
  • DOI: 10.1016/j.biortech.2012.07.086
  • Peer Reviewed
• [Presentation] 大型緑藻類からの硫酸化多糖のマイクロ波支援抽出 (2014)
  • Author(s): 椿俊太郎, 平岡雅規, 恩田歩武
  • Organizer: 第8回日本電磁波エネルギー応用学会シンポジウム
  • Place of Presentation: 高知会館, 高知
  • Year and Date: 2014-11-17 – 2014-11-18
• [Presentation] A noble ceramics powder prepration technique in super heated water vapor (2014)
  • Author(s): Yanagisawa, K., Kozawa, T., Onda, A.
  • Organizer: The 4thInternational Solvothermal and Hydrothermal Association Conference
  • Place of Presentation: Bordeaux, France
  • Year and Date: 2014-10-26 – 2014-10-29
• [Presentation] ハイドロキシアパタイト表面の酸塩基性評価 (2014)
  • Author(s): 恩田歩武，別宮恭平，松浦由美子，小河脩平，柳澤和道
  • Organizer: 第24回無機リン化学討論会
  • Place of Presentation: 高知会館, 高知
  • Year and Date: 2014-09-25 – 2014-09-26
• [Presentation] Microwave-assisted hydrothermal hydrolysis of algal biomass (2014)
  • Author(s): Tsubaki, S., Hiraoka, M., Onda, A., Ueda, T.
  • Organizer: Gordon Research Conference (Green Chemistry, 2014)
  • Place of Presentation: Hong Kong, China
  • Year and Date: 2014-07-27 – 2014-08-01
• [Presentation] Acrylic acid production from lactic acid by gas phase dehydration using hydroxyapatite catalysts (2014)
  • Author(s): Onda, A., Matsuura Y., Ogo, S., Yanagisawa, K.
  • Organizer: TOCAT 7
  • Place of Presentation: 京都テルサ, 京都
  • Year and Date: 2014-07-01 – 2014-07-05
• [Presentation] Acrylic acid production from lactic acid over hydroxyapatite catalysts (2013)
  • Author(s): Onda, A.
  • Organizer: The 15th Asian Chemical Congress
  • Place of Presentation: Singapore, Singapore
  • Invited
• [Presentation] Conversion of ethanol into 1-butanol over strontium phosphate apatite catalysts (2013)
  • Author(s): Onda, A., Ogo, S., Iwasa, Y., Matsuura, Y., Yanagisawa, K.
  • Organizer: 7 th International Symposium on Acid-Base Catalysis
  • Place of Presentation: Shinagawa Goos, Tokyo
• [Presentation] Selective Conversion of Lactic acid into Acrylic acid over Hydroxyapatite Catalysts (2013)
  • Author(s): Matsuura, Y., Onda, A., Ogo, S., Yanagisawa, K.
  • Organizer: 7 th International Symposium on Acid-Base Catalysis
  • Place of Presentation: Shinagawa Goos, Tokyo
• [Presentation] Lactic Acid Conversion into Acrylic Acid over Sodium Nitrate Supported Catalysts (2013)
  • Author(s): Matsuura, Y., Onda, A., Yanagisawa, K.
  • Organizer: The 14 th Japan-Korea Symposium on Catalysis
  • Place of Presentation: Winc Aichi, Ngoya
• [Presentation] Rapid hydrolysis of Ulva spp. by microwave irradiation with polyoxometalate cluster (2013)
  • Author(s): Tsubaki, S., Hiraoka, M., Ueda, T., Onda A., Azuma, J.
  • Organizer: 3rd International Conference on Algal Biomass, Biofuels & Bioproducts
  • Place of Presentation: Toronto, Canada
• [Presentation] Selective hydrolysis of cellulose into glucose by new methods using water vapor (2012)
  • Author(s): Onda, A., Iida, Y., Yanagisawa, K.
  • Organizer: The 15th International Conference on Catalysis
  • Place of Presentation: Munich, Germany
• [Presentation] Hydration of microcrystalline cellulose into glucose under steam with vapor catalysts (2012)
  • Author(s): Onda, A., Iida, Y., Yamada, T., Tsubaki, S., Yanagisawa, K.
  • Organizer: CAT4BIO post-satellite conference of the 15th International Congress on Catalysis 2012
  • Place of Presentation: Thessaloniki, Grece
• [Presentation] スルホ基を有する固体酸の水溶液中での触媒活性比較 (2012)
  • Author(s): 恩田歩武, 中村慎二郎, 山川晃弘, 柳澤和道
  • Organizer: 第110回触媒討論会
  • Place of Presentation: 九州大学（福岡県）
• [Book] “Application of Hydrothermal Reactions to Biomass Conversions, Chapter 4: Production of Lactic acid from Sugars by Homogeneous and Heterogeneous Catalysts”, Ed. F. Jin (2014)
  • Author(s): Onda, A.
  • Total Pages: 409
  • Publisher: Springer