Synthesis of High-qulailty Vehicle Fuel by Nanostructured Catalysts via BTL Process at Low Pressure
| Project/Area Number |
24560950
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | The University of Kitakyushu |
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Principal Investigator |
LI XIAOHONH 北九州市立大学, 国際環境工学部, 教授 (30326459)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | ＢＴＬ / ナノ構造触媒 / ＦＴ合成 / 触媒設計 / プロセス設計 / BTL / FT合成 / 三元ハイブリッド触媒 / WGS触媒 / エッグシェル型触媒 / ナノ構造 / F・T合成 / 水素化分解 |
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| Outline of Final Research Achievements |
The effects of metal species in a Fe-based catalyst on structural properties were investigated through the synthesis of Fe-based catalysts containing various metal species such as Mn, Zr and Ce. The addition of the metal species to the Fe-based catalyst resulted in high dispersions of the Fe species and high surface areas due to the formation of mesoporous voids about 2-4 nm surrounded by the catalyst particles. The metal-added Fe-based catalysts were employed together with Co-loaded beta zeolite for the synthesis of hydrocarbons from syngas with a lower H2/CO ratio of 1 than the stoichiometric H2/CO ratio of 2 for the Fischer-Tropsch synthesis (FTS). Among the catalysts, the Mn-added Fe-based catalyst exhibited a high activity for the water-gas shift (WGS) reaction with a comparative durability, leading to the enhancement of the CO hydrogenation in the FTS in comparison with Co-loaded beta zeolite alone.
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Report
(4 results)
Research Products
(43 results)
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[Journal Article] Catalyst of Palladium Supported on H-Beta Zeolite with Nanosized Al<sub>2</sub>O<sub>3</sub> for Isomerization of <i>n</i>-Heptane2012
Author(s)
Kimura, T., Suezaki, C., Sakashita, K., Li, X., Asaoka, S
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Journal Title
Journal of the Japan Petroleum Institute
Volume: 55
Issue: 2
Pages: 99-107
DOI
NAID
ISSN
1346-8804, 1349-273X
Related Report
Peer Reviewed
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[Journal Article] Catalyst of Palladium Supported on H-Beta Zeolite with Nanosized Al<sub>2</sub>O<sub>3</sub> for Isomerization of <i>n</i>-Hexane2012
Author(s)
Kimura, T., Gao, J., Sakashita, K., Li, X., Asaoka, S.
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Journal Title
Journal of the Japan Petroleum Institute
Volume: 55
Issue: 1
Pages: 40-50
DOI
NAID
ISSN
1346-8804, 1349-273X
Related Report
Peer Reviewed
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