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Preparation of porous adsorbents for tritium enrichment from tritiated water

Research Project

Project/Area Number 24561021
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nuclear fusion studies
Research InstitutionUniversity of Toyama

Principal Investigator

TAGUCHI Akira  富山大学, 水素同位体科学研究センター, 講師 (40401799)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsメソ多孔体 / トリチウム / 吸着・濃縮 / 回収 / 濃縮
Outline of Final Research Achievements

Mesoporous silica (SBA-15) were modified by -COOH, -SO3H and -NH2 groups and their tritium adsorption ability from tritiated water under solid-liquid sorption at 5 centigrade was investigated. The separation factor of SBA-COOH, SBA-SO3H, SBA-NH2 and bare-SBA were found to be 1.17, 1.17, 1.18 and 1.21, respectively. On the other hand, by the desorption from these adsorbents up to 250 centigrade using 176.5 kBq/mL of tritiated water, the concentration of resultant tritiated water was 84.0, 202.8, 213.8 and 182.6 kBq/mL, respectively. The SBA-SO3H, SBA-NH2 and bare-SBA showed higher tritium concentration than initial one. Also, tritium concentration from SBA-SO3H and SBA-NH2 showed larger value than that from bare-SBA. These SBA-SO3H and SBA-NH2 are found to be effective for enrichment of tritiated water.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (10 results)

All 2015 2014 2013 2012

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (6 results)

  • [Journal Article] Tritium removal from tritiated water by organic functionalized SBA-152015

    • Author(s)
      Akira Taguchi, Yuki Kato, Rie Akai, Yuji Torikai, Masao Matsuyama
    • Journal Title

      Fusion Science and Technology

      Volume: 67 Issue: 3 Pages: 592-595

    • DOI

      10.13182/fst14-t87

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tritium Removal from Tritiated Water by Organic Functionalized SBA-152014

    • Author(s)
      A. Taguchi, Y. Kato, R. Akai, Y. Torikai, M. Matsuyama
    • Journal Title

      Fusion Science and Technology

      Volume: accepted

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enrichment of Tritiated Water Using Mesoporous Silica2013

    • Author(s)
      A. Taguchi, Y. Kato, Y. Torikai, M. Matsuyama, S. Uchida
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 179 Pages: 217233-217233

    • DOI

      10.1016/j.micromeso.2013.05.031

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Desorption of tritiated water from reused MCM-412013

    • Author(s)
      Akira Taguchi, Yuji Torikai, Masao Matsuyama
    • Journal Title

      水素同位体科学研究センター 研究報告

      Volume: 32

    • NAID

      120005286442

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Desorption and Enrichment of Tritiated Water on Organic Functionalized SBA-152015

    • Author(s)
      Akira Taguchi, Yuki Kato, Yuji Torikai
    • Organizer
      International Symposium on Zeolite and Microporous Crystals 2015 (ZMPC2015)
    • Place of Presentation
      札幌
    • Year and Date
      2015-06-28 – 2015-07-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] Reuse of MCM-41 for enrichment of tritiated water2013

    • Author(s)
      A. Taguchi, Y. Torikai, M. Matsuyama
    • Organizer
      8th International Mesostructured Materials Symposium (IMMS2013)
    • Place of Presentation
      兵庫
    • Related Report
      2013 Research-status Report
  • [Presentation] Tritium Removal from Tritiated Water by Organic-Functionalized SBA-152013

    • Author(s)
      A. Taguchi, Y. Kato, Y. Torikai, M. Matsuyama
    • Organizer
      10th International Conference on Tritium Science and Technology (TRITIUM 2013)
    • Place of Presentation
      ニース(フランス)
    • Related Report
      2013 Research-status Report
  • [Presentation] MCM-41からのトリチウム水の脱着2013

    • Author(s)
      田口 明,鳥養祐二,松山政夫
    • Organizer
      日本原子力学会「2013年春の年会」
    • Place of Presentation
      近畿大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Reuse of MCM-41 for enrichment of tritiated water2013

    • Author(s)
      A. Taguchi, Y. Torikai, M. Matsuyama
    • Organizer
      8th International Mesostructured Materials Symposium
    • Place of Presentation
      兵庫
    • Related Report
      2012 Research-status Report
  • [Presentation] Enrichment of Tritiated Water using Mesoporous Silica2012

    • Author(s)
      A. Taguchi, Y. Torikai, M. Matsuyama
    • Organizer
      International Symposium on Zeolites and Microporous Crystals (ZMPC2012)
    • Place of Presentation
      広島
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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