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Study of a self-radiolysis reaction of concentrated tritiated water by using spectroscopictechnique

Research Project

Project/Area Number 24561022
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nuclear fusion studies
Research InstitutionUniversity of Toyama

Principal Investigator

KOBAYASHI Kaori  富山大学, 大学院理工学研究部(理学), 准教授 (80397166)

Co-Investigator(Kenkyū-buntansha) HARA Masanori  富山大学, 水素同位体科学研究センター, 准教授 (00334714)
OZEKI Hiroyuki  東邦大学, 理学部, 教授 (70260031)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords核融合 / トリチウム / 近赤外分光 / トリチウム水 / 分子分光 / 物理化学 / 放射線 / 分子分光学
Outline of Final Research Achievements

Tritium, when it is released to air, is said to be converted to tritiated water. We prepared a 1 m stainless double-walled cell and prepared a highly concentrated tritiated water that is necessary for the spectroscopic measurement. The near-infrared laser spectroscopy technique was applied to obtain the spectral information and assigned spectral lines based on the quantum chemical calculations. Two diode lasers were used to cover the two wavelength region about 1.38 micron and 1.45 micron. Including the information of the change in pressure, self-radiolysis reaction of the tritiated water due to the tritium's radioactivity was investigated.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (5 results)

All 2014 2013 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (4 results)

  • [Journal Article] Analysis of a tritium enhanced water spectrum between 7200 – 7245 cm-1 using new variational calculations2013

    • Author(s)
      M. J. Down, J. Tennyson, M. Hara, Y. Hatano, and K. Kobayashi
    • Journal Title

      Journal of Molecular Spectroscopy

      Volume: 289 Pages: 35-40

    • DOI

      10.1016/j.jms.2013.05.016

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 1.45 ミクロン帯のトリチウム水の分光研究2014

    • Author(s)
      齋藤萌美
    • Organizer
      2014年度日本物理学会北陸支部定例学術講演会
    • Place of Presentation
      福井大学
    • Year and Date
      2014-12-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] ANALYSIS OF 2ν3 BAND OF HTO2014

    • Author(s)
      小林かおり
    • Organizer
      International Symposium on Molecular Spectroscopy, 69th meeting
    • Place of Presentation
      University of Illinois, Urbana-Champaign
    • Year and Date
      2014-06-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] トリチウム水の近赤外分光データの解析

    • Author(s)
      槇 泰喜、山本 拓也、小林 かおり、原 正憲、波多野 雄治
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] トリチウム水の高分解能分光のための二重管セルの作製

    • Author(s)
      小林かおり、槇 泰喜、山本 拓也、原正憲、波多野雄治、尾関博之
    • Organizer
      日本原子力学会2014年春の年会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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