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Study on the mechanisms of radiocesium sorption/desorption on soil containing waste: Effects of organic matter through experimental and MD approaches

Research Project

Project/Area Number 24561036
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nuclear engineering
Research InstitutionHokkaido University

Principal Investigator

WATANABE Naoko  北海道大学, 工学(系)研究科(研究院), 准教授 (20624711)

Co-Investigator(Kenkyū-buntansha) KOZAKI Tamotsu  北海道大学, 工学研究院, 教授 (60234746)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords放射性セシウム / 土壌 / 収脱着 / MD計算 / 有機物
Outline of Final Research Achievements

To gain understanding on the long-term stability of the soil waste containing radiocesium for interim storage and disposal, effects of organic matter on the interaction between clay mineral surfaces and Cs were studied. Different sorption sites on mineral surfaces, including planar and interlayer surfaces as well as edges, were assumed to model the sorption experiment results to obtain the results that each site is affected differently by the presence of organic matter in the solution phase: sorption capacity of the interlayer sites of montmorillonite decreased with the presence of humic acid, and the selectivity on the illite FES site increased with the presence of fulvic acid. In addition, molecular dynamics simulation revealed the structure of a very strong innersphere complex formed at K-mica edges.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (5 results)

All 2014 2013 2012

All Presentation (5 results)

  • [Presentation] アルカリ金属を用いたイオン交換による福島土壌からの放射性セシウム脱離2014

    • Author(s)
      松木晃大,渡辺 直子,小崎 完
    • Organizer
      日本原子力学会春の年
    • Place of Presentation
      東京都市大学(東京都世田谷区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 福島土壌からのカリウムイオン及び塩酸によるセシウムの脱離2013

    • Author(s)
      松木晃大,大熊 成地,渡辺 直子,小崎 完,田中 真悟,佐藤 治夫,青木 和弘
    • Organizer
      日本原子力学会春の年会 学生企画セッション
    • Place of Presentation
      近畿大学(大阪府東大阪市)
    • Related Report
      2012 Research-status Report
  • [Presentation] 福島土壌への放射性核種の収着に及ぼす塩濃度影響2013

    • Author(s)
      大熊成地,知場一訓,渡辺直子,小崎完,田中真悟,佐藤治夫,青木和弘
    • Organizer
      日本原子力学会春の年会
    • Place of Presentation
      近畿大学(大阪府東大阪市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Molecular dynamics simulations of Cs adsorption at the pyrophyllite edge2012

    • Author(s)
      Aric Newton, Garrison Sposito, Naoko Watanabe, Tamotsu Kozaki, Seichi Sato
    • Organizer
      日本原子力学会秋の年会
    • Place of Presentation
      広島大学(広島県東広島市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Effects of electrolyte concentrations on radionuclides sorption by Fukushima and Hokkaido soils2012

    • Author(s)
      S. Okuma, T. Chiba, N. Watanabe, T. Kozaki, S. Sato
    • Organizer
      Clays in Natural and Engineered Barriers for Radioactive Waste Confinement
    • Place of Presentation
      Le Corum( France)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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