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Synthesis of Ionic Liquid Crystals Based on Organouranium Interaction

Research Project

Project/Area Number 24561046
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nuclear engineering
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

AOYAGI Noboru  独立行政法人日本原子力研究開発機構, 原子力科学研究部門 原子力基礎工学研究センター, 研究員 (80446400)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywordsウラン錯体 / レーザー分光 / イオン液体 / 有機アクチノイド / ウラン / イオン液晶 / 重金属錯体 / 機能材料
Outline of Final Research Achievements

Synthesis and photo-physical properties of uranium-containing ionic liquids based on the interaction among unanium-nitrogen donors are studied. The uranium tetrahalides (UX4) were obtained by the reaction of uranium oxides with vapor CCl4 and corresponding materials at the elevated temperature, affording colored powders such as light blue (UF4), green (UCl4), dark green (UBr4), and dark purple (UI4). The dissolution of these compounds in organic solvents or ionic liquids enables us to make in-depth understanding of luminescence of U(IV) complexes in solutions by UV-Vis-NIR absorption spectroscopy and time-resolved laser-induced fluorescence spectroscopy (TRLFS). Remarkable differences of photo-properties were found in ionic liquids other than organic solvents.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (27 results)

All 2015 2014 2013 2012 Other

All Journal Article (10 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 1 results) Presentation (13 results) (of which Invited: 1 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Photophysical property of catena-bis(thiocyanato)aurate(I) complexes in ionic liquids2015

    • Author(s)
      Noboru Aoyagi, Yusuke Shinha, Atsushi Ikeda-Ohno, Yoshinori Haga, Kojiro Shimojo, Neil R. Brooks, Akira Izuoka, Hirochika Naganawa, Takaumi Kimura, Koen Binnemans
    • Journal Title

      Crystal Growth & Design

      Volume: 15 Issue: 3 Pages: 1422-1429

    • DOI

      10.1021/cg501792m

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Optical properties of tetravalent uranium complexes in non-aqueous media2015

    • Author(s)
      Noboru Aoyagi, Masayuki Watanabe, Akira Kirishima, Nobuaki Sato, Takaumi Kimura
    • Journal Title

      Journal of Radioanalytical and Nuclear Chemistry

      Volume: 303 Issue: 2 Pages: 1095-1098

    • DOI

      10.1007/s10967-014-3616-x

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Efficient Extraction Separation of Lanthanides Using a Diglycolamic Acid Extractant2014

    • Author(s)
      K. Shimojo, N. Aoyagi, T. Saito, F. Kubota, M. Goto, H. Naganawa
    • Journal Title

      Analytical Sciences

      Volume: 30 Issue: 2 Pages: 263-269

    • DOI

      10.2116/analsci.30.263

    • NAID

      130004442263

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 六フッ化ウランの安定化処理について2014

    • Author(s)
      伊奈川潤,宝徳 忍、小田 哲三、青柳 登、間柄 正明
    • Journal Title

      JAEA-Technology

      Volume: 007 Pages: 1-48

    • Related Report
      2013 Research-status Report
  • [Journal Article] レーザー分光を用いたアクチノイドの状態分析2013

    • Author(s)
      青柳 登,斉藤 拓巳,木村 貴海
    • Journal Title

      ぶんせき

      Volume: 9 Pages: 536-542

    • NAID

      10031196112

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Luminescence and Potentiometric Studies on the Complexation of Europium(III) by Picolinate in an Aqueous Solution2012

    • Author(s)
      N. Aoyagi, T. Toraishi, S. Nagasaki, S. Tanaka
    • Journal Title

      Journal of Applied Solution Chemistry and Modeling

      Volume: 1 Issue: 2 Pages: 146-155

    • DOI

      10.6000/1929-5030.2012.01.02.11

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Specific Cooperative Effect of a Macrocyclic Receptor for Metal Ion Transfer into an Ionic Liquid2012

    • Author(s)
      Hiroyuki Okamura
    • Journal Title

      Analytical Chemistry

      Volume: 84 Issue: 21 Pages: 9332-9339

    • DOI

      10.1021/ac302015h

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Surface speciation of Eu^<3+> adsorbed on kaoli nite by time-resolved laser fluorescence spectroscopy(TRLFS) and parallel factor analysis(PARAFAC)2012

    • Author(s)
      K. Ishida, T. Saito, N. Aoyagi, T. Kimura, R. Nagaishi, S. Nagasaki, S. Tanaka
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 374 Issue: 1 Pages: 258-266

    • DOI

      10.1016/j.jcis.2012.01.060

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Laser-induced fluorescence and infrared spectroscopic studies on the specific solvation of tris(1-(2-thienyl)-4,4,4-trifluoro-1,3-butanedionato)europium(III) in an ionic liquid2012

    • Author(s)
      Hiroyuki Okamura
    • Journal Title

      Polyhedron

      Volume: 31 Issue: 1 Pages: 748-753

    • DOI

      10.1016/j.poly.2011.10.031

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Speciation of Eu^<3+> Bound to Humic Substan ces by Time-Resolved Laser Fluorescenc Spectroscopy(TRLFS) and Parallel Factor Analysis(PARAFAC)2012

    • Author(s)
      S. Lukman, T. Saito, N. Aoyagi, T. Kimu ra, S. Nagasaki
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 88 Pages: 199-215

    • DOI

      10.1016/j.gca.2012.04.023

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Synthesis and laser spectroscopy of uranium(IV, VI) complexes in ionic liquids2014

    • Author(s)
      N. Aoyagi, M. Watanabe, T. Kimura, A. Kirishima, N. Sato
    • Organizer
      2nd International Workshop on Advanced Techniques in Actinide Spectroscopy 2014 (ATAS2014)
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2014-11-03 – 2014-11-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] ウラン化合物を含有するイオン液体の合成と分光特性2014

    • Author(s)
      青柳 登,渡邉 雅之,木村 貴海,桐島 陽,佐藤 修彰
    • Organizer
      第 58 回放射化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-09-11 – 2014-09-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Spectroscopic study on tetravalent uranium compounds in non-aqueous solutions2014

    • Author(s)
      N. AOYAGI, M. Watanabe, A. Kirishima, N. Sato, T. Kimura,
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] マイクロウェーブ(MW)照射を用いたラテント化ジケトピロロピロール類縁体の高効率合成と置換基数の蛍光特性に及ぼす影響2014

    • Author(s)
      中野将貴,大石知司,渡邉雅之,青柳登
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 希土類元素のダイヤモンドへの吸着挙動2014

    • Author(s)
      四之宮佳浩,渡邉雅之,青柳登,木村貴海
    • Organizer
      日本原子力学会2014年春の年会
    • Place of Presentation
      東京都市大学世田谷キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Spectroscopy of uranium(IV) complexes in non-aqueous media2013

    • Author(s)
      N. Aoyagi, M. Watanabe, A. Kirishima, N. Sato, T. Kimura
    • Organizer
      Specific Behavior of Anthropogenic Radionuclides at Solid Solution Interface: Implication for Migration and Remediation
    • Place of Presentation
      福島駅前 ユニックスビル
    • Related Report
      2013 Research-status Report
  • [Presentation] キラルなスチルベンジアミンから誘導した四座のシッフ塩基を配位子とするY(III), La(III), Gd(III)単核錯体の合成と発光特性2013

    • Author(s)
      鈴木かおり,槌本昌信,青柳 登,渡邉雅之,中島清彦
    • Organizer
      錯体化学討論会
    • Place of Presentation
      琉球大学 千原キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Na型モンモリロナイトに対するEu(III)の収着分配係数の測定と解釈 その22013

    • Author(s)
      上田健揚,佐々木隆之,斉藤拓巳,青柳 登,木村貴海,舘 幸男
    • Organizer
      日本原子力学会春の年会
    • Place of Presentation
      近畿大,東大阪
    • Related Report
      2012 Research-status Report
  • [Presentation] Chromic materials based on uranium2012

    • Author(s)
      N. Aoyagi, K. Shimojo, M. Watanabe, N. R. Brooks, K. Binnemans, T. Kimura
    • Organizer
      Plutonium Futures 2012
    • Place of Presentation
      Cambridge, UK
    • Related Report
      2012 Research-status Report
  • [Presentation] Application of multi-mode factor analysis as a robust data reduction tool for time-resolved laser spectroscopy2012

    • Author(s)
      T. Saito, N. Aoyagi, T. Kimura
    • Organizer
      International Workshop on Advanced Techniques in Actinide Spectroscopy (ATAS)
    • Place of Presentation
      Dresden, Germany
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 金(I)-チオシアン錯体のカートネーションと励起多量体2012

    • Author(s)
      青柳 登,榛葉祐介,池田篤史,芳賀芳範,下条晃司郎,渡邉雅之,Brooks N.R.,泉岡 明,長縄弘親,Binnemans K.,木村貴海
    • Organizer
      第24回配位化合物の光化学討論会
    • Place of Presentation
      生産研,東大駒場
    • Related Report
      2012 Research-status Report
  • [Presentation] 放射性汚染水処理における放射線効果に関する研究;(6)ゼオライト系吸着剤の表面構 造への照射効果2012

    • Author(s)
      永石隆二, 熊谷友多, 青柳 登, 山岸功, 西原健司
    • Organizer
      日本原子力学会秋の大会
    • Place of Presentation
      広島大,東広島
    • Related Report
      2012 Research-status Report
  • [Presentation] マイクロウェーブ(MW)照射を用いたラテント化ジケトピロロピロール類縁体及び含有薄膜の高効率合成と蛍光特性

    • Author(s)
      中野 将貴,大石 知司,渡邉 雅之,青柳 登
    • Organizer
      第24回日本化学会関東支部茨城地区研究交流会
    • Place of Presentation
      ワークプラザ勝田
    • Related Report
      2013 Research-status Report
  • [Book] Laser surface engineering: Processes and applications2015

    • Author(s)
      N. Aoyagi, T. Saito (Edited by J. Lawrence and D. G. Waugh)
    • Total Pages
      694
    • Publisher
      Woodhead Publishing, Ltd.
    • Related Report
      2014 Annual Research Report
  • [Book] Chapter 26 “Luminescence spectroscopy of f-block metal complexes at solid-water interfaces”, Laser surface engineering: Processes and applications2014

    • Author(s)
      Edited by: Jonathan Lawrence, Colin Dowding, David Waugh and Jonathan Griffiths
    • Total Pages
      900
    • Publisher
      Woodhead Publishing, Ltd.
    • Related Report
      2013 Research-status Report
  • [Remarks] Radiochemistry Group

    • URL

      http://nsed.jaea.go.jp/Radiochem/Welcome.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] Radiochemistry Group

    • URL

      http://nsed.jaea.go.jp/Radiochem/Welcome.html

    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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