| Project/Area Number |
24590031
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Meiji Pharmaceutical University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
|
| Project Status |
Completed (Fiscal Year 2014)
|
| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | 不斉芳香族第三アミン / 一電子移動 / 有機触媒 / 陽極酸化 / 光電子移動 / 可視光型増感剤 / ポルフィリン / ビナフチルアミン / 不斉芳香族第三級アミン / 一電子移動型不斉有機触媒 / 可視光型光増感剤 / ナフチルヒドラゾン / 無金属ポルフィリン / 官能基許容性有機マグネシウム反応剤 / 芳香族第三アミン / 不斉触媒 / 光増感剤 / 芳香族スルフィド / ビアリール / 電解合成 |
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| Outline of Final Research Achievements |
A challenge for developing triarylamine- and arylsulfide-based organocatalysts that can mediate asymmetric, one-electron transfer reactions of various organic molecules, such as alcohols and ethers is described. Among triarylamine and arylsulfide derivatives examined, triarylamines bearing chiral biaryl moieties were found to be a possible effective ‘asymmetric, one-electron transfer catalyst,’ which could mediate asymmetric oxidation of benzylethers via anodic processes. In addition to these studies, synthesis and physical properties of new porphyrin derivatives, which could be used as an efficient photosensitizer, were also explored.
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