Synthesis of redox based switching nanodevice using oxide nanowire

• Project/Area Number: 24651138
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: Osaka University
• Principal Investigator: NAGASHIMA Kazuki 大阪大学, 産業科学研究所, 助教 (10585988)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
• Keywords: 酸化物ナノワイヤ / VLS成長 / 酸化還元 / スイッチング素子 / 抵抗変化メモリ効果

Outline of Final Research Achievements

Self-assembled single crystalline oxide nanowires were successfully synthesized by understanding the underlying growth mechanism. Using the oxide nanowires, the nanoscale redox based switching devices were also demonstrated with a design rule for stable switching operation.

Research Products

• [Journal Article] A flux induced crystal phase transition in the vapor-liquid-solid growth of indium-tin oxide nanowires (2014)
  • Author(s): G. Meng et al.
  • Journal Title: Nanoscale Volume: 6 Issue: 12 Pages: 7033-7038
  • DOI: 10.1039/c4nr01016g
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Cellulose Nanofiber Paper as an Ultra Flexible Nonvolatile Memory (2014)
  • Author(s): K. Nagashima et al.
  • Journal Title: Scientific Reports Volume: 4 Issue: 1 Pages: 5532-5532
  • DOI: 10.1038/srep05532
  • NAID: 120006955452
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Scaling Effect on Unipolar and Bipolar Resistive Switching of Metal Oxides (2013)
  • Author(s): T. Yanagida
  • Journal Title: Scientific Reports Volume: 3 Issue: 1 Pages: 1657-1657
  • DOI: 10.1038/srep01657
  • Peer Reviewed
• [Journal Article] Impact of Preferential Indium Nucleation on Electrical Conductivity of VLS Grown Indium-Tin-Oixde Nanowires (2013)
  • Author(s): G. Meng
  • Journal Title: Journal of the American Chemical Society Volume: 135 Issue: 18 Pages: 7033-7038
  • DOI: 10.1021/ja401926u
  • Peer Reviewed
• [Journal Article] Advanced Photoassisted Atomic Switch Produced Using ITO Nanowire Electrodes and Molten Photoconductive Organic Semiconductor (2013)
  • Author(s): A. Klamchuen, H. Tanaka, D. Tanaka, H. Toyama, G. Meng, S. Rahong, K. Nagashima, M. Kanai, T. Yanagida, T. Kawai and T. Ogawa
  • Journal Title: Advanced Materials Volume: 25 Issue: 41 Pages: 5893-5897
  • DOI: 10.1002/adma.201302552
  • Peer Reviewed / Open Access
• [Journal Article] Carrier type dependence on spatial asymmetry of unipolar resistive switching of metal oxides (2013)
  • Author(s): K. Nagashima
  • Journal Title: Applied Physics Letters Volume: 103 Issue: 17 Pages: 173506-173506
  • DOI: 10.1063/1.4826558
  • Peer Reviewed
• [Journal Article] Crystal Plane Dependence of Critical Concentration for Nucleation on Hydrothermal ZnO Nanowires (2013)
  • Author(s): Y. HE, T. YANAGIDA, K. NAGASHIMA, F. ZHUGE, G. MENG, B. XU, A. KLAMCHUEN, S. RAHONG, M. KANAI, X. LI, M. SUZUKI, S. KAI, T. KAWAI
  • Journal Title: The Journal of Physics Chemistry C Volume: 117 Issue: 2 Pages: 1197-1203
  • DOI: 10.1021/jp3113232
  • Peer Reviewed
• [Journal Article] Pressure-induced evaporation dynamics of gold nanoparticles on oxide substrate (2013)
  • Author(s): G. MENG, T. YANAGIDA, M. KANAI, M. SUZUKI, K. NAGASHIMA, B. XU, F. ZHUGE, A. KLAMCHUEN, Y. HE, S. RAHONG, S. KAI, T. KAWAI
  • Journal Title: Physical Review E Volume: 87 Issue: 1 Pages: 12405-12405
  • DOI: 10.1103/physreve.87.012405
  • Peer Reviewed
• [Journal Article] DNA Manipulation and Separation in Sublithographic-Scale Nanowire Array (2013)
  • Author(s): Takao YASUI, Sakon RAHONG, Koki MOTOYAMA, Takeshi YANAGIDA, Qiong WU, Noritada KAJI, Masaki KANAI, Kentaro DOI, Kazuki NAGASHIMA, Masanobu TOKESHI, Masateru TANIGUCHI, Satoyuki KAWANO, Tomoji KAWAI, and Yoshinobu BABA
  • Journal Title: ACS Nano Volume: 7 Issue: 4 Pages: 3029-3035
  • DOI: 10.1021/nn4002424
  • Peer Reviewed
• [Journal Article] Facile and Scalable Methodology for Sublithographic Scale Uniform Nanowires by Ultra-Thin AAO Free-Standing Membrane (2012)
  • Author(s): G.Meng他13名
  • Journal Title: RSC Adv Volume: 2 Issue: 28 Pages: 10618-10623
  • DOI: 10.1039/c2ra21643d
  • Peer Reviewed
• [Journal Article] Prominent Thermodynamical Interaction with Surroundings on Nanoscale Memristive Switching of Metal Oxides (2012)
  • Author(s): K.Nagashima他12名
  • Journal Title: Nano Lett Volume: 12 Issue: 11 Pages: 5684-5690
  • DOI: 10.1021/nl302880a
  • Peer Reviewed
• [Journal Article] Switching Properties of Titanium Dioxide Nanowire Memristor (2012)
  • Author(s): K.Nagashima他11名
  • Journal Title: Jpn. J. Appl. Phys Volume: 51 Issue: 11S Pages: 11PE09-11PE09
  • DOI: 10.1143/jjap.51.11pe09
  • Peer Reviewed
• [Journal Article] Fundamental Strategy for Creating VLS Grown TiO2 Single Crystalline Nanowires (2012)
  • Author(s): F.Zhuge他14名
  • Journal Title: J. Phys. Chem. C Volume: 116 Issue: 45 Pages: 24367-24372
  • DOI: 10.1021/jp308945b
  • Peer Reviewed
• [Presentation] Cellulose Nanofiber Paper as an Ultra Flexible Nonvolatile Memory (2014)
  • Author(s): K. Nagashima et al.
  • Organizer: 2014 MRS Fall Meeting
  • Place of Presentation: Boston
  • Year and Date: 2014-11-30 – 2014-12-05
• [Presentation] Composition and Crystal Phase Engineering of VLS Nanowires: Impact of Element Nucleation Competitions at Liquid-Solid Interface (2014)
  • Author(s): G. Meng et al.
  • Organizer: 2014 MRS Fall Meeting
  • Place of Presentation: Boston
  • Year and Date: 2014-11-30 – 2014-12-05
• [Presentation] Doping in VLS Metal Oxide Nanowires: Manipulation of Conductivity and Crystal Phase (2014)
  • Author(s): G. Meng et al.
  • Organizer: 2014 MRS Fall Meeting
  • Place of Presentation: Boston
  • Year and Date: 2014-11-30 – 2014-12-05
• [Presentation] 単結晶ナノワイヤ構造体によるナノ物性探索 (2014)
  • Author(s): 長島 一樹
  • Organizer: 第2回アライアンス若手研究交流会
  • Place of Presentation: 大阪大学
  • Year and Date: 2014-11-26
• [Presentation] Rational Designing of Vapor-liquid-solid Oxide Nanowire Growth (2014)
  • Author(s): Annop Klamchuen et al.
  • Organizer: 第75回応用物理学会秋季学術講演会
  • Place of Presentation: 北海道大学
  • Year and Date: 2014-09-17 – 2014-09-20
• [Presentation] Single Crystalline NiO Nanowires Grown via VLS Mechanism and Their Significance on Resistive Switching Memory (2014)
  • Author(s): 長島 一樹 他
  • Organizer: 第75回応用物理学会秋季学術講演会
  • Place of Presentation: 北海道大学
  • Year and Date: 2014-09-17 – 2014-09-20
• [Presentation] Rational Concept for Designing Vapor-Liquid-Solid Growth of Metal Oxide Nanowire (2014)
  • Author(s): Annop Klamchuen et al.
  • Organizer: 第75回応用物理学会秋季学術講演会
  • Place of Presentation: 北海道大学
  • Year and Date: 2014-09-17 – 2014-09-20
• [Presentation] Rational Concept for Designing Metal Oxide Nanowires (2014)
  • Author(s): F. W. Zhuge
  • Organizer: The 17th SANKEN International Symposium 2014
  • Place of Presentation: Osaka, Japan
• [Presentation] Impact of Preferential Indium Nucleation on Electrical Conductivity of VLS Grown Indium-Tin-Oxide Nanowires (2014)
  • Author(s): G. Meng
  • Organizer: The 17th SANKEN International Symposium 2014
  • Place of Presentation: Osaka, Japan
• [Presentation] Crucial Role of Material Flux on Growth Temperature for Vapor-Liquid-Solid Oxide Nanowire Growth (2014)
  • Author(s): K. Nagashima
  • Organizer: The 17th SANKEN International Symposium 2014
  • Place of Presentation: Osaka, Japan
• [Presentation] Carrier Type Dependence on Spatial Asymmetry of Unipolar Resistive Switching of Metal Oxides (2014)
  • Author(s): K. Nagashima
  • Organizer: The 17th SANKEN International Symposium 2014
  • Place of Presentation: Osaka, Japan
• [Presentation] Flux Induced Crystal Phase Variation in Vapor-Liquid-Solid Growth of Multi-component Metal Oxide Nanowires (2014)
  • Author(s): G. Meng
  • Organizer: The 17th SANKEN International Symposium 2014
  • Place of Presentation: Osaka, Japan
• [Presentation] Fundamental Design Rule for Nanowire Alignment on Water Favorable Pattern (2014)
  • Author(s): Y. He
  • Organizer: The 17th SANKEN International Symposium 2014
  • Place of Presentation: Osaka, Japan
• [Presentation] Enhancement of thermoelectric properties via inhomogeneous radial dopant profile in Boron doped Si nanowires (2014)
  • Author(s): F. W. Zhuge
  • Organizer: The 17th SANKEN International Symposium 2014
  • Place of Presentation: Osaka, Japan
• [Presentation] ユニポーラ型酸化物抵抗変化メモリにおける伝導パス形成機構のキャリアタイプ依存性 (2014)
  • Author(s): 長島 一樹
  • Organizer: 第61回応用物理学会春季学術講演会
  • Place of Presentation: 青山学院大学, 神奈川
• [Presentation] 紙資源を利用した超フレキシブル不揮発性メモリ (2014)
  • Author(s): 長島 一樹
  • Organizer: 第61回応用物理学会春季学術講演会
  • Place of Presentation: 青山学院大学, 神奈川
• [Presentation] Size Selective Rule of Nanowire Alignment by Solution based Coating Method (2014)
  • Author(s): Yong He
  • Organizer: 第61回応用物理学会春季学術講演会
  • Place of Presentation: 青山学院大学, 神奈川
• [Presentation] Enhancement of Thermoelectric Properties via Radial Dopant Distribution in Boron-doped Silicon Nanowires (2014)
  • Author(s): Fuwei Zhuge
  • Organizer: 第61回応用物理学会春季学術講演会
  • Place of Presentation: 青山学院大学, 神奈川
• [Presentation] Flux Induced Crystal Phase Transition in Vapor-Liquid-Solid Growth of Indium-Tin Oxide Nanowires (2014)
  • Author(s): Gang Meng
  • Organizer: 第61回応用物理学会春季学術講演会
  • Place of Presentation: 青山学院大学, 神奈川
• [Presentation] Ultrafast and Wide Range Analysis of DNA Molecules Using Tunable Rigid Network Structure of Solid Nanowires (2014)
  • Author(s): Sakon Rahong
  • Organizer: 第61回応用物理学会春季学術講演会
  • Place of Presentation: 青山学院大学, 神奈川
• [Presentation] Material Design Rule for Nanoscale Memristive Switching (2013)
  • Author(s): K. Nagashima
  • Organizer: The 12th International Symposium on Sputtering & Plasma Processes
  • Place of Presentation: Kyoto, Japan
• [Presentation] Single Crystalline NiO Nanowires Grown via VLS Mechanism and Their Properties on Resistive Switching Memory (2013)
  • Author(s): K. Nagashima
  • Organizer: Material Research Society Fall Meeting 2013
  • Place of Presentation: Boston, USA
• [Presentation] Impact of Preferential Indium Nucleation on Electrical Conductivity of VLS Grown Indium-Tin-Oxide Nanowires (2013)
  • Author(s): G. Meng
  • Organizer: Material Research Society Fall Meeting 2013
  • Place of Presentation: Boston, USA
• [Presentation] 単結晶NiOナノワイヤのVLS形成における成長温度と供給フラックスの相関性 (2013)
  • Author(s): 長島 一樹
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 同志社大学, 京都
• [Presentation] Fundamental Design Rule for Precise Nanowires Positioning on Water Favorable Nano-pattern by Blade-coating Method (2013)
  • Author(s): Yong He
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 同志社大学, 京都
• [Presentation] Impact of Preferential Indium Nucleation on Electrical Conductivity of VLS Grown Indium-Tin-Oxide Nanowires (2013)
  • Author(s): Gang Meng
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 同志社大学, 京都
• [Presentation] Thermopower Factor Measurement of Single Nanowires: On the Diameter Modulation to the Seebeck Coefficient and Electrical Conductivity (2013)
  • Author(s): Fuwei Zhuge
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 同志社大学, 京都
• [Presentation] Pressure Induced Evaporation Dynamics of Gold Nanoparticles on Oxide Substrate (2013)
  • Author(s): Gang Meng
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 同志社大学, 京都
• [Presentation] VLS法により形成されたITO単結晶ナノワイヤの組成制御と輸送特性 (2013)
  • Author(s): 金井真樹
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 同志社大学, 京都
• [Presentation] Sublithographic-Scale Nanowire Array for Long DNA Manipulation and Separation (2013)
  • Author(s): Sakon Rahong
  • Organizer: 第74回応用物理学会秋季学術講演会
  • Place of Presentation: 同志社大学, 京都
• [Presentation] 紙資源を利用した折り畳める不揮発性メモリの開発 (2013)
  • Author(s): 長島 一樹
  • Organizer: 第2回ネイチャー・インダストリー・アワード～若手研究者からの発信～
  • Place of Presentation: 大阪科学技術センター, 大阪
• [Presentation] Novel Design Rule Toward Nanoscale Memristive Switching (2013)
  • Author(s): K. Nagashima
  • Organizer: The 16th SANKEN International Symposium 2013
  • Place of Presentation: Osaka, Japan
• [Presentation] Exquisite Size Control of Au Nanoparticle Arrays by Thermal Shrinking (2013)
  • Author(s): G. Meng
  • Organizer: The 16th SANKEN International Symposium 2013
  • Place of Presentation: Osaka, Japan
• [Presentation] Crystal Plane Dependence of Critical Concentration for Nucleation on Hydrothermal ZnO Nanowires (2013)
  • Author(s): Y. He
  • Organizer: The 16th SANKEN International Symposium 2013
  • Place of Presentation: Osaka, Japan
• [Presentation] Fundamental strategy for VLS grown TiO2 nanowires (2013)
  • Author(s): F. W. Zhuge
  • Organizer: The 16th SANKEN International Symposium 2013
  • Place of Presentation: Osaka, Japan
• [Presentation] Photoassisted Atomic Switch using ITO Nanowire Electrodes (2013)
  • Author(s): A. Klamchuen
  • Organizer: The 16th SANKEN International Symposium 2013
  • Place of Presentation: Osaka, Japan
• [Presentation] ナノスケールメモリスタにおける周辺雰囲気との熱力学的相互作用の重要性 (2013)
  • Author(s): 長島 一樹
  • Organizer: 分子ナノシステムの創発化学領域修了シンポジウム
  • Place of Presentation: 東京国際フォーラム
• [Presentation] 水熱合成法を用いた酸化亜鉛ナノワイヤ成長における結晶表面エネルギーの役割 (2013)
  • Author(s): 柳田 剛
  • Organizer: 化学工学会第78回年会
  • Place of Presentation: 大阪大学
• [Presentation] 陽極酸化アルミナメンブレンを用いた大面積均一ナノワイヤ成長法の開発 (2013)
  • Author(s): 長島 一樹
  • Organizer: 化学工学会第78回年会
  • Place of Presentation: 大阪大学
• [Presentation] VLS 法を用いた単結晶NiO ナノワイヤの創成および抵抗変化メモリ特性 (2013)
  • Author(s): 長島 一樹
  • Organizer: 第60回応用物理学会春季学術講演会
  • Place of Presentation: 神奈川工科大学
• [Presentation] 陽極酸化アルミナメンブレンを用いた大面積均一ナノワイヤ成長法の開発 (2013)
  • Author(s): 長島 一樹
  • Organizer: 第60回応用物理学会春季学術講演会
  • Place of Presentation: 神奈川工科大学
• [Presentation] VLS 法を用いた単結晶TiO2ナノワイヤの創成 (2013)
  • Author(s): 柳田 剛
  • Organizer: 第60回応用物理学会春季学術講演会
  • Place of Presentation: 神奈川工科大学
• [Presentation] TiO2ナノワイヤ結晶成長方位のサイズ依存性 (2013)
  • Author(s): 柳田 剛
  • Organizer: 第60回応用物理学会春季学術講演会
  • Place of Presentation: 神奈川工科大学
• [Presentation] 酸化亜鉛ナノワイヤ水熱合成における結晶表面エネルギの役割 (2013)
  • Author(s): 柳田 剛
  • Organizer: 第60回応用物理学会春季学術講演会
  • Place of Presentation: 神奈川工科大学
• [Presentation] Identification of Nanoscale Memristive Switching Using a Single Oxide Nanowire (2012)
  • Author(s): K. Nagashima
  • Organizer: Material Research Society Spring Meeting 2012
  • Place of Presentation: San Francisco, USA
• [Presentation] Surrounding Effects on Nanoscale Memristive Switching Behaviors (2012)
  • Author(s): K. Nagashima
  • Organizer: 19th International Workshop on Oxide Electronics
  • Place of Presentation: Apeldoorn, Netherland
• [Presentation] Scaling Effect on Unipolar and Bipolar Resistive Switching (2012)
  • Author(s): T. Yanagida
  • Organizer: 19th International Workshop on Oxide Electronics
  • Place of Presentation: Apeldoorn, Netherland
• [Presentation] Intrinsic Redox Balancing of Nanoscale Memristive Oxides (2012)
  • Author(s): K. Nagashima
  • Organizer: 5th International Symposium on Atomically Controlled Fabrication Technology
  • Place of Presentation: Osaka, Japan
• [Presentation] Surrounding Effects on Nanoscale Memristive Switching Behaviors (2012)
  • Author(s): K. Nagashima
  • Organizer: 25th International Microprocesses and Nanotechnology Conference
  • Place of Presentation: Hyogo, Japan
• [Presentation] Crucial Role of Ambient Pressure on Thermal Shrinking of Au Nanodot Array (2012)
  • Author(s): G. Meng
  • Organizer: 25th International Microprocesses and Nanotechnology Conference
  • Place of Presentation: Hyogo, Japan
• [Presentation] Creation of Novel Metal Oxide Nanowires (2012)
  • Author(s): T. Kawai
  • Organizer: Material Research Society Fall Meeting 2012
  • Place of Presentation: Boston, USA
• [Presentation] Nanowire Memristor: Fabrication and Memristive Properties (2012)
  • Author(s): T. Yanagida
  • Organizer: Material Research Society Fall Meeting 2012
  • Place of Presentation: Boston, USA
• [Presentation] Impact of Crystal Plane Dependence of Saturated Concentration on Hydrothermal Growth of ZnO Nanowires (2012)
  • Author(s): Y. He
  • Organizer: 8th Handai Nanoscience and Nanotechnology International Symposium
  • Place of Presentation: Osaka, Japan
• [Presentation] Photoassisted Atomic Switch Using ITO Nanowire Electrodes (2012)
  • Author(s): A. Klamchuen
  • Organizer: 8th Handai Nanoscience and Nanotechnology International Symposium
  • Place of Presentation: Osaka, Japan
• [Presentation] Novel Design Rule of Nanoscale Memristive Switching (2012)
  • Author(s): K. Nagashima
  • Organizer: 8th Handai Nanoscience and Nanotechnology International Symposium
  • Place of Presentation: Osaka, Japan
• [Presentation] Fundamental Strategy Toward VLS Grown TiO2 Nanowires (2012)
  • Author(s): F. W. Zhuge
  • Organizer: 8th Handai Nanoscience and Nanotechnology International Symposium
  • Place of Presentation: Osaka, Japan
• [Presentation] Crucial Role of Surrounding Pressure on Thermal Shrinking of Au Nanoparticle Arrays (2012)
  • Author(s): G. Meng
  • Organizer: 8th Handai Nanoscience and Nanotechnology International Symposium
  • Place of Presentation: Osaka, Japan
• [Presentation] ナノスケール抵抗変化メモリにおける周辺環境との熱力学的相互作用の重要性 (2012)
  • Author(s): 長島 一樹
  • Organizer: 第73回応用物理学会学術講演会
  • Place of Presentation: 愛媛大学・松山大学
• [Presentation] ユニポーラ・バイポーラ抵抗変化メモリ現象におけるサイズ効果 (2012)
  • Author(s): 柳田 剛
  • Organizer: 第73回応用物理学会学術講演会
  • Place of Presentation: 愛媛大学・松山大学