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Creation of nano magnetic devices using chiral carbon nanotubes and organic molecules

Research Project

Project/Area Number 24651142
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Nanomaterials/Nanobioscience
Research InstitutionOsaka University

Principal Investigator

OGAWA Takuji  大阪大学, 理学(系)研究科(研究院), 教授 (80169185)

Co-Investigator(Renkei-kenkyūsha) TANAKA Daisuke  大阪大学, 大学院理学研究科, 助教 (60589399)
KOMATSU Naoki  滋賀医科大学, 医学部, 准教授 (30253008)
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsカーボンナノチューブ / 単分子磁石 / テルビウム / 光学活性カーボンナノチューブ / 単一分子磁石 / ナノ磁気特性 / キラル / ナノマグネット
Research Abstract

Carbon nanotubes (CNTs) are cylindrical compounds made from carbon atoms, which have left- and right-handed structures. Since the CNTs are electrically conductive, we have an idea that they can possibly work as tiny electrical magnets. Because detection of the small magnetic field will be difficult directly, we considered to use magnetic molecules to attach on the surface of CNTs and to observe the effects of them.
As the basis for the aim, we studied self-assembled structure of single molecular magnetic molecules (terbium porphyrin double decker complexes) on the surface of carbon materials (HOPG) by using scanning tunneling microscope (STM). We prepared protonated, anion, and radical form of the terbium porphyrin double decker complexes and determined their supra molecular structures on HOPG.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (33 results)

All 2014 2013 2012 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (24 results)

  • [Journal Article] Surface self-assembly of trans-substituted porphyrin double-decker complexes exhibiting slow magnetic relaxation2014

    • Author(s)
      D. Tanaka, T. Inose, S. Shimono, H. Tanaka, T. Tamaki, A. I. A. Abd El-Mageed, A. K. F. Dyab, N. Ishikawa, and T. Ogawa
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 12 Pages: 124-128

    • NAID

      130004933809

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Surface self-assembly of trans-substituted porphyrin double-decker complexes exhibiting slow magnetic relaxation2014

    • Author(s)
      D. Tanaka, T. Inose, S. Shimono, H. Tanaka, T. Tamaki, A. I. A. Abd El-Mageed, A. K. F. Dyab, N. Ishikawa, and T. Ogawa
    • Journal Title

      e-Journal of Surface Science and Nanotechnolog

      Volume: in press

    • NAID

      130004933809

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rectification direction inversion in a phosphododecamolybdic acid / single-walled carbon nanotube junction2013

    • Author(s)
      L. Hong, H. Tanaka and T. Ogawa
    • Journal Title

      J. Mat. Chem. C

      Volume: 1(6) Pages: 1137-1143

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rectification direction inversion in a phosphododecamolybdic acid /single-walled carbon nanotube junction2013

    • Author(s)
      Liu Hong, Hirofumi Tanaka and Takuji Ogawa
    • Journal Title

      J. Mat. Chem. C

      Volume: 1(6) Issue: 6 Pages: 1137-1143

    • DOI

      10.1039/c2tc00171c

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Large Rectification Effect Achieved by a Combination of Carbon Nanotube Junction and Molecule-Carbon Nanotube Interface2012

    • Author(s)
      L. Hong, H. Tanaka, and T. Ogawa
    • Journal Title

      Applied Physics Express

      Volume: 5 Pages: 115102-115102

    • NAID

      10031126458

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Computational Investigation of A Photo-Switchable Single-Molecule Magnet Based on A Porphyrin Terbium Double-Decker Complex2012

    • Author(s)
      T. Inose, D. Tanaka, T. Ogawa
    • Journal Title

      Heterocycles

      Volume: 86 Pages: 1549-1554

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Large Rectification Effect Achieved bya Combination of Carbon Nanotube Junction and Molecule-Carbon Nanotube Interface2012

    • Author(s)
      Liu Hong, Hirofumi Tanaka, and Takuji Ogawa
    • Journal Title

      Applied Physics Express

      Volume: 5 Issue: 11 Pages: 115102-115102

    • DOI

      10.1143/apex.5.115102

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Computational Investigation of A Photo-Switchable Single-Molecule Magnet Based on A Porphyrin Terbium Double-Decker Complex2012

    • Author(s)
      Tomoko Inose, Daisuke Tanaka, Takuji Ogawa
    • Journal Title

      Heterocycles

      Volume: 86 Issue: 2 Pages: 1549-1554

    • DOI

      10.3987/com-12-s(n)86

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Switching of single-molecule magnetic properties and observation of carbon-surface supramolecular structures of Tb(III) porphyrin double-decker complexes

    • Author(s)
      T. Inose, D. Tanaka, H. Tanaka, O. Ivasenko, T. Nagata, Y. Ohta, S. De Feyter, N. Ishikawa, and T. Ogawa
    • Journal Title

      Chemistry–A European Journal

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] アルキル鎖を導入したポルフィリンTbダブルデッカー型錯体の合成と系統的特性評価2014

    • Author(s)
      下野颯騎、田中大輔、猪瀬朋子、田中啓文、石川直人、小川琢治
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] 単分子電導度計測を目指したポルフィリンダブルデッカー型単分子磁石の合成と物性評価2014

    • Author(s)
      炭谷宣登、TIMMERMAN Vanessa、田中大輔、猪瀬朋子、田中啓文、石川直人、小川琢治
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] ポルフィリンダブルデッカー型単分子磁石の界面微細構造評価2014

    • Author(s)
      猪瀬朋子、田中大輔、田中啓文、石川直人、永田央、Oleksandr Ivasenko、Steven De Feyter、田原一邦、戸部義人、小川琢治
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] ポルフィリン単分子磁石のHOPG上分子配列制御2014

    • Author(s)
      田中大輔,猪瀬朋子,田中啓文,石川直人,小川琢治
    • Organizer
      第4回分子アーキテクトニクス研究会
    • Place of Presentation
      東京大学山上会館
    • Year and Date
      2014-03-11
    • Related Report
      2013 Final Research Report
  • [Presentation] Proton-induced switching and controlling of molecular alignment on HOPG of porphyrin-based terbium(III) single molecular magnets2013

    • Author(s)
      Tomoko Inose, Daisuke Tanaka, Takuji Ogawa
    • Organizer
      2013 MRS Fall Meeting
    • Place of Presentation
      Boston, Massachusetts, U.S.A.
    • Year and Date
      2013-12-01
    • Related Report
      2013 Final Research Report
  • [Presentation] Controlling molecular alignment of double-decker single molecular magnets2013

    • Author(s)
      Tomoko Inose, Daisuke Tanaka, Hirofumi Tanaka, Oleksandr Ivasenko, Toshi Nagata, Steven De Feyter, Naoto Ishikawa, Takuji Ogawa
    • Organizer
      ACSIN-12 & ICSPM21
    • Place of Presentation
      Tsukuba International Congress Center
    • Year and Date
      2013-11-05
    • Related Report
      2013 Final Research Report
  • [Presentation] ポルフィリンダブルデッカー型単分子磁石のSTMによるHOPG上表面構造評価2013

    • Author(s)
      猪瀬朋子、田中大輔、田中啓文、石川直人、永田央、Oleksandr Ivasenko、Steven De Feyter、小川琢治
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学(沖縄県)
    • Year and Date
      2013-11-04
    • Related Report
      2013 Final Research Report
  • [Presentation] ポルフィリンダブルデッカー型単分子磁石のスイッチング特性2013

    • Author(s)
      田中大輔・猪瀬朋子・下野颯騎・炭谷宣登・田中啓文・石川直人・小川琢治
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学(沖縄県)
    • Year and Date
      2013-11-04
    • Related Report
      2013 Final Research Report
  • [Presentation] 長鎖アルキル基を導入したポルフィリンダブルデッカー型錯体の合成と磁気特性評価2013

    • Author(s)
      下野颯騎・田中大輔・猪瀬朋子・田中啓文・石川直人・小川琢治
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学(沖縄県)
    • Year and Date
      2013-11-02
    • Related Report
      2013 Final Research Report
  • [Presentation] ポルフィリンダブルデッカー型単分子磁石のHOPG上分子配列制御2013

    • Author(s)
      猪瀬朋子、田中大輔、田中啓文、石川直人、永田央、Oleksandr Ivasenko、Steven De Feyter、田原一邦、戸部義人、小川琢治
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京都府、京田辺市)
    • Year and Date
      2013-09-16
    • Related Report
      2013 Final Research Report
  • [Presentation] 新規ポルフィリンTbダブルデッカー型錯体の合成と磁気特性評価2013

    • Author(s)
      下野颯騎,田中大輔,猪瀬朋子,田中啓文,石川直人,小川琢治
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学
    • Year and Date
      2013-09-05
    • Related Report
      2013 Final Research Report
  • [Presentation] HOPG上オクタエチルポルフィリンダブルデッカー型単分子磁石の単分子膜分子配列制御2013

    • Author(s)
      猪瀬朋子,田中大輔,田中啓文,Oleksandr Ivasenko,永田央,Steven De Feyter,石川直人
    • Organizer
      春季第60回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工大
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] オクタエチルポルフィリン-テルビウムダブルデッカー型単分子磁石の磁性評価とSTMによる自己集合単分子膜の構造観察2013

    • Author(s)
      猪瀬朋子・田中大輔・田中啓文・Ivasenko, Oleksandr・永田央・De Feyter, Steven・石川直人・小川琢治
    • Organizer
      日本化学会年会
    • Place of Presentation
      立命館大学
    • Year and Date
      2013-03-22
    • Related Report
      2013 Final Research Report
  • [Presentation] ポルフィリンダブルデッカー型単分子磁石の磁性スイッチングと表面構造観察2012

    • Author(s)
      猪瀬朋子、田中大輔、太田雄介、田中啓文、阪上祥平、Oleksandr Ivasenko、Steven De Feyter、石川直人、小川琢治
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学五福キャンパス(富山市)
    • Year and Date
      2012-09-22
    • Related Report
      2013 Final Research Report
  • [Presentation] Proton-induced switching of TbIII-tetraphenylporphyrin double-decker single molecule magnet2012

    • Author(s)
      Tomoko Inose, Daisuke Tanaka, Hirofumi Tanaka, Naoto Ishikawa, Takuji Ogawa
    • Organizer
      AsiaNano 2012
    • Place of Presentation
      Crowne Plaza Lijiang Ancient Town, China
    • Year and Date
      2012-09-09
    • Related Report
      2013 Final Research Report
  • [Presentation] HOPG上ポルフィリンダブルデッカー型単分子磁石のSTM観察2012

    • Author(s)
      猪瀬朋子,田中大輔,太田雄介,阪上祥平,田中啓文, Oleksandr Ivasenko, Steven De Feyter,石川直人,小川琢治
    • Organizer
      ナノ学会
    • Place of Presentation
      大阪大学(大阪府、豊中市)
    • Year and Date
      2012-06-14
    • Related Report
      2013 Final Research Report
  • [Presentation] ポルフィリンダブルデッカー型単分子磁石の界面

    • Author(s)
      猪瀬朋子、田中大輔、田中啓文、石川直人、永田央、Oleksandr Ivasenko、Steven De Feyter、田原一邦、
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] ポルフィリン単分子磁石の HOPG 上分子配列制御

    • Author(s)
      田中 大輔, 猪瀬 朋子,田中 啓文,石川 直人, 小川 琢治
    • Organizer
      第4回分子アーキテクトニクス研究会
    • Place of Presentation
      東京大学山上会館
    • Related Report
      2013 Annual Research Report
  • [Presentation] Proton-induced switching and controlling of molecular alignment on HOPG of porphyrin-based terbium(III) single molecular magnets

    • Author(s)
      Tomoko Inose, Daisuke Tanaka, Takuji Ogawa
    • Organizer
      2013 MRS Fall Meeting
    • Place of Presentation
      Boston, Massachusetts
    • Related Report
      2013 Annual Research Report
  • [Presentation] Controlling molecular alignment of double-decker single molecular magnets.

    • Author(s)
      Tomoko Inose, Daisuke Tanaka, Hirofumi Tanaka, Oleksandr Ivasenko, Toshi Nagata, Steven De Feyter, Naoto Ishikawa, Takuji Ogawa
    • Organizer
      ACSIN-12 & ICSPM21
    • Place of Presentation
      Tsukuba International Congress CenterTsukuba International Congress Center
    • Related Report
      2013 Annual Research Report
  • [Presentation] ポルフィリンダブルデッカー型単分子磁石のSTM によるHOPG 上表面構造評価

    • Author(s)
      猪瀬朋子、田中大輔、田中啓文、石川直人、永田央、Oleksandr Ivasenko、Steven De Feyter、小川琢治
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 長鎖アルキル基を導入したポルフィリンダブルデッカー型錯体の合成と磁気特性評価

    • Author(s)
      下野 颯騎・田中 大輔・猪瀬 朋子・田中 啓文・石川 直人・小川 琢治
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] ポルフィリンダブルデッカー型単分子磁石の HOPG 上分子配列制御

    • Author(s)
      猪瀬朋子、田中大輔、田中啓文、石川直人、永田央、Oleksandr Ivasenko、Steven De Feyter、田原一邦、戸部義人、小川琢治
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 超構造形成のための平坦ポルフィリンアレイの合成

    • Author(s)
      尾島茉由子・山名亜由子・玉木孝・田中大輔・田中啓文・小川琢治
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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