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Development of analytical methods for clumped-isotope of CO2 and O2

Research Project

Project/Area Number 24654182
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Geochemistry/Astrochemistry
Research InstitutionNagoya University

Principal Investigator

ABE Osamu  名古屋大学, 環境学研究科, 助教 (00293720)

Co-Investigator(Kenkyū-buntansha) YAMADA Keita  東京工業大学, 総合理工学研究科, 准教授 (70323780)
Co-Investigator(Renkei-kenkyūsha) YOSHIDA Naohiro  東京工業大学, 総合理工学研究科, 教授 (60174942)
MORIMOTO Maki  名古屋大学, 大学院環境学研究科, 研究員 (30377999)
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords安定同位体 / 二重置換同位体組成 / clumped-isotope / サンゴ骨格 / 地球化学 / 同位体
Research Abstract

Analytical system of clumped isotopes in CO2 was first established with a small-sector isotope ratio mass spectrometer. The internal precision of the single gas D47 measurements was obtained as 0.02 permil for the routine analytical condition, which are comparable with that obtained using a MAT253 mass spectrometer.
Temporal variation of clumped isotopes in Porites coral skeleton, which was collected at Yonaguni Island, southwestern Japan, was determined. The D47 time-series result shows a good agreement with observed temperature variation.
Analytical method of clumped isotopes in O2 was established, based on the CO2 analysis which is generated from O2 and C-13 free graphite.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (10 results)

All 2014 2013 2012

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (6 results) (of which Invited: 1 results)

  • [Journal Article] Accurate method for the determination of intramolecular C-13 isotope composition of ethanol from aqueous solutions2013

    • Author(s)
      Alexis Gilbert, Keita Yamada, Naohiro Yoshida
    • Journal Title

      Analytical Chemistry

      Volume: 85 Issue: 14 Pages: 6566-6570

    • DOI

      10.1021/ac401021p

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Exploration of intramolecular C-13 isotope distribution in long chain n-alkanes (C-11-C-31) using isotopic C-13 NMR2013

    • Author(s)
      Alexis Gilbert, Keita Yamada, Naohiro Yoshida
    • Journal Title

      Organic Geochemistry

      Volume: 62 Pages: 56-61

    • DOI

      10.1016/j.orggeochem.2013.07.004

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Precision and long-term stability of clumped isotope analysis of CO2by a small sector isotope ratio mass spectrometer2013

    • Author(s)
      Naohiro Yoshida
    • Journal Title

      Rapid communications in mass spectrometry

      Volume: 27 Issue: 1 Pages: 207-215

    • DOI

      10.1002/rcm.6431

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Reply to Nicholson's comment on "Consistent calculation of aquatic gross production from oxygen triple isotope measurements" by Kaiser (2011)2012

    • Author(s)
      J. Kaiser and O. Abe
    • Journal Title

      Biogeosciences

      Volume: 9 Issue: 8 Pages: 2921-2933

    • DOI

      10.5194/bg-9-2921-2012

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Reconstruction of 9c-12c marine environment using long-lived fossil coral proxies2014

    • Author(s)
      O. Abe
    • Organizer
      International Joint Workshop on coral reef environmental earth sciences
    • Place of Presentation
      Hokkaido University
    • Year and Date
      2014-03-26
    • Related Report
      2013 Final Research Report
  • [Presentation] Vertical distribution of triple isotopic composition of dissolved O_2 in the northwestern Pacific2013

    • Author(s)
      O. Abe
    • Organizer
      EGU General Assembly 2013
    • Place of Presentation
      Vienna, Austria
    • Year and Date
      2013-04-11
    • Related Report
      2013 Final Research Report
  • [Presentation] 南西諸島石垣島の化石サンゴ長尺試料の骨格酸素同位体比2013

    • Author(s)
      阿部理
    • Organizer
      日本海洋学会2013年春季大会
    • Place of Presentation
      東京海洋大学
    • Year and Date
      2013-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] 炭酸塩の炭素・酸素二重置換同位体分子研究の現状と課題~原子比から分子比へ~2012

    • Author(s)
      阿部理
    • Organizer
      日本地球化学会年会
    • Place of Presentation
      九州大学
    • Year and Date
      2012-09-13
    • Related Report
      2013 Final Research Report
  • [Presentation] 代替水温指標としての炭酸塩の炭素・酸素二重置換同位体組成2012

    • Author(s)
      阿部理
    • Organizer
      日本古生物学会2012年年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2012-06-29
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] 炭酸塩の炭素・酸素二重置換同位体分子研究 の現状と課題~原子比から分子比へ~2012

    • Author(s)
      阿部 理
    • Organizer
      日本地球化学会年会
    • Place of Presentation
      九州大学
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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