Charge transfer mechanisms in organic crystals revealed by intermolecular vibrational excitations
Project/Area Number |
24655011
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Single-year Grants |
Research Field |
Physical chemistry
|
Research Institution | Kyoto University |
Principal Investigator |
WATANABE Kazuya 京都大学, 理学(系)研究科(研究院), 准教授 (30300718)
|
Project Period (FY) |
2012-04-01 – 2014-03-31
|
Project Status |
Completed (Fiscal Year 2013)
|
Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
Keywords | 有機固体 / 電子励起状態 / コヒーレントフォノン / 超高速分光 / 格子振動 / 励起状態ダイナミクス / 非線形分光 |
Research Abstract |
In this project we aimed to study an effect of phonon mode excitation on an excited state dynamics in organic crystals. We have developed an optical set up that generates femtosecond pulse trains with variable pulse repetition rates in order to excite phonon modes with mode selective fashion. We applied it to singlet fission process in rubrene crystal and investigated the effect of the phonon excitations on the fission rates. We also studied a coherent phonon dynamics in rubrene crystal during the fission process.
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Report
(3 results)
Research Products
(3 results)