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Zero emission CO2 transformation based on visible light irradiation

Research Project

Project/Area Number 24655026
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionNagoya University

Principal Investigator

SAITO Susumu  名古屋大学, 理学(系)研究科(研究院), 教授 (90273268)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
KeywordsPhoto reaction / CO2 / HCO2H / CO / MeOH / transition metal complex / visible light / 還元 / 可視光 / 金属錯体 / ギ酸 / 一酸化炭素 / CO2固定化 / 電荷移動錯体 / 可視光触媒化学 / 炭素-炭素結合形成
Outline of Final Research Achievements

We demonstrated that under visible light (> 400 nm) irradiation, CO2 was converted into CO and HCO2H using transition metal complexes bearing Ir, Ru or Co as a metal center coordinated with (P,N,N,P)-type tetradentate ligands. The highest turnover number recorded is around 20. It was also revealed that structural robustness (no decomposition of metal complex during light irradiation) should be more improved to ensure a higher TON. Direct conversion of CO2 to MeOH would be also possible in a future development of a higher performance molecular catalyst bearing a tetradentate ligand.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (37 results)

All 2015 2014 2013 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 1 results,  Open Access: 1 results) Presentation (14 results) (of which Invited: 11 results) Book (3 results) Remarks (3 results) Patent(Industrial Property Rights) (7 results) (of which Overseas: 1 results)

  • [Journal Article] One-step synthesis of patterned polymer brushes by photocatalytic microcontact printing with TiO2 nanoparticles2015

    • Author(s)
      Friederike Kettling, Benjamin Vonhören, Jennifer A. Krings, Susumu Saito, Bart Jan Ravoo
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 6 Pages: 1027-1030

    • DOI

      10.1039/c4cc08646e

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydration of Nitriles to Amides by a Chitin- supported Ruthenium Catalyst2015

    • Author(s)
      Aki Matsuoka, Takahiro Isogawa, Yuna Morioka, Benjamin R. Knappett, Andrew E. H. Wheatley, Susumu Saito, and Hiroshi Naka
    • Journal Title

      RSC Adv.

      Volume: 5 Issue: 16 Pages: 12152-12160

    • DOI

      10.1039/c4ra15682j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] N-Methylation of amines with methanol at room temperature2015

    • Author(s)
      Vasily N. Tsarev, Yuna Morioka, Joaquim Caner, Qing Wang, Richiro Ushimaru, Akihiko Kudo, Hiroshi Naka, Susumu Saito
    • Journal Title

      Org. Lett.

      Volume: nd Issue: 10 Pages: 2530-2533

    • DOI

      10.1021/acs.orglett.5b01063

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereoselective Synthesis of cis,cis‐configured vicinal triamines2014

    • Author(s)
      Adrian Schulte, Xingci Situ, Susumu Saito, Bernhard Wünsch
    • Journal Title

      Eur. J .Org. Chem.

      Volume: none Issue: 26 Pages: 5749-5756

    • DOI

      10.1002/ejoc.201402685

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bromolactamization as key step in the stereoselective synthesis of enantiomerically pure, cis-configured perhydropyrroloquinoxalines2014

    • Author(s)
      Adrian Schulte, Xingci Situ, Susumu Saito, Bernhard Wünsch
    • Journal Title

      Chirality

      Volume: none Issue: 12 Pages: 793-800

    • DOI

      10.1002/chir.22350

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of propylene from renewable allyl alcohol by photocatalytic transfer hydrogenolysis2014

    • Author(s)
      J. Caner, Zijun Liu, Y. Takada, A. Kudo, H. Naka, and S. Saito
    • Journal Title

      Catal. Sci. Tec.

      Volume: 4 Issue: 11 Pages: 4093-4098

    • DOI

      10.1039/c4cy00329b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Catalytic fluoride triggers dehydrative oxazolidinone synthesis from CO22014

    • Author(s)
      Yuki Takada, Siong Wan Foo, Yusuke Yamazakia, Susumu Saito
    • Journal Title

      RSC Advances

      Volume: 4 Issue: 92 Pages: 50851-50857

    • DOI

      10.1039/c4ra09609f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydrative Synthesis of Chiral Oxazolidinones Catalyzed by Alkali Metal Carbonates under Low Pressure of CO22013

    • Author(s)
      Siong Wan Foo, Yuki Takada, Yusuke Yamazaki, Susumu Saito
    • Journal Title

      Tetrahedron Lett.

      Volume: 54 Issue: 35 Pages: 4714-4720

    • DOI

      10.1016/j.tetlet.2013.06.100

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Redox-selective Generation of Aldehydes and H2 from Alcohols under Visible Light2013

    • Author(s)
      Zijun Liu, Joaquim Caner, Akihiko Kudo, Hiroshi Naka, Susumu Saito
    • Journal Title

      Chem. Eur. J.

      Volume: 19 Issue: 29 Pages: 9452-9456

    • DOI

      10.1002/chem.201301347

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Acetals of N,N-Dimethylformamides: Ambiphilic Behavior in Converting Carbon Dioxide to Dialkyl Carbonates2013

    • Author(s)
      Yuki Takada, Aki Matsuoka, Ya Du, Hiroshi Naka, Susumu Saito
    • Journal Title

      Chem. Lett.

      Volume: 42 Issue: 2 Pages: 146-147

    • DOI

      10.1246/cl.2013.146

    • NAID

      130004426857

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 分子表面の多彩な活性化に基づく不活性カルボン酸誘導体の水素化2015

    • Author(s)
      斎藤進
    • Organizer
      第8回分子活性化公開シンポジウム
    • Place of Presentation
      大阪大学Σホール(豊中キャンパス)
    • Year and Date
      2015-01-23 – 2015-01-24
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Hydrogen Management Catalysis Using Thermal and Light Energy for Organic Synthesis2014

    • Author(s)
      Susumu Saito
    • Organizer
      The 18th (FINAL) Joint IRTG Symposium for Nagoya–Münster University
    • Place of Presentation
      Münster University, Germany
    • Year and Date
      2014-11-26 – 2014-11-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Hydrogen Management Catalysis for Transformation of CO2- and Biomass-derived Feedstock2014

    • Author(s)
      Susumu Saito
    • Organizer
      Vietnam and Malaysia International Chemical Congress (VMICC)
    • Place of Presentation
      Hanoi, Vietnam
    • Year and Date
      2014-11-05 – 2014-11-07
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Hydrogen Management for Chemcial Transformation of CO2- and Biomass-derived Feedstock2014

    • Author(s)
      Susumu Saito
    • Organizer
      18th Malaysian International Chemical Congress (18MICC)
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Year and Date
      2014-11-01 – 2014-11-03
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Selective Hydrogenation of Inert Carbonyl Compounds Using Catalytic Molecular Surface Built on Transition Metals2014

    • Author(s)
      Susumu Saito
    • Organizer
      41st International Conference on Coordination Chemistry (ICCC-41)
    • Place of Presentation
      Singapore
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Hydrogen Management for Sustainable Organic Synthesis: Control of Hydrogen Transfer Diversity in Catalysis Involving Alcohols2014

    • Author(s)
      Susumu Saito
    • Organizer
      MEXT, Japan/Canada Joint Symposium
    • Place of Presentation
      The University of Ottawa, Canada
    • Year and Date
      2014-07-05 – 2014-07-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Redox-Selective Generation of Aldehydes and H2 from Alcohols under Visible Light2014

    • Author(s)
      中 寛史,斎藤進
    • Organizer
      The 3rd International Conference on the MEXT project of Integrated Research on Chemical Synthesis
    • Place of Presentation
      福岡
    • Related Report
      2013 Research-status Report
  • [Presentation] New Catalysis for Hydrogen Management2014

    • Author(s)
      Susumu Saito
    • Organizer
      SJTU-NU inter-university research seminar for Ph.D. course students -Campus Asia-
    • Place of Presentation
      Shanghai, China
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 「水素マネージメント」触媒を用いるバイオマス由来物質の合成的利用2014

    • Author(s)
      斎藤進
    • Organizer
      第94日本化学会春季年会アドバンスト・テクノロジー・プログラム (ATP) セッション「再生可能資源を活用するための有機合成化学」
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 可視光と水を用いるアルコールからのレドックス選択的な水素とアルデヒドの形成反応の開拓2013

    • Author(s)
      Zijun Liu, Joaquim Caner, 工藤昭彦,中寛史,斎藤進
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      愛媛大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 水素マネージメントに基づく触媒開発は次世代物質生産の基盤になりうるか?基幹化学物質から医薬関連物質の合成まで2013

    • Author(s)
      斎藤進
    • Organizer
      (株)三菱化学科学技術研究センター講演会
    • Place of Presentation
      横浜
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Hydrogen Management: Hydrogenation and Dehydrogenation for Organic Synthesis2013

    • Author(s)
      Susumu Saito
    • Organizer
      The 15th Joint IRTG Symposium for Nagoya-Muenster University
    • Place of Presentation
      Muenster, Germany
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 新触媒で脱石油化学に挑む2013

    • Author(s)
      斎藤進
    • Organizer
      名大Cafe,Science, and Me
    • Place of Presentation
      栄,名古屋
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] N,N-ジメチルホルムアミド ジアルキルアセタールの両性を利用した二酸化炭素のジアルキルカーボネートへの変換2013

    • Author(s)
      高田雄貴、松岡亜希、Ya Du、中寛史、野依良治、斎藤進
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学、南草津
    • Related Report
      2012 Research-status Report
  • [Book] 「触媒年鑑」触媒技術の動向と展望2015

    • Author(s)
      斎藤進
    • Publisher
      触媒学会
    • Related Report
      2014 Annual Research Report
  • [Book] 二酸化炭素の直接利用技術最前線2013

    • Author(s)
      中寛史,斎藤進
    • Total Pages
      11
    • Publisher
      NTS出版
    • Related Report
      2013 Research-status Report 2012 Research-status Report
  • [Book] 月刊化学2013

    • Author(s)
      斎藤進
    • Total Pages
      2
    • Publisher
      化学同人
    • Related Report
      2013 Research-status Report
  • [Remarks] Publications

    • URL

      http://noy.chem.nagoya-u.ac.jp/noy_j/publications.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 受験サプリ「低化石資源社会を目指した触媒と有機合成 ~水素を操れ!~」

    • URL

      http://jyukensapuri.jp/rnet/LP/pc/promo2015-01/?vos=evcpysl0001x0334301

    • Related Report
      2014 Annual Research Report
  • [Remarks] 論文:二酸化炭素の固定化

    • URL

      http://noy.chem.nagoya-u.ac.jp/noy_j/Top/entori/2013/2/5_lun_wen_er_suan_hua_tan_suno_gu_ding_hua.html

    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] カルボン酸化合物の水素化によるアルコールの製造方法、 及び該製造方法に用いるルテニウム錯体2015

    • Inventor(s)
      斎藤進,野依良治,鳴戸真之
    • Industrial Property Rights Holder
      国立大学法人 名古屋大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-081711
    • Filing Date
      2015-04-13
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 配位子、その配位子を含む金属錯体、及びその金属錯体を 用いた反応2014

    • Inventor(s)
      斎藤進、野依良治、三浦隆志、鳴戸真之、戸田勝章、二村聡太等
    • Industrial Property Rights Holder
      国立大学法人 名古屋大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-03-04
    • Related Report
      2013 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 有機化合物の製造方法2013

    • Inventor(s)
      斎藤進、野依良治、中寛史、Caner, Liu
    • Industrial Property Rights Holder
      国立大学法人 名古屋大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-193470
    • Filing Date
      2013-09-18
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 3級アミン又は3級アミン誘導体の製造方法2013

    • Inventor(s)
      斎藤進、野依良治、中寛史等
    • Industrial Property Rights Holder
      国立大学法人 名古屋大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-213167
    • Filing Date
      2013-10-10
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] カルボン酸化合物の水素化によるアルコールの製造方法、及び該製造方法に用いるルテニウム錯体2013

    • Inventor(s)
      斎藤進、野依良治、鳴戸真之
    • Industrial Property Rights Holder
      国立大学法人 名古屋大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-267866
    • Filing Date
      2013-12-25
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] カルボン酸化合物及びエステル化合物の水素化によるアルコールの製造方法2013

    • Inventor(s)
      斎藤進、野依良治、Santosh Agrawal、鳴戸真之
    • Industrial Property Rights Holder
      国立大学法人 名古屋大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-268047
    • Filing Date
      2013-12-25
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 環状ウレタンの製造方法2013

    • Inventor(s)
      斎藤 進、野依良治、中寛史、Siong Wan Foo
    • Industrial Property Rights Holder
      国立大学法人 名古屋大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-065083
    • Filing Date
      2013-03-26
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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