novel method to link independent conjugated systems in biary compounds
| Project/Area Number |
24655030
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
YASUDA Makoto 大阪大学, 工学(系)研究科(研究院), 教授 (40273601)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | 有機合成化学 / 有機合成反応 / 共役系 / 非平面 / スルースペース / 電荷移動 / 発光 |
|---|
| Outline of Final Research Achievements |
The control of photoluminescence wavelength is significant for the design of emitting materials, and a compound having aryl-aryl bonds is one of the most useful candidates for the synthesis of these materials. However, the biaryl system lacks an efficient linkage of independent conjugated moieties. In this research, a novel method to link independent π-systems in biaryl compounds was studied. The oxy-substituents at the peri-position in 1-arylnaphthalene systems showed interesting and unexpected photophysical properties. In particular, peri-OH-substituted arylnaphthalenes showed a large bathochromic shift. The through-space interaction between the peri-substituted OH and aryl groups generated an unexpected extended conjugation system.
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Report
(4 results)
Research Products
(34 results)
