Development of ambipolar organic semiconductor using properties of antiaromatic ring
| Project/Area Number |
24655036
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Tokyo Metropolitan University |
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Principal Investigator |
NISHINAGA Tohru 首都大学東京, 理工学研究科, 准教授 (30281108)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 反芳香族性 / 有機半導体 / トランジスタ / 電界効果トランジスタ / 両極性半導体 / シクロオクタテトラエン / 低バンドギャップ |
|---|
| Research Abstract |
It is difficult to realize an ambipolar organic semiconductor with high and balanced mobility and only a few example of such semiconductors have been reported. In this work, unlike the conventional donor-acceptor structure, we succeeded in the development of a novel ambipolar semiconductor based on cyclic tetrathiophene having narrow HOMO-LUMO gap derived from antiaromatic planar COT ring.
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Report
(3 results)
Research Products
(44 results)
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[Journal Article] Multifunctional π-Expanded Macrocyclic Oligothiophene 6-Mers and Related Macrocyclic Oligomers2014
Author(s)
Iyoda, M.; Tanaka, K.; Shimizu, H.; Hasegawa, M.; Nishinaga, T.; Nishiuchi, T.; Kunugi, Y.; Ishida, T.; Otani, H.; Sato, H.; Inukai, K.; Tahara, K.; Tobe, Y.
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Journal Title
J. Am. Chem. Soc.
Volume: 136
Issue: 6
Pages: 2389-2396
DOI
Related Report
Peer Reviewed
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