Development of new photocatalysts for hydride transfer
| Project/Area Number |
24655046
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
ISHITANI Osamu 東京工業大学, 理工学研究科, 教授 (50272282)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 多核錯体 / 光触媒 |
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| Research Abstract |
We newly developed photochemical CO2 reduction to CO by using an Ir(III) complex as photocatalyst with amine as reductant. Irradiation to a Ru(II) dimer with a benzofurane bridge ligand gave the corresponding dihydrido complex, however, this photochemical system could not reduce CO2 to formaldehyde and methanol.
We carefully investigated the hydride transfer reactions from a Ru(II) hydrido complex to various NAD model compounds and clarified both electronic and steric effects on the selectivity of the products and the reaction rates.
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Report
(3 results)
Research Products
(15 results)
