| Project/Area Number |
24655047
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
KONDO Mitsuru 静岡大学, グリーン科学技術研究所, 教授 (80254142)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | アニオンレセプター / 過塩素酸イオン / アニオン捕捉 / 水溶性カプセル / 呈色活性 / 三核錯体 / アニオン検出 / 構造変換 / 過塩素酸イオン認識 / 硝酸イオン認識 / アニオン除去 / 脱塩 / アニオン認識 / カプセル分子 |
|---|
| Research Abstract |
Although it is known that perchlorate ion shows toxicity, which inhibits growth of newborns and children, it is quite difficult to remove the anion from water because of the high solubility in water. In this work, new coordination polymers that remove the anion from water were synthesized from bis-imidazole type ligand, bitb. Moreover, new molecular capsule system was developed by using a new bis-imidazole type ligand with hydroxy group. The system detects perchlorate in aqueous solutions by selective encapsulates it within the cage.
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