• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of multichromic device based on the dynamic molecular motion of the chiral metal complexes

Research Project

Project/Area Number 24655053
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionOsaka City University

Principal Investigator

MIYAKE Hiroyuki  大阪市立大学, 大学院理学研究科, 准教授 (00271198)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsセンシング / 超分子化学 / 不斉 / 発光 / 円二色性 / 赤外振動スペクトル / 希土類錯体 / スイッチング / 円偏光
Research Abstract

Metal complexes have unique spectroscopic and magnetic properties depending on their characteristic coordination geometries. To develop the rapid conversion system of their properties in solution for multichromic transmission and detection, we developed (1) the multi-luminescent device in response to the external stimuli, (2) the multichromic system including conversion of coordination geometries, (3) the multi-detectable system for determination of the substrates' chirality, which have been constructed from the labile and chiral metal complexes developed by our group.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (57 results)

All 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 5 results) Presentation (46 results) (of which Invited: 14 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Lanthanide Tris(β-diketonates) as Useful Probes for Chirality Determination of Biological Amino Alcohols in Vibrational Circular Dichroism : Ligand to Ligand Chirality Transfer in Lanthanide Coordination Sphere2014

    • Author(s)
      H. Miyake, K. Terada and H. Tsukube
    • Journal Title

      Chirality

      Volume: 26 Issue: 6 Pages: 293-299

    • DOI

      10.1002/chir.22319

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 分子認識から始まる動的分子プログラミング–錯体化学を基盤としたキラリティー誘起と反転スイッチング2013

    • Author(s)
      三宅弘之
    • Journal Title

      化学

      Volume: 68 (5) Pages: 46-52

    • NAID

      40019676283

    • URL

      http://www.kagakudojin.co.jp/kagaku/web-kagaku03/c6805/c6805-miyake/index.html

    • Related Report
      2013 Final Research Report
  • [Journal Article] Materials-Based Receptors : Design Principle and Applications2013

    • Author(s)
      K. Singh, D. Sareen, P. Kaur, H. Miyake, and H. Tsukube
    • Journal Title

      Chem. Eur. J

      Volume: 19 Issue: 22 Pages: 6914-6936

    • DOI

      10.1002/chem.201300249

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] 分子認識から始まる動的分子プログラミング-錯体化学を基盤としたキラリティー誘起と反転スイッチング2013

    • Author(s)
      三宅弘之
    • Journal Title

      化学

      Volume: 68 Pages: 46-52

    • NAID

      40019676283

    • Related Report
      2012 Research-status Report
  • [Journal Article] Preferential Crystallization of Lanthanoid Tris(β-diketonates) with Bridged Bis(2-pyridylmethyl)amine Ligands toward Separation Application2012

    • Author(s)
      Masafumi Yano
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 85 Issue: 4 Pages: 490-496

    • DOI

      10.1246/bcsj.20110281

    • NAID

      130004153052

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Helicity Inversion from Left- to Right-Handed Square Planar Pd(II) Complexes : Synthesis of a Diastereomer Pair from a Single Chiral Ligand and their Structure Dynamism2012

    • Author(s)
      Hiroyuki Miyake
    • Journal Title

      Chem.Commun.

      Volume: 48 Issue: 31 Pages: 3721-3723

    • DOI

      10.1039/c2cc18154a

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Coordination Chemistry Strategies for Dynamic Helicates : Time-Programmable Chirality Switching with Labile and Inert Metal Helicates2012

    • Author(s)
      H. Miyake, and H. Tsukube
    • Journal Title

      Chem. Soc. Rev

      Volume: 41 Issue: 21 Pages: 6977-6991

    • DOI

      10.1039/c2cs35192g

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Time-Programming of Conformational Dynamics in Chiral Metallopeptides2014

    • Author(s)
      H. Miyake
    • Organizer
      The 2nd International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      Campus Plaza Kyoto, Kyoto, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] TPEN-Nd(III)錯体を用いたキラリティープローブ法の開発2014

    • Author(s)
      國屋拓郎・篠田哲史・築部浩・三宅弘之
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] キラルメタロフォルダマーの合成とらせん構造の制御2014

    • Author(s)
      藤田愛子・篠田哲史・三宅弘之
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 硝酸アニオンをトリガーとしたトリス(2,2'-ビピリジン)金属錯体のヘリシティー反転とタイムプログラミング2014

    • Author(s)
      阪本達哉・小原一朗・山口健太郎・築部浩・三宅弘之
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] テトラアミドサイクレン―希土類錯体の新規合成法の開発2014

    • Author(s)
      佐竹良介・篠田哲史・築部浩・三宅弘之
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] カテコールの光酸化による希土類錯体の近赤外発光増強2014

    • Author(s)
      篠田哲史
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] TPEN-Nd(III)錯体を用いたキラリティープローブ法の開発2014

    • Author(s)
      國屋拓郎
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] カドミウム(II)ポルフィリンを基盤とした多点認識型レセプターの合成2014

    • Author(s)
      篠田哲史
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 硝酸アニオンをトリガーとしたトリス(2,2'-ビピリジン)金属錯体のヘリシティー反転とタイムプログラミング2014

    • Author(s)
      阪本達哉
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] キラルメタロフォルダマーの合成とらせん構造の制御2014

    • Author(s)
      藤田愛子
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] テトラアミドサイクレン―希土類錯体の新規合成法の開発2014

    • Author(s)
      佐竹良介
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Stimuli-Responsive Dynamic Molecular Motion in Labile Metal Complexes2013

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Center for Nanoscience
    • Place of Presentation
      Dept. of Chemistry & Biochemistry, University of Missouri - St. Louis, USA
    • Year and Date
      2013-09-06
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Chirality Induction and Its Dynamic Control in Coordination Chemistry2013

    • Author(s)
      H. Miyake
    • Organizer
      Symmetry Festival
    • Place of Presentation
      Delft, The Netherlands
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Invited
  • [Presentation] Stimuli-responsive molecular motion in optically active metal complexes2013

    • Author(s)
      H. Miyake
    • Organizer
      246th ACS National Meeting & Exposition
    • Place of Presentation
      Indianapolis, IN, USA
    • Related Report
      2013 Final Research Report
  • [Presentation] NO ^–3 Responsive Helicity Inversion of Tris(2,2'-bipyridine)-Labile Metal Complexes : Dynamic Chirality Integration from Helical Complex Terminal to Complex Center2013

    • Author(s)
      H. Miyake, T. Sakamoto, K. Ohara, K. Yamaguchi, H. Tsukube
    • Organizer
      14th International Conference on Chiroptical Spectroscopy
    • Place of Presentation
      Nashville, Tennessee
    • Related Report
      2013 Final Research Report
  • [Presentation] 配位化学を活用したキラル分子プログラミング2013

    • Author(s)
      三宅弘之
    • Organizer
      第20回記念シンポジウムモレキュラー・キラリティー2013
    • Place of Presentation
      京都大学吉田キャンパス
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 錯体ヘリシティーの反転スイッチング;錯体から錯体へのキラル情報の伝達2013

    • Author(s)
      三宅弘之・阪本達哉・小原一朗・山口健太郎・築部浩
    • Organizer
      第10回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      和歌山大学
    • Related Report
      2013 Final Research Report
  • [Presentation] NO3- Responsive Helicity Inversion of Tris(2,2'-bipyridine)-Labile Metal Complexes: Dynamic Chirality Integration from Helical Complex Terminal to Complex Center2013

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      14th International Conference on Chiroptical Spectroscopy
    • Place of Presentation
      Nashville, TN, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Stimuli-Responsive Molecular Motion in Optically Active Metal Complexes2013

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      246th ACS National Meeting & Exposition
    • Place of Presentation
      Indianapolis, IN, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] 配位化学を活用したキラル分子プログラミング2013

    • Author(s)
      三宅弘之
    • Organizer
      第20回記念シンポジウム モレキュラー・キラリティー2013
    • Place of Presentation
      京都大学 吉田キャンパス
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 同位体標識質量分析法による光学活性錯体を用いたアミノ酸の光学純度決定2013

    • Author(s)
      中小路崇
    • Organizer
      第20回記念シンポジウム モレキュラー・キラリティー2013
    • Place of Presentation
      京都大学 吉田キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] TPEN-希土類錯体を活用したアミノ酸アニオンのキラルセンシング2013

    • Author(s)
      國屋拓郎
    • Organizer
      第20回記念シンポジウム モレキュラー・キラリティー2013
    • Place of Presentation
      京都大学 吉田キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 錯体ヘリシティーの反転スイッチング;錯体から錯体へのキラル情報の伝達2013

    • Author(s)
      三宅弘之
    • Organizer
      第10回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      和歌山大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] CD法を活用したTPEN-Nd(III)錯体によるアミノ酸アニオンのキラリティーセンシング2013

    • Author(s)
      三宅弘之
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 外部刺激応答性キラル金属錯体を末端に含むトリス (2,2'-ビピリジン)金属錯体のアロステリックなヘリシティー反転2013

    • Author(s)
      三宅弘之
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] キラルな錯体を活用した動的分子スイッチの開発~キラル情報の伝達・増幅・変換2012

    • Author(s)
      三宅弘之
    • Organizer
      錯体化学若手の会近畿地区勉強会
    • Place of Presentation
      大学利用施設UNITY、神戸
    • Year and Date
      2012-12-08
    • Related Report
      2013 Final Research Report
  • [Presentation] Coordination Chemistry-Based Approach for Dynamic Helicates2012

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Department of Chemistry
    • Place of Presentation
      Faculty of Science, Chulalongkorn University, THAILAND
    • Year and Date
      2012-10-25
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Molecular Programming of Helicity Inversion in Coordination Chemistry2012

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Department of Chemistry
    • Place of Presentation
      Wayne State University, USA
    • Year and Date
      2012-06-08
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Stimuli-Responsive Dynamic Molecular Motions in Chiral Metal Complexes2012

    • Author(s)
      H. Miyake and H. Tsukube
    • Organizer
      International Conference on Emerging Advanced Nanomaterials 2012 (ICEAN-2012)
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Invited
  • [Presentation] Helicity Switching Of Dynamic Metal Complexes Toward Supramolecular Synthesis2012

    • Author(s)
      H. Miyake^, and H. Tsukube
    • Organizer
      IUPAC 8th International Conference on Novel Materials and their Synthesis (NMS-VIII) & 22^<nd> International Symposium on Fine Chemistry and Functional Polymers (FCFP-XXII)
    • Place of Presentation
      Xi'An, P. R. China
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Microwave Assisted Direct Syntheses of Optically Active Metal Complexes with Kinetically Inert Metal Centers2012

    • Author(s)
      H. Miyake, M. Ueda, S. Murota, H. Sugimoto, H. Tsukube
    • Organizer
      62^<nd> JSCC Symposium
    • Place of Presentation
      Toyama
    • Related Report
      2013 Final Research Report
  • [Presentation] Enantioselective binding characteristics of amino acid to chiral copper(II) complex using electrospray ionization mass spectrometry coupling with the deuterium-labeled method2012

    • Author(s)
      T. Nakakoji, H. Sato, H. Miyake, H. Kawasaki, R. Arakawa, D. Ono, H. Tsukube, M. Shizuma
    • Organizer
      19th International Mass Spectrometry Conference (IMSC2012)
    • Place of Presentation
      Kyoto International Conference Center, Kyoto, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Helicity Inversion in a Square Planar Pd(II) Complex2012

    • Author(s)
      H. Miyake and H. Tsukube
    • Organizer
      The 24th International Symposium on Chirality (Chirality 2012)
    • Place of Presentation
      Fort Worth, Texas, USA
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Dendrimeric Array of Chiral Metal Complexes : Chirality Integration and Dynamic Inversion2012

    • Author(s)
      H. Miyake, T. Sakamoto, K. Ohara, K. Yamaguchi, H. Tsukube
    • Organizer
      Symposium on Molecular Chirality ASIA 2012
    • Place of Presentation
      Centennial Hall Kyushu University School of Medicine, Fukuoka, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of a Diastereomer Pair of Square Planar Palladium(II) Complex and its Helicity Inversion2012

    • Author(s)
      H. Miyake, M. Ueda, S. Murota, H. Tsukube
    • Organizer
      Symposium on Molecular Chirality ASIA 2012
    • Place of Presentation
      Centennial Hall Kyushu University School of Medicine, Fukuoka, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of a Diastereomer Pair of Square Planar Palladium(II) Complex and its Helicity Inversion2012

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      Symposium on Molecular Chirality ASIA 2012
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Dendrimeric Array of Chiral Metal Complexes: Chirality Integration and Dynamic Inversion2012

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      Symposium on Molecular Chirality ASIA 2012
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Enantioselective binding characteristics of amino acid to chiral copper(II) complex using electrospray ionization mass spectrometry coupling with the deuterium-labeled method2012

    • Author(s)
      Takashi Nakakoji
    • Organizer
      19th International Mass Spectrometry Conference (IMSC2012)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Microwave Assisted Direct Syntheses of Optically Active Metal Complexes with Kinetically Inert Metal Centers2012

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      62nd JSCC Symposium
    • Place of Presentation
      Toyama, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Helicity Switching Of Dynamic Metal Complexes Toward Supramolecular Synthesis2012

    • Author(s)
      Hiroyuki Miyake
    • Organizer
      IUPAC 8th International Conference on Novel Materials and their Synthesis (NMS-VIII) & 22nd International Symposium on Fine Chemistry and Functional Polymers (FCFP-XXII)
    • Place of Presentation
      Xi’An, China
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] ナフチルアミド末端を含む多座配位子からなるZn(II)錯体:単核/六核錯体の変換スイッチング2012

    • Author(s)
      三宅弘之
    • Organizer
      第9回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      北海道大学
    • Related Report
      2012 Research-status Report
  • [Presentation] キラルTPEN-Eu(III)錯体を用いたアミノ酸基質の不斉認識2012

    • Author(s)
      三宅弘之
    • Organizer
      第9回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      北海道大学
    • Related Report
      2012 Research-status Report
  • [Presentation] TPEN-Eu(III)錯体を活用したアミノ酸誘導体の不斉認識:キラリティーの導入によるバイアス効果の検討2012

    • Author(s)
      三宅弘之
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 光学活性四座配位子を有する銅錯体へのアミノ酸のエナンチオ選択的錯形成挙動2012

    • Author(s)
      中小路崇
    • Organizer
      第23回基礎有機化学討論会
    • Place of Presentation
      京都テルサ
    • Related Report
      2012 Research-status Report
  • [Presentation] 光学活性銅錯体のアミノ酸に対する光学異性体識別:マススペクトル法によるアプローチ2012

    • Author(s)
      中小路崇
    • Organizer
      日本油学会フレッシュマンサミットOSAKA2012
    • Place of Presentation
      近畿大学
    • Related Report
      2012 Research-status Report
  • [Presentation] キラルな錯体を活用した動的分子スイッチの開発~キラル情報の伝達・増幅・変換2012

    • Author(s)
      三宅弘之
    • Organizer
      錯体化学若手の会近畿地区勉強会
    • Place of Presentation
      大学利用施設 UNITY、神戸
    • Related Report
      2012 Research-status Report
    • Invited
  • [Book] Synergy in Supramolecular Chemistry, (ed) T. Nabeshima, Supramolecular chemistry strategies for naked-eye detection and sensing2014

    • Author(s)
      K. Singh, P. Kaur, H. Miyake and H. Tsukube
    • Total Pages
      400
    • Publisher
      CRC Press
    • Related Report
      2013 Final Research Report
  • [Book] Synergy in Supramolecular Chemistry2014

    • Author(s)
      Tatsuya Nabeshima
    • Publisher
      CRC Press
    • Related Report
      2013 Annual Research Report
  • [Book] 無機化学演習-大学院入試問題を中心に(化学演習シリーズ7)2012

    • Author(s)
      中沢浩、西岡孝訓、篠田哲史、廣津昌和、三宅弘之(板崎真澄共著、中沢浩編)
    • Total Pages
      215
    • Publisher
      東京化学同人
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.sci.osaka-cu.ac.jp/chem/func/FC/Top.html

    • Related Report
      2013 Final Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi