| Project/Area Number |
24655081
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|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Osaka University |
|---|
Principal Investigator |
TAKESHI Naota 大阪大学, 大学院・基礎工学研究科, 教授 (20164113)
|
|---|
| Project Period (FY) |
2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
|
|---|
| Keywords | 渡環型錯体 / 金属水素相互作用 / 分子内C-H活性化 / 白金 |
|---|
| Research Abstract |
Transition metal complexes with “picnic basket” shaped structures bearing bridged polymethylene unit were prepared. Regioselective intramolecular CH-metal (d orbital) interaction was observed. Remote controlling of the position of C-H activation can be performed by tuning of methylene spacer length and the structure of ligands.
|
