Synthesis and reaction of optical active azahelicene
| Project/Area Number |
24655086
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyushu Institute of Technology |
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Principal Investigator |
KITAMURA MITSURU 九州工業大学, 工学(系)研究科(研究院), 准教授 (10313199)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | ヘリセン / らせん不斉 |
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| Research Abstract |
Efficient asymmetric reactions have been developed, in which central chiral or axial chiral asymmetric reagents have been used commonly. However there are few reports on the asymmetric reaction using helical chiral reagents. Azahelicene is one of the good candidate for the asymmetric reactions as a new helical chiral source. We archived the synthesis of new helical compounds, pseudo azahelicendiols.
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Report
(3 results)
Research Products
(4 results)
