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Synthesis and reaction of optical active azahelicene

Research Project

Project/Area Number 24655086
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionKyushu Institute of Technology

Principal Investigator

KITAMURA MITSURU  九州工業大学, 工学(系)研究科(研究院), 准教授 (10313199)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsヘリセン / らせん不斉
Research Abstract

Efficient asymmetric reactions have been developed, in which central chiral or axial chiral asymmetric reagents have been used commonly. However there are few reports on the asymmetric reaction using helical chiral reagents. Azahelicene is one of the good candidate for the asymmetric reactions as a new helical chiral source. We archived the synthesis of new helical compounds, pseudo azahelicendiols.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (4 results)

All 2014 2013 Other

All Presentation (3 results) Remarks (1 results)

  • [Presentation] 8,8'-ビキノリンジオールの合成2014

    • Author(s)
      福馬弘章,小林充明,岡内辰夫,北村充
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-03-27
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 7, 7'-置換-8,8'-ビキノリン類の合成2013

    • Author(s)
      福馬弘章,北村充
    • Organizer
      有機合成化学協会九州山口支部第25回若手セミナー
    • Place of Presentation
      福岡
    • Year and Date
      2013-08-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 7, 7'-置換-8,8'-ビキノリン類の合成

    • Author(s)
      福馬弘章,北村充
    • Organizer
      有機合成化学協会九州山口支部第25回若手セミナー
    • Place of Presentation
      福岡
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.che.kyutech.ac.jp/chem27/chem27.html

    • Related Report
      2013 Final Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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