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Syntheses of high-performance polyamides by asymmetric reaction of itaconic acid

Research Project

Project/Area Number 24655099
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

KANEKO Tatsuo  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 准教授 (20292047)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Keywordsポリアミド / イタコン酸 / 重縮合 / ステレオコンプレックス / 高耐熱ポリマー / 高分子合成 / アミノ酸 / ピロリドン / ナイロン / 光学活性
Outline of Final Research Achievements

Bio-based polymers prepared from plant-derived starting-materials are important in the viewpoint of carbon-fixation and renewability. In addition, the bio-based polymers give a new field of functional polymeric materials induced from the specific structures of biomolecules. However the bio-based polymers are not applized very widely because of the low thermal resistance performance. In this project, the polyamides such as NylonTM were newly synthesized one of widely-circulating biomolecules, itaconic acid, and from which we developed high-thermoresistance bioplastics. Moreover the polymers prepared by incorporation of both of L-amino acid and D-amino acid showed a higher crystallization degree, higher thermoresistance, and higher mechanical properties than those prepared by each of L-amino acid and D-amino acid.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (21 results)

All 2015 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 5 results) Presentation (13 results) (of which Invited: 3 results) Book (1 results)

  • [Journal Article] 芳香環/ヘテロ環を有する超高性能バイオプラスチックの開発2015

    • Author(s)
      金子達雄
    • Journal Title

      バイオインダストリー

      Volume: 32 Pages: 12-19

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] ヘテロ環を有する超高性能バイオポリマー材料の開発2015

    • Author(s)
      金子達雄
    • Journal Title

      ペトロテック

      Volume: 38 Pages: 41-46

    • NAID

      40020324883

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] 微生物分子の構造を基盤とする 超高性能バイオプラスチックの分子設計2015

    • Author(s)
      金子達雄
    • Journal Title

      日本素材物性学会学術誌

      Volume: 未定

    • NAID

      130005141302

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Syntheses of rigid-rod but degradable biopolyamides from itaconic acid with aromatic diamines2014

    • Author(s)
      M. A. Ali, S. Tateyama, T. Kaneko
    • Journal Title

      Polym. Degrad. Stabil.

      Volume: 109 Pages: 367-372

    • DOI

      10.1016/j.polymdegradstab.2014.05.031

    • NAID

      120005763994

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] イタコン酸を利用した植物性高耐熱ナイロン2014

    • Author(s)
      立山誠治・Mohammad Asif Ali・金子達雄
    • Journal Title

      Polyfile

      Volume: 51 Pages: 18-21

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Syntheses of rigid-rod but degradable biopolyamides from itaconic acid with aromatic diamines2014

    • Author(s)
      M. ALI, S. Tateyama, T. Kaneko
    • Journal Title

      Polymer Degradation and Stability

      Volume: 106

    • NAID

      120005763994

    • Related Report
      2013 Research-status Report
  • [Journal Article] High-performance Biopolyamides Derived from Itaconic Acid and Their Environmental Corrosion2013

    • Author(s)
      M. ALI, S. Tateyama, Y. Oka, M. Okajima, D. Kaneko, T. Kaneko
    • Journal Title

      Macromolecules

      Volume: 46 Pages: 3719-3725

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Synthesis of high performance environmentally-degradable biopolyamides derived from itaconic acid and their composites with Montmorillonite2014

    • Author(s)
      Mohammad Asif Ali,Nupur Tandon,Seiji Tateyama, Tatsuo Kaneko
    • Organizer
      the 10th SPSJ International Polymer Conference (IPC2014)
    • Place of Presentation
      EPOCAL TSUKUBA(茨城県、つくば市)
    • Year and Date
      2014-12-02 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] High-performance bioplastics from renewable itaconic acid with physically cross-linked hybrids by montmorillonites2014

    • Author(s)
      Mohammad Asif Ali,Nupur Tandon,Seiji Tateyama, Tatsuo Kaneko
    • Organizer
      the 22nd Polymer Networks Group Meeting (PNG) and the 10th Gel Symposium
    • Place of Presentation
      東京大学(東京都、文京区)
    • Year and Date
      2014-11-10 – 2014-11-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Environmentally-corrosive, high-performance biopolyamides derived from itaconic acid and their composites with montmorillonite2014

    • Author(s)
      Mohammad Asif Ali,Nupur Tandon,Seiji Tateyama, Tatsuo Kaneko
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学(長崎県、長崎市)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Environmentally-degradable, High-performance Biopolyamides Derived from Itaconic Acid and their Composites with Montmorillonite2014

    • Author(s)
      Mohammad Asif ALI, Nupur TANDON, Seiji TATEYAMA, Tatsuo KANEKO
    • Organizer
      MACRO2014
    • Place of Presentation
      チェンマイ国際会議場(チェンマイ、タイ)
    • Year and Date
      2014-07-06 – 2014-07-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] High performance green-innovation polymers with photoresponsive functions2014

    • Author(s)
      金子達雄
    • Organizer
      International Symposium for Green-Innovation Polymers (GRIP2014)
    • Place of Presentation
      近江町交流センター(石川県)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Nanohybridization of itaconate bio-derived polypyrrolidones with montmorillonites2013

    • Author(s)
      Nupur TANDON, Mohammad Asif ALI, Seiji TATEYAMA, Tatsuo KANEKO
    • Organizer
      International Symposium on Advanced Materials 2013
    • Place of Presentation
      北陸先端科学技術大学院大学(石川県)
    • Related Report
      2013 Research-status Report
  • [Presentation] Syntheses of itaconate-derived biopolyamides and their high performance Nanocomposites with montmorillonites2013

    • Author(s)
      Nupur Tandon, Mohammad Asif Ali, Seiji Tateyama, Tatsuo Kaneko
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学(石川県)
    • Related Report
      2013 Research-status Report
  • [Presentation] Environmentally-degradable, Bioderived Polyamides Converted from Itaconic Acid Salts with Diamines2012

    • Author(s)
      Mohammad Asif Ali
    • Organizer
      ACS 2012 Rocky Mountain Regional Meeting
    • Place of Presentation
      Denver
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis and Materialization of Bio-based Polyamides from Itaconic Acid2012

    • Author(s)
      Mohammad Asif Ali
    • Organizer
      The 9th SPSJ International Polymer Conference (IPC2012)
    • Place of Presentation
      神戸国際会議場
    • Related Report
      2012 Research-status Report
  • [Presentation] Syntheses of polypyrollidones for itaconic acid bioconjugates with amino acid

    • Author(s)
      Mohammad Asif Ali, Seiji Tateyama, Tatsuo Kaneko
    • Organizer
      日本化学会北陸地区講演会と研究発表会
    • Place of Presentation
      石川ハイテク交流センター(石川県)
    • Related Report
      2013 Research-status Report
  • [Presentation] Nanohybridization of itaconate bioderived polypyrrollidones with Montmorillonite

    • Author(s)
      Nupur Tandon, Mohammad Asif Ali, Seiji Tateyama, Tatsuo Kaneko
    • Organizer
      日本化学会北陸地区講演会と研究発表会
    • Place of Presentation
      石川ハイテク交流センター(石川県)
    • Related Report
      2013 Research-status Report
  • [Presentation] Development of high performance biodegradable plastics from aromatic biomolecules

    • Author(s)
      金子達雄
    • Organizer
      First International Workshop on Corrosion and Protection Materials
    • Place of Presentation
      VAST
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Lignin-mimetic molecular design of functional, biodegradable, aromatic biopolymers

    • Author(s)
      金子達雄
    • Organizer
      The 13th International Symposium on Biomimetic Materials Processing
    • Place of Presentation
      ホテルアソシア高山リゾート
    • Related Report
      2012 Research-status Report
    • Invited
  • [Book] Encyclopedia of Polymeric Nanomaterials "Polyamide syntheses"2015

    • Author(s)
      Mohammad Asif Ali, Tatsuo Kaneko (分担執筆)
    • Publisher
      Springer-Verlag
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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