Approach to Precise Modification of Graphene Surface by Metal Complexes for Properties Control

• Project/Area Number: 24655114
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Single-year Grants
• Research Field: Functional materials chemistry
• Research Institution: University of Tsukuba
• Principal Investigator: NABESHIMA Tatsuya 筑波大学, 数理物質系, 教授 (80198374)
• Project Period (FY): 2012-04-01 – 2014-03-31
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
• Keywords: 超分子化学 / 分子認識 / 芳香族化合物 / 金属錯体 / テルピリジン / ジピリドアクリジン / 白金錯体 / 超分子 / ホスト－ゲスト

Research Abstract

Graphene has recently attracted considerable attention to many researchers in fields not only of basic science such as chemistry and physics but also of applied technology of functional materials including electronic materials. We have synthesized triangular multi-metal complexes and box-shaped metal complexes for modifying graphene surface to prepare more functionalized grapheme derivatives. These two kinds of metal complexes recognize large aromatic compounds probably due to pi-pi interactions and cation-pi interactions. In particular, the triangular ligand and its complex were adsorbed on graphite surface as a model compound for graphene. This method using these metal complexes would open a new way to modify the surface of graphene.

Research Products

• [Journal Article] Dynamic helicity control of single-helical oligooxime metal complexes by coordination of chiral carboxylate ions (2014)
  • Author(s): Sairenji, S.; Akine, S.; Nabeshima, T.
  • Journal Title: Tetrahedron Lett. Volume: 55 Issue: 12 Pages: 1987-1990
  • DOI: 10.1016/j.tetlet.2014.02.009
  • Peer Reviewed
• [Journal Article] Highly-Effective Structural Modulation of Trisaloph Heterotetranuclear Zn3La Complex by Anion Coordination (2014)
  • Author(s): M. Yamamura, M. Iida, K. Kanazawa, M. Sasaki, and T. Nabeshima
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 87 Issue: 2 Pages: 334-340
  • DOI: 10.1246/bcsj.20130243
  • NAID: 130004153268
  • Peer Reviewed
• [Journal Article] Perfect encapsulation of guanidinium ion in a helical trinickel(II) metallocryptand for efficient regulation of helix inversion rate (2014)
  • Author(s): Akine, S.; Miyashita, M.; Piao, S.; Nabeshima, T.
  • Journal Title: Inorg. Chem. Front. Volume: 1 Issue: 1 Pages: 53-57
  • DOI: 10.1039/c3qi00067b
  • Peer Reviewed
• [Journal Article] Dynamic Helicity Control of a Single-Helical Oligooxime Complex and Acid－Base Triggered Repeated Helicity Inversion Mediated by Amino Acids (2014)
  • Author(s): S. Sairenji, S. Akine, and T. Nabeshima
  • Journal Title: Chem. Lett. Volume: 印刷中
  • Peer Reviewed
• [Journal Article] Synthesis of Planar Metal Complexes and the Stacking Abilities of Naphthalenediol-Based Acyclic and Macrocyclic Salen-Type Ligands (2013)
  • Author(s): Akine, S.; Varadi, Z.; Nabeshima, T.
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2013 Issue: 35 Pages: 5987-5998
  • DOI: 10.1002/ejic.201300917
  • Peer Reviewed
• [Journal Article] Stepwise Helicity Inversions by Multisequential Metal Exchange (2013)
  • Author(s): Akine, S.; Sairenji, S.; Taniguchi, T.; Nabeshima, T.
  • Journal Title: J. Am. Chem. Soc. Volume: 135 Issue: 35 Pages: 12948-12951
  • DOI: 10.1021/ja405979v
  • Peer Reviewed
• [Journal Article] Programmed multiple complexation for the creation of helical structures from acyclic phenol-bipyridine oligomer ligands (2013)
  • Author(s): Akine, S.; Nagumo, H.; Nabeshima, T.
  • Journal Title: Dalton Trans. Volume: 42 Issue: 45 Pages: 15974-15986
  • DOI: 10.1039/c3dt51240a
  • Peer Reviewed
• [Journal Article] Cooperative Formation and Functions of Multi-metal Supramolecular Systems (2013)
  • Author(s): T. Nabeshima and M. Yamamura
  • Journal Title: Pure Appl. Chem. Volume: 85 Issue: 4 Pages: 763-776
  • DOI: 10.1351/pac-con-12-08-02
  • Peer Reviewed
• [Journal Article] Cage-like tris(salen)-type metallocryptand for cooperative guest recognition (2013)
  • Author(s): Akine, S.; Piao, S.; Miyashita, M.; Nabeshima, T.
  • Journal Title: Tetrahedron Lett. Volume: 54 Issue: 48 Pages: 6541-6544
  • DOI: 10.1016/j.tetlet.2013.09.098
  • Peer Reviewed
• [Journal Article] Conformational control of electron-rich calix[6]arene skeleton by paraquat recognition (2013)
  • Author(s): Akine, S.; Kusama, D.; Nabeshima, T
  • Journal Title: Tetrahedron Lett Volume: 54 Issue: 3 Pages: 205-209
  • DOI: 10.1016/j.tetlet.2012.10.105
  • Peer Reviewed
• [Journal Article] Luminescent Biscyclometalated Iridium(III) Complex for Selective and Switchable Cu^<2+> Ion Binding in Aqueous Media (2013)
  • Author(s): F. Lu, M. Yamamura, and T. Nabeshima
  • Journal Title: Tetrahedron Lett. Volume: 54 Issue: 8 Pages: 779-782
  • DOI: 10.1016/j.tetlet.2012.11.116
  • Peer Reviewed
• [Journal Article] "Cooperative Formation and Functions of Multi-metal Supramolecular Systems" (2013)
  • Author(s): T. Nabeshima and M. Yamamura
  • Journal Title: Pure Appl. Chem. Volume: -
  • Peer Reviewed
• [Journal Article] Oligometallic Template Strategy for Synthesis of a Macrocyclic Dimer-Type Octaoxime Ligand for Its Cooperative Complexation (2012)
  • Author(s): Akine, S.; Tadokoro, T.; Nabeshima, T
  • Journal Title: Inorg. Chem Volume: 51 Issue: 21 Pages: 11478-11486
  • DOI: 10.1021/ic3012525
  • Peer Reviewed
• [Journal Article] Synthesis and Guest Recognition of Molecular Cleft Consisting of Terpyridine-Pt(Il) Acetylide Complexes (2012)
  • Author(s): T. Nabeshima, Y. Hasegawa, R. Trokowski, and M. Yamamura
  • Journal Title: Terahedron Lett. Volume: 53 Issue: 46 Pages: 6182-6185
  • DOI: 10.1016/j.tetlet.2012.08.116
  • Peer Reviewed
• [Journal Article] α-Bridged BODIPY oligomers with switchable near-IR photoproperties by external-stimuli-induced foldamer formation and disruption (2012)
  • Author(s): 坂本直也
  • Journal Title: Chemical Communications Volume: 48(in press) Issue: 40 Pages: 4818-4820
  • DOI: 10.1039/c2cc17513d
  • Peer Reviewed
• [Journal Article] Photoisomerization Locking of Azobenzene by Formation of a Self-assembled Macrocycle (2012)
  • Author(s): M. Yamamura, Y. Okazaki, and T. Nabeshima
  • Journal Title: Ch em, C ommun. Volume: 48 Issue: 46 Pages: 5724-5726
  • DOI: 10.1039/c2cc18014f
  • Peer Reviewed
• [Journal Article] Hierarchical Helix of Helix in the Crystal: Formation of Variable-Pitch Helical π-Stacked Array of Single-Helical Dinuclear Metal Complexes (2012)
  • Author(s): Akine, S.; Nagumo, H.; Nabeshima, T
  • Journal Title: Inorg. Chem Volume: 51 Issue: 10 Pages: 5506-5508
  • DOI: 10.1021/ic3004273
  • Peer Reviewed
• [Journal Article] Design and controlled emission properties of bioorganometallic compounds composed of uracils and organoplatinum(II) moieties (2012)
  • Author(s): Moriuchi, T.; Sakamoto, Y.; Noguchi, S.; Fujiwara, T.; Akine, S.; Nabeshima, T.; Hirao, T
  • Journal Title: Dalton Trans Volume: 41 Issue: 28 Pages: 8524-8531
  • DOI: 10.1039/c2dt30533j
  • Peer Reviewed
• [Presentation] シリル基の除去反応を活用したらせん型亜鉛多核錯体の動的ヘリシティー反転 (2014)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋(口頭)
• [Presentation] Formation of Pentacenequinone Dimer by Sandwich Complexation with Alkali Metal Ion (2014)
  • Author(s): Yuri Takatsuki, Shigehisa Akine, and Tatsuya Nabeshima
  • Organizer: 2014 CENIDE-CNMM-TIMS Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: Tsinghua University (Hsinchu, Taiwan)
• [Presentation] Multi-step Helicity Inversion of Helical Multinuclear Complex by Stepwise Metal Exchange (2014)
  • Author(s): Shigehisa Akine, Shiho Sairenji, and Tatsuya Nabeshima
  • Organizer: International Symposium on Coordination Programming 2014
  • Place of Presentation: The University of Tokyo (Tokyo)
• [Presentation] シリル基の除去反応を活用したらせん型亜鉛多核錯体の動的ヘリシティー反転 (2014)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学（名古屋）
• [Presentation] アルカリ金属イオンとの錯形成を利用したペンタセンキノン二量体の形成 (2014)
  • Author(s): 高槻百合、秋根茂久、鍋島達弥
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学（名古屋）
• [Presentation] 開口部に架橋ジアミン配位子をもつ新規かご型コバルト三核錯体の合成とゲスト認識 (2014)
  • Author(s): 宮下真人、秋根茂久、鍋島達弥
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学（名古屋）
• [Presentation] Stepwise Helicity Inversion of Helical Complex by Exchange of Constituent Metal Ions (2013)
  • Author(s): Shiho Sairenji, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: The 3rd Gereman-Japan Nanoworkshop
  • Place of Presentation: Tsukuba(poster)
  • Year and Date: 2013-09-03
• [Presentation] Multi-step Helicity Inversion of Helical Oligooxime Complex by Exchange of Constituent Metal Ions (2013)
  • Author(s): Shiho Sairenji, Sigehisa Akine, Tatsuya Nabeshima
  • Organizer: 14th Tetrahedron Symposium -Asia Edition
  • Place of Presentation: Seoul, Korea(poster)
• [Presentation] 複素環を縮環したTrisaloph金属多核錯体の合成と性質 (2013)
  • Author(s): 金澤浩太郎、山村正樹、鍋島達弥
  • Organizer: 第3回CSJ化学フェスタ2013
  • Place of Presentation: 東京(ポスター)
• [Presentation] 複数のフェニル基を導入したビピリジンおよびテルピリジン配位子の合成と錯形成 (2013)
  • Author(s): 小林愛、秋根茂久、鍋島達弥
  • Organizer: 第3回CSJ化学フェスタ2013
  • Place of Presentation: 東京(ポスター)
• [Presentation] 機能性不斉超分子のためのC_<3h>対称Trisalophの合成 (2013)
  • Author(s): 小林佳奈、山村正樹、鍋島達弥
  • Organizer: 第3回CSJ化学フェスタ2013
  • Place of Presentation: 東京(ポスター)
• [Presentation] キラルなカルボン酸イオンの化学変換を活用したらせん型メタロフォルダマーの動的ヘリシティー制御 (2013)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 第24回基礎有機化学討論会
  • Place of Presentation: 東京(口頭)
• [Presentation] 直鎖オリゴオキシムの錯形成によるらせん構造の創製と段階的な金属添加による多段階ヘリシティー反転 (2013)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 第24回基礎有機化学討論会
  • Place of Presentation: 東京(ポスター)
• [Presentation] キラルカウンターイオンの化学変換によるらせん型錯体の動的ヘリシティー制御 (2013)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 第10回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 和歌山(ポスター)
• [Presentation] 化学変換を活用したらせん型ヘキサオキシム多核錯体の動的ヘリシティー制御 (2013)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 草津(口頭)
• [Presentation] π共役系を拡張したTrisaloph金属多核錯体の合成と性質 (2013)
  • Author(s): 金澤浩太郎、飯田昌也、山村正樹、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 草津(口頭)
• [Presentation] Multi-step Helicity Inversion of Helical Oligooxime Complex by Exchange of Constituent Metal Ions (2013)
  • Author(s): Shiho Sairenji, Sigehisa Akine, and Tatsuya Nabeshima
  • Organizer: 14th Tetrahedron Symposium -Asia Edition
  • Place of Presentation: The Ritz-Carlton (Seoul, Korea)
• [Presentation] Development of a rational strategy for helicity inversion of helical metal complexes (2013)
  • Author(s): Shigehisa Akine and Tatsuya Nabeshima
  • Organizer: 4th Asian Conference on Coordination Chemistry
  • Place of Presentation: International Convention Center (Jeju, Korea)
• [Presentation] キラルカウンターイオンの化学変換によるらせん型錯体の動的ヘリシティー制御 (2013)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 第10回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 和歌山大学（和歌山）
• [Presentation] 三つの遷移金属錯体部位をもつメタロクリプタンドの合成と分子認識 (2013)
  • Author(s): 宮下真人、秋根茂久、鍋島達弥
  • Organizer: 第10回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 和歌山大学（和歌山）
• [Presentation] キラルなカルボン酸イオンの化学変換を活用したらせん型メタロフォルダマーの動的ヘリシティー制御 (2013)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 第24回基礎有機化学討論会
  • Place of Presentation: 学習院大学（東京）
• [Presentation] 直鎖オリゴオキシムの錯形成によるらせん構造の創製と段階的な金属添加による多段階ヘリシティー反転 (2013)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 第24回基礎有機化学討論会
  • Place of Presentation: 学習院大学（東京）
• [Presentation] クラウンエーテル部位を導入したペンタセンキノンの合成と錯形成 (2013)
  • Author(s): 高槻百合、秋根茂久、鍋島達弥
  • Organizer: 第3回CSJ化学フェスタ2013
  • Place of Presentation: タワーホール船堀（東京）
• [Presentation] 複素環を縮環したTrisaloph金属多核錯体の合成と性質 (2013)
  • Author(s): 金澤浩太郎、山村正樹、鍋島達弥
  • Organizer: 第3回CSJ化学フェスタ2013
  • Place of Presentation: タワーホール船堀（東京）
• [Presentation] 複数のフェニル基を導入したビピリジンおよびテルピリジン配位子の合成と錯形成 (2013)
  • Author(s): 小林愛、秋根茂久、鍋島達弥
  • Organizer: 第3回CSJ化学フェスタ2013
  • Place of Presentation: タワーホール船堀（東京）
• [Presentation] 三つのsaloph部位を有するニッケル三核メタロクリプタンドの合成とゲスト認識 (2013)
  • Author(s): 宮下真人、秋根茂久、鍋島達弥
  • Organizer: 第3回CSJ化学フェスタ2013
  • Place of Presentation: タワーホール船堀（東京）
• [Presentation] らせん構造をもつニッケル三核メタロクリプタンドの合成と分子認識 (2013)
  • Author(s): 宮下真人、秋根茂久、鍋島達弥
  • Organizer: 錯体化学会第63回討論会
  • Place of Presentation: 琉球大学（沖縄）
• [Presentation] Synthesis of Triangular Trisaloph Zn_7 and Zn_3La Complexes by Utilizing the Template Effect (2012)
  • Author(s): Kotaro Kanazawa, Masaya Iida, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: The 4th Tsukuba-Hsinchu Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: Tsukuba(poster)
• [Presentation] Guest Recognition of Novel Molecular Clefts Bearing Extendedπ-Conjugated Thiolato (dipyridoacridine) Platinum(II) Complex Moieties (2012)
  • Author(s): Yusuke Yamaki, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: The 4th Tsukuba-Hsinchu Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: Tsukuba(poster)
• [Presentation] Multi-step Helicity Inversion of Helical Metallofoldamers by Metal Exchange (2012)
  • Author(s): Shiho Sairenji, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creation of Functional Materials
  • Place of Presentation: Tsukuba(poster)
• [Presentation] Guest Recognition of Molecular Clefts Bearing Extendedπ-Conjugated Thiolato(dipyridoacridine) Platinum(II) Complex Moieties (2012)
  • Author(s): Yusuke Yamaki, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creation of Functional Materials
  • Place of Presentation: Tsukuba(poster)
• [Presentation] 金属イオンをテンプレートとしたTrisaloph金属多核錯体のワンポット合成 (2012)
  • Author(s): 金澤浩太郎、佐々木正男、飯田昌也、山村正樹、鍋島達弥
  • Organizer: 第39回有機典型元素化学討論会
  • Place of Presentation: 盛岡(ポスター)
• [Presentation] 広い共役系を有するチオラト(ジピリドアクリジン)白金(II)錯体部位をもつクレフト型ホストの合成とその分子認識能 (2012)
  • Author(s): 山木裕介、山村正樹、鍋島達弥
  • Organizer: 第2回CSJ化学フェスタ(2012)
  • Place of Presentation: 東京(ポスター)
• [Presentation] らせん型ヘキサオキシム金属錯体を利用したヘリシティー制御・反転システム (2012)
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山(口頭)
• [Presentation] チオラト(ジピリドアクリジン)白金(II)錯体部位をもつクレフト型ホストの合成とその分子認識能 (2012)
  • Author(s): 山木裕介、山村正樹、鍋島達弥
  • Organizer: 第6回バイオ関連化学シンポジウム
  • Place of Presentation: 札幌(ポスター)
• [Presentation] ヘキサ-peri-ヘキサベンゾコロネン骨格をもつ大環状ホスト分子による芳香族化合物の認識 (2012)
  • Author(s): 小沼孝大、秋根茂久、鍋島達弥
  • Organizer: 第9回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 札幌(ポスター)
• [Presentation] Stepwise Helicity Inversion of Helical Complex by Exchange of Constituent Metal Ions
  • Author(s): Shiho Sairenji, Shigehisa Akine, and Tatsuya Nabeshima
  • Organizer: The 3rd Gereman-Japan Nanoworkshop
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Cooperative Functions on the Basis of Synergistic Unique Interactions in Multi-metal Molecular Systems”
  • Author(s): Tatsuya Nabeshima
  • Organizer: The 10th International Conference on Heteroatom Chemistry (ICHAC-10)
  • Place of Presentation: Kyoto University (Kyoto)
  • Invited
• [Presentation] “Isomerization Locking of Azobenzenes Induced by Macrocyclic Structure Formation by Complexation with Boron or Titanium”
  • Author(s): Masaki Yamamura, Yuki Okazaki, Tatsuya Nabeshima
  • Organizer: The 10th International Conference on Heteroatom Chemistry (ICHAC-10) 2012.5.21 Kyoto University (Kyoto)
  • Place of Presentation: Kyoto University (Kyoto)
• [Presentation] “Cooperative Functions of Artificial Molecular Architectures”
  • Author(s): Tatsuya Nabeshima
  • Organizer: 2nd German-Japanese Workshop: Nanomaterials for Energy Applications
  • Place of Presentation: Directions to the Fraunhofer-inHaus-Center (Duisburg, Germany)
  • Invited
• [Presentation] “Cooperative and Responding Functions of Supramolecular Metallo-systems”
  • Author(s): Tatsuya Nabeshima
  • Organizer: Lecture at Chemistry Department of RWTH Aachen University
  • Place of Presentation: RWTH Aachen University (Aachen, Germany)
  • Invited
• [Presentation] “Strategic Helicity Control of Helical Metal Complexes by Molecular Leverage”
  • Author(s): Shigehisa Akine, Sayaka Hotate, Tatsuya Nabehisma
  • Organizer: The 40 International Conference on Coordination Chemistry (ICCC40)
  • Place of Presentation: Valencia Conference Centre (Valencia, Spain)
• [Presentation] “Unique Properties and Functions of Multi‐Nuclear Complexes Consisting of Oligo‐N2O2 Ligands”
  • Author(s): Tatsuya Nabeshima
  • Organizer: The 2012 International Conference on Emerging Advanced Nanomaterials (ICEAN)
  • Place of Presentation: Mercure Hotel (Brisbane, Australia)
  • Invited
• [Presentation] “Hypercoordinate Group-14 (Si, Ge, and Sn) Complexes of N2O2-type Dipyrrins: Strong Fluorescence and Regulation of the Optical Properties”
  • Author(s): Masaki Yamamura, Chusaku Ikeda, Naoya Sakamoto, Tatsuya Nabeshima, Marcel Albrecht, Markus Albrecht
  • Organizer: 4th Asian Silicon Symposium (ASiS-4)
  • Place of Presentation: Tsukuba International Congress Center (Tsukuba)
• [Presentation] “Synthesis, Structure and Luminescent Properties of Hypercoordinate Germanium Complexes of N2O2-type Dipyrrins”
  • Author(s): Hiroyuki Takizawa, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: 4th Asian Silicon Symposium (ASiS-4)
  • Place of Presentation: Tsukuba International Congress Center (Tsukuba)
• [Presentation] ”Helicity Control of Helical Metal Complexes by Molecular Leverage Mechanism”
  • Author(s): Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: The Twelfth International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-12)
  • Place of Presentation: RIHGA Royal Hotel Kyoto (Kyoto)
• [Presentation] “Red/Near-infrared Fluorescent Ar,O-BODIPY Dyes Bearing a Water-soluble Tag: Their Application to Cellar Staining”
  • Author(s): Masaki Yamamura, Shinya Yazaki, Michio Shimamura, Tatsuya Nabeshima
  • Organizer: The First International Symposium on Biofunctional Chemistry (ISBC2012)
  • Place of Presentation: Tokyo Institute of Technology (Tokyo)
• [Presentation] “Multi-step Helicity Inversion of Helical Metallofoldamers by Metal Exchange”
  • Author(s): Shiho Sairenji, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creation of Functional Materials
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Fluorescent Dipyrrin-Aluminum Complexes (ALDIPY) Having a Cation-Recognition Site”
  • Author(s): Junji Uchida, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creation of Functional Materials
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Synthesis of Cage-like Trisaloph Metallohost and Guest Recognition”
  • Author(s): Masato Miyashita, Shigehisa Akine, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creation of Functional Materials
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Guest Recognition of Molecular Clefts Bearing Extended π-Conjugated Thiolato(dipyridoacridine) Platinum(II) Complex Moieties”
  • Author(s): Yusuke Yamaki, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: 3rd International Symposium on Creation of Functional Materials
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Typical Element Complexes of π-Conjugated Dipyrrin Ligands: Highly Luminescent Materials Responsive to an External Environment”
  • Author(s): Masaki Yamamura, Naoya Sakamoto, Chusaku Ikeda, Tatsuya Nabeshima
  • Organizer: The 4th Tsukuba-Hsinchu Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Cellular Staining Using Red/Near-infrared Fluorescent BODIPYs Bearing a Water-soluble Tag”
  • Author(s): Masaki Yamamura, Michio Shimamura, Shinya Yazaki, Tatsuya Nabeshima
  • Organizer: The 4th Tsukuba-Hsinchu Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Luminescent Biscyclometalated Iridium(III) complex for Selective and Switchable Detection of Cu2+ Ion in Aqueous Media”
  • Author(s): Fengniu Lu, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: The 4th Tsukuba-Hsinchu Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Synthesis and Spectral Properties of Acridine-based π-Conjugated Oligomers”
  • Author(s): Seira Ikuma, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: The 4th Tsukuba-Hsinchu Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Synthesis and Cation Recognition of N2O2-type Dipyrrin Aluminum Complex (ALDIPY)”
  • Author(s): Junji Uchida, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: The 4th Tsukuba-Hsinchu Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Synthesis of Triangular Trisaloph Zn7 and Zn3La Complexes by Utilizing the Template Effect”
  • Author(s): Kotaro Kanazawa, Masaya Iida, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: The 4th Tsukuba-Hsinchu Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] “Guest Recognition of Novel Molecular Clefts Bearing Extended π-Conjugated Thiolato (dipyridoacridine) Platinum(II) Complex Moieties”
  • Author(s): Yusuke Yamaki, Masaki Yamamura, Tatsuya Nabeshima
  • Organizer: The 4th Tsukuba-Hsinchu Joint Symposium on Interdisciplinary Nano-Science and Technology
  • Place of Presentation: University of Tsukuba (Tsukuba)
• [Presentation] 「ジアンモニウム認識を駆動力とするらせん型錯体のヘリシティー制御」
  • Author(s): 秋根茂久、保立さやか、鍋島達弥
  • Organizer: 第9回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 北海道大学（札幌）
• [Presentation] 「ヘキサ-peri-ヘキサベンゾコロネン骨格をもつ大環状ホスト分子による芳香族化合物の認識」
  • Author(s): 小沼孝大、秋根茂久、鍋島達弥
  • Organizer: 第9回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 北海道大学（札幌）
• [Presentation] 「チオラト(ジピリドアクリジン)白金(II)錯体部位をもつクレフト型ホストの合成とその分子認識能」
  • Author(s): 山木裕介、山村正樹、鍋島達弥
  • Organizer: 第6回バイオ関連化学シンポジウム
  • Place of Presentation: 北海道大学（札幌）
• [Presentation] 「分子認識部位を導入した新規トリポダンドの合成と機能」
  • Author(s): 奥原昂、山村正樹、鍋島達弥
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都テレサ（京都）
• [Presentation] 「チオフェン部位を有する新規BODIPY誘導体の合成と光学特性」
  • Author(s): 瀧澤浩之、山村正樹、鍋島達弥
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都テレサ（京都）
• [Presentation] 「ジピリンアルミニウム錯体(ALDIPY)を基本骨格とするホストの合成と光学特性制御」
  • Author(s): 内田純二、大長真奈美、山村正樹、鍋島達弥
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都テレサ（京都）
• [Presentation] 「かご型trisalophメタロホストの合成とゲスト認識」
  • Author(s): 宮下真人、秋根茂久、鍋島達弥
  • Organizer: 第23回基礎有機化学討論会
  • Place of Presentation: 京都テレサ（京都）
• [Presentation] 「らせん型ヘキサオキシム金属錯体を利用したヘリシティー制御・反転システム」
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 錯体化学会第62回討論会
  • Place of Presentation: 富山大学（富山）
• [Presentation] 「窒素含有共役系有機分子を吸着させたグラファイト表面の局所電子状態観察」
  • Author(s): 岩竹啓吾、秋葉千聖、張嘉文、難波江裕太、柿本雅明、山村正樹、鍋島達弥、近藤剛弘、中村潤児
  • Organizer: 第110回触媒討論会
  • Place of Presentation: 九州大学（福岡）
• [Presentation] 「グラファイト表面に吸着した窒素含有有機化合物のSTM/STS観測」
  • Author(s): 秋葉千聖、岩竹啓吾、森戸裕二郎、郭東輝、張嘉文、難波江裕太、柿本雅明、鍋島達弥、近藤剛弘、中村潤児
  • Organizer: 第110回触媒討論会
  • Place of Presentation: 九州大学（福岡）
• [Presentation] 「チオフェン部位を有する新規N2O2型ジピリンホウ素錯体の合成と光学特性」
  • Author(s): 瀧澤浩之、山村正樹、鍋島達弥
  • Organizer: 第2回CSJ化学フェスタ(2012)
  • Place of Presentation: 東京工業大学（東京）
• [Presentation] 「認識部位を有するジピリンアルミニウム錯体(ALDIPY)の合成と光学特性制御」
  • Author(s): 内田純二、山村正樹、鍋島達弥
  • Organizer: 第2回CSJ化学フェスタ(2012)
  • Place of Presentation: 東京工業大学（東京）
• [Presentation] 「広い共役系を有するチオラト(ジピリドアクリジン)白金(II)錯体部位をもつクレフト型ホストの合成とその分子認識能」
  • Author(s): 山木裕介、山村正樹、鍋島達弥
  • Organizer: 第2回CSJ化学フェスタ(2012)
  • Place of Presentation: 東京工業大学（東京）
• [Presentation] “Recognition of Amphiphilic Acylglucoside Derived from Helicobacter Pylori by C-type Lectin Receptor Mincle”（口頭）
  • Author(s): Masahiro Nagata, Michio Shimamura, Eri Ishikawa, Shigenori Nagai, Tatsuya Nabeshima, Shigeo Koyasu, Sho Yamasaki
  • Organizer: 第41回日本免疫学会学術集会
  • Place of Presentation: 神戸国際会議場（神戸）
• [Presentation] “Recognition of Amphiphilic Acylglucoside Derived from Helicobacter Pylori by C-type Lectin Receptor Mincle”（ポスター）
  • Author(s): Masahiro Nagata, Michio Shimamura, Eri Ishikawa, Shigenori Nagai, Tatsuya Nabeshima, Shigeo Koyasu, Sho Yamasaki
  • Organizer: 第41回日本免疫学会学術集会
  • Place of Presentation: 神戸国際会議場（神戸）
• [Presentation] 「高配位ジピリン14族元素錯体の合成と光学特性制御」（口頭）
  • Author(s): 瀧澤浩之、坂本直也、山村正樹、鍋島達弥
  • Organizer: 第39回有機典型元素化学討論会
  • Place of Presentation: いわて県民情報センター（盛岡）
• [Presentation] 「高配位ジピリン14族元素錯体の合成と光学特性制御」(ポスター)
  • Author(s): 瀧澤浩之、坂本直也、山村正樹、鍋島達弥
  • Organizer: 第39回有機典型元素化学討論会
  • Place of Presentation: いわて県民情報センター（盛岡）
• [Presentation] 「金属イオンをテンプレートとしたTrisaloph金属多核錯体のワンポット合成」
  • Author(s): 金澤浩太郎、佐々木正男、飯田昌也、山村正樹、鍋島達弥
  • Organizer: 第39回有機典型元素化学討論会
  • Place of Presentation: いわて県民情報センター（盛岡）
• [Presentation] 「エチニル架橋アクリジンオリゴマーの合成と性質」
  • Author(s): 伊熊征良、山村正樹、鍋島達弥
  • Organizer: 第39回有機典型元素化学討論会
  • Place of Presentation: いわて県民情報センター（盛岡）
• [Presentation] 「協同的・相乗的機能をもつ分子システムの設計と合成」
  • Author(s): 鍋島達弥
  • Organizer: ナノ・バイオサイエンス研究センター start-up講演会
  • Place of Presentation: 同志社大学（京田辺）
  • Invited
• [Presentation] 「化学変換を活用したらせん型ヘキサオキシム多核錯体の動的ヘリシティー制御」
  • Author(s): 西連地志穂、秋根茂久、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学（草津）
• [Presentation] 「空気中で安定な四座配位ジピリン白金錯体の中性ラジカルの合成」
  • Author(s): 瀧澤浩之、山村正樹、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学（草津）
• [Presentation] 「オリゴチオフェン部位を有するN2O2型BODIPY誘導体の合成と光学特性」
  • Author(s): 瀧澤浩之、山村正樹、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学（草津）
• [Presentation] 「ホスフェート部位を有するpH応答性ジピリン誘導体」
  • Author(s): 瀧澤浩之、山村正樹、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学（草津）
• [Presentation] 「認識部位にキノリノールを有する発光性N2O2型ジピリン錯体のカチオン認識」
  • Author(s): 内田純二、山村正樹、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学（草津）
• [Presentation] 「π共役系を拡張したTrisaloph金属多核錯体の合成と性質」
  • Author(s): 金澤浩太郎、飯田昌也、山村正樹、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学（草津）
• [Presentation] 「らせん構造をもつクリプタンド型Trisalophメタロホストの合成とゲスト認識」
  • Author(s): 宮下真人、秋根茂久、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学（草津）
• [Presentation] 「動的な大環状錯体の形成に伴うアゾベンゼンの異性化挙動の制御」
  • Author(s): 山川紘司、山村正樹、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学（草津）
• [Presentation] 「チオフェン架橋ジピリンオリゴマーの合成と分光特性」
  • Author(s): 齋野奏輔、山村正樹、鍋島達弥
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学（草津）
• [Book] Synergy in Supramolecular Chemistry (2014)
  • Author(s): Nabeshima, T.
  • Publisher: CRC Press
• [Book] "Synergy and Cooperativity in Multi-metal Supramolecular Systems","Synergy in Supramolecular Chemistry", Chapter 1, ed. by Nabeshima
  • Author(s): Nabeshima, Tatsuya
  • Publisher: CRC Press(in press)
• [Remarks]
  • URL: http://www.chem.tsukuba.ac.jp/nabesima/
• [Remarks] 筑波大学数理物質系 超分子化学研究室
  • URL: http://www.chem.tsukuba.ac.jp/nabesima/
• [Remarks] 筑波大学数理物質系 超分子化学研究室
  • URL: http://www.chem.tsukuba.ac.jp/nabesima/