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Construction of organic optical switching device by using light driven reversible aggregation conversion

Research Project

Project/Area Number 24655124
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionOsaka University

Principal Investigator

TOHNAI NORIMITSU  大阪大学, 工学(系)研究科(研究院), 准教授 (30346184)

Co-Investigator(Renkei-kenkyūsha) HISAKI Ichiro  大阪大学, 大学院工学研究科, 助教 (90419466)
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords結晶工学 / 光スイッチング / フォトクロミック / 有機塩 / 超分子複合体
Research Abstract

Tuning the optical properties of luminscent materials by external stimuli has been intensively studied because of their ability for various devices, such as sensors and optical media. However, practical example of changing optical properties by light stimuli is challenging. In this context, we prepared organic crystals from anthracenedisulfonic acids and photochromic thymine arranges and reversibly modulate optical properties by UV irradiation. The organic salt can incorporate several organic solvents and emits various fluorescence depending on guest solvents.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (25 results)

All 2014 2013 2012 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (14 results) (of which Invited: 4 results) Remarks (1 results)

  • [Journal Article] Water inclusion as a trigger for modulation of anthracene arrangement and fluorescence emission of organic salt2014

    • Author(s)
      Sugino Misa, Hatanaka Keisuke, Miyano Tetsuya, Hisaki Ichiro, Miyata Mikiji, Sakon Aya, Uekusa Hidehiro, Tohnai Norimitsu
    • Journal Title

      Tetrahedron Lett.

      Volume: 55 Issue: 3 Pages: 732-736

    • DOI

      10.1016/j.tetlet.2013.12.005

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Amphiphilic Inclusion Spaces for Various Guests and Regulation of Fluorescence Intensity of 1,8-Bis(4-aminophenyl)anthracene Crystals2014

    • Author(s)
      Sugino Misa, Hatanaka Keisuke, Araki Yusuke, Hisaki Ichiro, Miyata Mikiji, Tohnai Norimitsu
    • Journal Title

      Chem. - Eur. J.

      Volume: 20 Issue: 11 Pages: 3069-3076

    • DOI

      10.1002/chem.201304541

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Engineering Switchable Rotors in Molecular Crystals with Open Porosity2014

    • Author(s)
      Comotti Angiolina, Bracco Silvia, Yamamoto Atsushi, Beretta Mario, Hirukawa Tomofumi, Tohnai Norimitsu, Miyata Mikiji, Sozzani Piero
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 2 Pages: 618-621

    • DOI

      10.1021/ja411233p

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Role-allocated Combination of Two Types of Hydrogen Bonds toward Constructing Breathing Diamondoid Porous Organic Salt2013

    • Author(s)
      Atsushi Yamamoto, Tetsuya Hasegawa, Tomoya Hamada, Tomofumi Hirukawa, Ichiro Hisaki, Mikiji Miyata, Norimitsu Tohnai
    • Journal Title

      Chem. Eur. J

      Volume: 19 Issue: 9 Pages: 3006-3016

    • DOI

      10.1002/chem.201202959

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Dynamically Deformable Cube-like Hydrogen Bonding Network in Water-responsive Diamondoid Porous Organic Salts2013

    • Author(s)
      Atsushi Yamamoto, Tomoya Hamada, Ichiro Hisaki, Mikiji Miyata, Norimitsu Tohnai
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 52 Issue: 6 Pages: 1709-1712

    • DOI

      10.1002/anie.201208153

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] A facile and versatile approach to efficient enhancement of solid-state luminescence by organic-inorganic hybrid salts2013

    • Author(s)
      Tohnai Norimitsu, Sugino Misa, Araki Yusuke, Hatanaka Keisuke, Hisaki Ichiro, Miyata Mikiji
    • Journal Title

      Dalton Trans.

      Volume: 42 Issue: 45 Pages: 15922-15926

    • DOI

      10.1039/c3dt51422f

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Elucidation of Anthracene Arrangement for Excimer Emission at Ambient Conditions2013

    • Author(s)
      Sugino Misa, Araki Yusuke, Hatanaka Keisuke, Hisaki Ichiro, Miyata Mikiji, Tohnai Norimitsu
    • Journal Title

      Cryst. Growth Des.

      Volume: 13 Issue: 11 Pages: 4986-4992

    • DOI

      10.1021/cg401166v

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Diamondoid Porous Organic Salts towards Applicable Strategy for Construction of Versatile Porous Structures2012

    • Author(s)
      Atsushi Yamamoto, Shinji Uehara, Tomoya Hamada, Mikiji Miyata, Ichiro Hisaki, Norimitsu Tohnai
    • Journal Title

      Cryst. Growth Des.

      Volume: 12 Issue: 9 Pages: 4600-4606

    • DOI

      10.1021/cg300796u

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Supramolecular-Tilt-Chirality on Two-Fold Helical Assemblies2012

    • Author(s)
      Ichiro Hisaki, 他
    • Journal Title

      Chemistry-A European Journal

      Volume: (in press) Issue: 33 Pages: 10066-10073

    • DOI

      10.1002/chem.201200688

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Regulation of π-Stacked Anthracene Arrangement for Fluorescence Modulation of Organic Solid from Monomer to Excited Oligomer Emission2012

    • Author(s)
      Tomoaki Hinoue, Yuta Shigenoi, Misa Sugino, Yuji Mizobe, Ichiro Hisaki, Mikiji Miyata, Norimitsu Tohnai
    • Journal Title

      Chemistry-A European Journal

      Volume: 18 Issue: 15 Pages: 4634-4643

    • DOI

      10.1002/chem.201103518

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 有機塩を用いた超分子的アプローチによる結晶構造制御と機能化2013

    • Author(s)
      藤内謙光
    • Organizer
      第17回液晶化学研究会シンポジウム
    • Place of Presentation
      筑波
    • Year and Date
      2013-06-13
    • Related Report
      2013 Final Research Report
  • [Presentation] 水素結合ネットワークを利用した多孔質有機塩(POSs)の構築とそのゲスト依存的発光特性2013

    • Author(s)
      浜田智也・山本淳志・藤内謙光・久木一朗・宮田幹二
    • Organizer
      第62回高分子年次大会
    • Place of Presentation
      京都
    • Year and Date
      2013-05-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 有機結晶のフォトルミネッセンスとその制御2013

    • Author(s)
      藤内謙光
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Year and Date
      2013-03-25
    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Invited
  • [Presentation] Modulation of Emission Process and Molecular Arrangement in Crystal Composed of 9,10-Bisaminophenylanthracene and Mineral Acid2013

    • Author(s)
      Sugino Misa, Tohnai Norimitsu, Hisaki Ichiro, Miyata Mikiji
    • Organizer
      The 21th International Conference on the Chemistry of the Organic Solid State (ICCOSS XXI)
    • Place of Presentation
      Oxford, UK
    • Related Report
      2013 Annual Research Report
  • [Presentation] Fluorescent Color Modulation of Organic Solids by Regulation of π-Stacked Stilbene Arrangements2013

    • Author(s)
      Chien-Chih Chen, Tohnai Norimitsu, Hisaki Ichiro, Miyata Mikiji
    • Organizer
      第62回高分子年次大会
    • Place of Presentation
      京都国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水素結合ネットワークを利用した多孔質有機塩(POSs)の構築と そのゲスト依存的発光特性2013

    • Author(s)
      浜田智也 ・山本淳志・藤内謙光 ・久木一朗・宮田幹二
    • Organizer
      第62回高分子年次大会
    • Place of Presentation
      京都国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 有機塩を用いた超分子的アプローチによる結晶構造制御と機能化2013

    • Author(s)
      藤内謙光
    • Organizer
      第17回液晶化学研究会シンポジウム
    • Place of Presentation
      産業技術総合研究所
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Supramolecular Assemblies and Fluorescence Properties of 9,10-Anthracene Derivative in Inclusion Crystals2012

    • Author(s)
      N. Tohna, I. Hisaki, M. Miyata
    • Organizer
      Japan-Taiwan Bilateral Workshop on Nano-Science 2012
    • Place of Presentation
      Suita, Osaka、Japan
    • Year and Date
      2012-12-04
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Supramolecular assemblies and photophysical properties of9,10-anthracene derivative in solid state2012

    • Author(s)
      N. TOHNAI, M. SUGINO I. HISAKI, M. MIYATA
    • Organizer
      第61回高分子年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2012-05-29
    • Related Report
      2013 Final Research Report
  • [Presentation] πスタック型ナノクラスターからなるビーズ状超分子の構築と外部刺激応答的固体発光2012

    • Author(s)
      藤内謙光・樋上友亮・久木一朗・宮田幹二
    • Organizer
      第9回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      札幌
    • Year and Date
      2012-05-26
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Fluorescence Tuning System by using Organic Salts composed Anthracene Disulfonic Acid (ADS) and Primary Alkyl Amines in Crystalline State2012

    • Author(s)
      N. Tohnai, I. Hisaki, M. Miyata
    • Organizer
      XXIV IUPAC Photochemistry
    • Place of Presentation
      Coimbra
    • Related Report
      2012 Research-status Report
  • [Presentation] Supramolecular Assemblies and Fluorescence Properties of 9,10-Anthracene Derivative in Inclusion Crystals2012

    • Author(s)
      N. Tohnai, I. Hisaki, M. Miyata
    • Organizer
      Japan-Taiwan Bilateral Workshop on Nano-Science 2012
    • Place of Presentation
      Osaka
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] "Supramolecular assemblies and photophysical properties of9,10-anthracene derivative in solid state"2012

    • Author(s)
      N. TOHNAI, M. SUGINO I. HISAKI, M. MIYATA
    • Organizer
      第61回高分子年次大会
    • Place of Presentation
      横浜
    • Related Report
      2012 Research-status Report
  • [Presentation] Fluorescence Tuning System by using Organic Salts composed Anthracene Disulfonic Acid (ADS) and Primary Alkyl Amines in Crystalline State

    • Author(s)
      N. Tohnai, I. Hisaki, M. Miyata
    • Organizer
      XXIV IUPAC Photochemistry
    • Place of Presentation
      Coimbra,Portugal
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.mls.eng.osaka-u.ac.jp/~mol_rec/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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