| Project/Area Number |
24655126
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials chemistry
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| Research Institution | Kobe University |
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Principal Investigator |
MOCHIDA Tomoyuki 神戸大学, 理学(系)研究科(研究院), 教授 (30280580)
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| Co-Investigator(Kenkyū-buntansha) |
KUWAHARA Daisuke 電気通信大学, 研究設備センター, 准教授 (50270468)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | イオン液体 / 金属錯体 / 触媒 / メタロセン |
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| Research Abstract |
This study aims at developing liquid catalysts having ionic conductivity. By applying the molecular design that we developed earlier, a variety of ionic liquids were prepared from metal complexes having catalytic activities.
First, Ru-containing ionic liquids were prepared from arene-Ru complexes bearing various bidentate ligands. These salts exhibited high catalytic activities toward the oxidation of alcohols, but the complexes were found to undergo gradual decomposition during the reaction. Second, Cu-containing ionic liquids were prepared from Cu complexes bearing tripod ligands. Ligands containing alkyl-imidazole moieties were designed. Cu(I) complexes were highly unstable; however, Cu(II) complexes were isolated as solids or highly viscous liquids.
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