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High pressure properties of organic molecules obtained by the confinement into the interlayer spaces of inorganic nanosheets

Research Project

Project/Area Number 24655131
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionYamaguchi University

Principal Investigator

JUN Kawamata  山口大学, 医学(系)研究科(研究院), 教授 (40214689)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords無機ナノシート / 無機層状化合物 / 粘土鉱物 / 高圧物性 / 蛍光
Outline of Final Research Achievements

Conformation of an organic molecule is flattened when the molecule is confined in the interlayer space of inorganic nanosheets. Similar flattening of an organic molecule was reported when the high pressure field was applied to the solution of the molecule. In this study, the corresponding pressure applied to an organic molecule confined in the interlayer space of nanosheets was estimated. As a result, the molecule was found to be at a high pressure field corresponded to ~ 1 GPa. Based on this result, strategies for controlling the high pressure field applied to the molecules confined in the interlayer space of inorganic nanosheets have been established. By employing the other type of nanosheet or by varying loading level of the organic molecule, the high pressure field could be tuned from 0.5 to 1.8 GPa.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (37 results)

All 2015 2014 2013 2012 Other

All Journal Article (12 results) (of which Peer Reviewed: 10 results) Presentation (22 results) (of which Invited: 5 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Temperature and concentration dependence of J-aggregate of a cyanine dye in a Laponite film fabricated by Langmuir-Blodgett technique2015

    • Author(s)
      S. Chakraborty, D. Bhattacharjee, H. Soda, M. Tominaga, Y. Suzuki, J. Kawamata, S. A. Hussain
    • Journal Title

      Applied Clay Science

      Volume: 104 Pages: 245-251

    • DOI

      10.1016/j.clay.2014.11.039

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 合成サホナイトの層間に取り込まれたシアセチレン誘導体の二光子吸収特性2015

    • Author(s)
      富永亮、杉原寛之、持田修平、谷誠治、鈴木康孝、川俣純
    • Journal Title

      粘土科学

      Volume: 53 Pages: 63-67

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 無機層状化合物の層間に取り込まれた有機化合物の光物性2014

    • Author(s)
      富永亮、鈴木康孝、 川俣純
    • Journal Title

      化学工業

      Volume: 65 Pages: 962-966

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Two-photon absorotion properties of acetylene derivative confined in the interlayer space of a smectite2014

    • Author(s)
      Y. Suzuki, H. Sugihara, K. Satomi, M. Tominaga, S. Mochida, J. Kawamata
    • Journal Title

      Appl. Clay Sci.

      Volume: 印刷中 Pages: 2895-290

    • DOI

      10.1016/j.clay.2014.01.014

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 粘土/有機化合物ハイブリットの光学デバイスへの応用2014

    • Author(s)
      Y. Suzuki, J. Kawamata
    • Journal Title

      Journal of the Society of Inorganic Materials, Japan

      Volume: 21 Pages: 61-67

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 粘土鉱物の層間に取り込まれた有機化合物の機能性2014

    • Author(s)
      川俣純、鈴木康孝
    • Journal Title

      化学と教育

      Volume: 62 Pages: 108-111

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] THIRD ORDER NONLINEAR OPTICAL PROPERTIES OF A J-AGGREGATED CYANINE DYE INTERCALATED IN SAPONITE2013

    • Author(s)
      Y. Suzuki, Y. Tenma, Y. Nishioka, M. Tominaga, S. Tani, J. Kawamata
    • Journal Title

      Clay Science

      Volume: 17 Pages: 41-45

    • NAID

      110009614921

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Two-Photon Absorption (TPA) Spectra of Tris(4, 7-diphenyl-1, 10-phenantholine)- metal(II) Perchlorate : Drastic Effects of Central Metal(II) Ions on TPA CrossSection2013

    • Author(s)
      H. Moritomo, K. Nakagawa. H. Sugihara, Y. Suzuki, J. Kawamata
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 4 Pages: 441-443

    • DOI

      10.1246/cl.131110

    • NAID

      130004868068

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 粘土鉱物/有機化合物ハイブリッドによる非線形光学材料の創製2013

    • Author(s)
      川俣純
    • Journal Title

      粘土科学

      Volume: 51 Pages: 12-14

    • Related Report
      2012 Research-status Report
  • [Journal Article] Efficient Nonliner Optical Properties of Dyes Confiend in Interlayer Nanospaces of Clay Minerals2012

    • Author(s)
      Yasutaka Suzuki
    • Journal Title

      Chemistry an Asian Journal

      Volume: 7 Issue: 6 Pages: 1170-1179

    • DOI

      10.1002/asia.201200049

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Novel Moleculer Design Strategy for Eficient Two-Photon Absorption Materials2012

    • Author(s)
      Jun Kawamata
    • Journal Title

      Current Pharmaceutical Biotechnology

      Volume: 13 Pages: 2569-2574

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Incorporation of Cationic Electron Donor of Ni-pyridyltetrathiafulvalene with Anionic Electron Acceptor of Polyoxometalate2012

    • Author(s)
      Ryo Tsunashima, Takumi Matsumoto, Kei Kondo, Yoshihiko Suyama, Yukihiro Nishioka, Jun Kawamata, Shin-ichiro Noro, Takayoshi Nakamura, Tomoyuki Akutagawa , Katsuya Ishiguro
    • Journal Title

      Dalton Transactions.

      Volume: 41 Issue: 33 Pages: 10060-10064

    • DOI

      10.1039/c2dt30398a

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 水の加除により蛍光色が制御できる粘土鉱物-有機化合物-ポリマー三元系ハイブリッド膜2015

    • Author(s)
      富永亮、鬼木悠大、鈴木康孝、川俣純
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジアセチレン誘導体の粘土層間での二光子吸収挙動2015

    • Author(s)
      鈴木康孝、持田修平、里見浩一郎、杉原寛之、富永亮、川俣純
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 棒状カチオン分子の粘土層間における蛍光量子収率2014

    • Author(s)
      持田修平、姫野大輔、斎藤貴子、鈴木康孝、谷誠治、川俣純
    • Organizer
      山口大学と九州工業大学の光機能材料開発
    • Place of Presentation
      山口大学(山口市)
    • Year and Date
      2014-12-12 – 2014-12-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] スメクタイト系粘土鉱物の層間に取り込まれた有機化合物が示す特異的な光物性2014

    • Author(s)
      川俣純
    • Organizer
      山口大学と九州工業大学の光機能材料開発
    • Place of Presentation
      山口大学(山口市)
    • Year and Date
      2014-12-12 – 2014-12-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 粘土層間におけるスチルベン誘導体のソルバトクロミズム2014

    • Author(s)
      持田修平、富永亮、中村亜衣、鈴木康孝、川俣純
    • Organizer
      2014年日本化学会中四国支部大会
    • Place of Presentation
      山口大学(山口市)
    • Year and Date
      2014-11-08 – 2014-11-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 粘土層間に取り込まれた有機化合物の有機溶媒の添加による発光色の制御2014

    • Author(s)
      富永亮、中村亜衣、鈴木康孝、川俣純
    • Organizer
      第58回粘土化学討論会
    • Place of Presentation
      福島市A・O・Z
    • Year and Date
      2014-09-24 – 2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 粘土層間に取り込まれた棒状分子の蛍光特性2014

    • Author(s)
      富永亮、持田修平、中村亜衣、鈴木康孝、川俣純
    • Organizer
      日本化学会「低次元系光機能材料研究会」第3回サマーセミナー「無機-有機複合材料の光科学と新展開」
    • Place of Presentation
      佐渡島開発総合センター
    • Year and Date
      2014-09-02 – 2014-09-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Enhanced Two-Photon Absorption Cross-Sections of Organic Compounds Confined in Interlayer Spaces of Clay Minerals2013

    • Author(s)
      J. Kawamata
    • Organizer
      International Conference on Photochemistry
    • Place of Presentation
      Leuven (ベルギー)
    • Related Report
      2013 Research-status Report
  • [Presentation] 無機ナノシート層間に取り込まれた有機化合物の光物性2013

    • Author(s)
      川俣純
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(草津)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 粘土鉱物に取り込まれたアセチレン化合物の分子振動2013

    • Author(s)
      鈴木康孝
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(草津)
    • Related Report
      2012 Research-status Report
  • [Presentation] 粘土層間に取り込まれたビフェニル誘導体の有機溶媒による電子的性質のスイッチング2013

    • Author(s)
      富永亮
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(草津)
    • Related Report
      2012 Research-status Report
  • [Presentation] Nonlinear Optical Properties of Organic Material2013

    • Author(s)
      Jun Kawamata
    • Organizer
      International Conference of Material Science 2013
    • Place of Presentation
      トリプラ大学(インド)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 粘土層間に取り込まれた有機分子に作用する一軸性圧力への層間水の効果2012

    • Author(s)
      富永亮
    • Organizer
      第2回CSJ化学フェスタ2012
    • Place of Presentation
      東京工業大学(大岡山)
    • Related Report
      2012 Research-status Report
  • [Presentation] HIGH-PRESSURE FIELD APPLIED TO A BIPHENYL DERIVATIVE INTERCALATED INTO AN INTERLAYER SPACE OF CLAY MINERALS2012

    • Author(s)
      Makoto Tominaga
    • Organizer
      The 2nd Asian Clay Conference
    • Place of Presentation
      Ewha Womans University (Seoul)
    • Related Report
      2012 Research-status Report
  • [Presentation] Switchable electronic property of a biphenyl derivative intercalated into a clay mineral

    • Author(s)
      M. Tominaga, Y. Nishioka, Y. Suzuki, S. Tani, J. Kawamata
    • Organizer
      XV International Clay Conference
    • Place of Presentation
      Rio de Janeiro (ブラジル)
    • Related Report
      2013 Research-status Report
  • [Presentation] Enhanced two-photon absorption coefficient of organic dyes incorporated into saponite

    • Author(s)
      Y. Suzuki, J. Kawamata
    • Organizer
      XV International Clay Conference
    • Place of Presentation
      Rio de Janeiro (ブラジル)
    • Related Report
      2013 Research-status Report
  • [Presentation] 粘土-ビフェニル誘導体-ポリマーの三成分から成るハイブリッドの示すメカノクロミズム

    • Author(s)
      松尾英明、富永亮、綱島亮、鈴木康孝、川俣純
    • Organizer
      日本化学会「低次元系光機能材料研究会」第2回 サマーセミナー
    • Place of Presentation
      にぎたつ会館(松山市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Enhanced fluorescent quantum efficiencies of acetylene derivatives intercalated in clay minerals

    • Author(s)
      S. Mochida, Y. Suzuki, S. Tani, J. Kawamata
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 近赤外発光型高効率二光子励起蛍光化合物を用いた生細胞イメージング

    • Author(s)
      川俣純、鈴木康孝
    • Organizer
      第10回バイオオプティクス研究会
    • Place of Presentation
      東京農工大学(小金井市)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] スメクタイト系粘土鉱物に取り込まれたジフェニルアセチレン誘導体の二光子吸収特性

    • Author(s)
      里見浩一郎、杉原寛之、持田修平、斎藤貴子、鈴木康孝、川俣純
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 圧力応答蛍光特性を示す粘土鉱物-ビフェニル誘導体-ポリマー三元系ハイブリッド膜

    • Author(s)
      富永亮、松尾英明、中村亜衣、鈴木康孝、川俣純
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 無機層状化合物に取り込まれた有機化合物の機能

    • Author(s)
      川俣純
    • Organizer
      物質・デバイス領域共同研究拠点」研究会
    • Place of Presentation
      北海道大学(札幌)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Book] 『革新機能材料の開発と応用展開 -粘土鉱物、ナノシート、メソ孔シリカと有機層状材料を利用して- 』、第2章2012

    • Author(s)
      鈴木康孝
    • Total Pages
      10
    • Publisher
      シーエムシー出版
    • Related Report
      2012 Research-status Report
  • [Remarks] 山口大学 理学部 生物・化学科 物性化学研究室

    • URL

      http://web.cc.yamaguchi-u.ac.jp/~solid/

    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 圧力感知材料、その製造方法、及び圧力感知塗料2013

    • Inventor(s)
      川俣純、鈴木康孝、松尾英明、富永亮、綱島亮
    • Industrial Property Rights Holder
      国立大学法人 山口大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-185648
    • Filing Date
      2013-09-06
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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