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Challenge for Construction of Metal Organic Frameworks with Photosensitizer and Application as New Solid Catalysts

Research Project

Project/Area Number 24655134
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionKyushu University

Principal Investigator

HISAEDA Yoshio  九州大学, 工学研究院, 教授 (70150498)

Co-Investigator(Renkei-kenkyūsha) ABE Masaaki  九州大学, 大学院・工学研究院, 准教授 (90260033)
SHIMAKOSHI Hisashi  九州大学, 大学院・工学研究院, 准教授 (00284539)
Project Period (FY) 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Keywords機能触媒 / 多孔性錯体 / 光増感剤 / ビタミンB / 脱ハロゲン化反応 / 1,2-転位反応 / 金属錯体 / 光増感作用 / ビタミンB12 / 固体触媒 / 官能基1,2-転位反応
Research Abstract

The chemistry of metal-organic frameworks (MOFs) has evolved rapidly in recent years. Most MOF research has focused on storage and separation of small gaseous molecules by taking advantage of their high microporosities. However, numerous recent reports have demonstrated that active functional groups can be incorporated into MOFs to create hybrid materials with applications. At the same time, vitamin B12 and its derivatives are used as efficient catalysts for a number of chemical transformations due to their rich redox and coordination chemistry. To develop the advantage of MOFs and B12, we adopt absorption method that enables immobilization of vitamin B12 derivatives into the MOFs which has photo-physicochemical property, then to catalyze the reaction. In this study, a novel photosensitive Ru-MOF was synthesized and Ru-MOF-B12 compound was explored for the dechlorination reaction and 1,2-migration reaction in the solid states.

Report

(2 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • Research Products

    (16 results)

All 2013 2012 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (10 results) (of which Invited: 3 results) Remarks (2 results)

  • [Journal Article] Dechlorination of DDT Catalyzed by Visible-Light-Driven System Composed of Vitamin B_<12> Derivative and Rhodamine B2013

    • Author(s)
      K. Tahara, K. Mikuriya, T. Masuko, J. Kikuchi, Y. Hisaeda
    • Journal Title

      J. Porphyr. Phthalocya

      Volume: Vol.17, No.1-2 Issue: 01n02 Pages: 135-141

    • DOI

      10.1142/s1088424612501398

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bioinspired catalytic reactions with vitamin B12 derivative and photosensitizers2013

    • Author(s)
      Y. Hisaeda, K. Tahara, H. Shimakoshi, T. Masuko
    • Journal Title

      Pure and Applied Chemistry

      Volume: 85 Issue: 7 Pages: 1415-1426

    • DOI

      10.1351/pac-con-12-10-05

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bioinspired Catalytic Reactions with Vitamin B12 Derivative and Photosensitizers2013

    • Author(s)
      Y. Hisaeda
    • Journal Title

      Pure. Appl. Chem.

      Volume: -

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and photosensitizing properties of porphycene with imidazolium tag2012

    • Author(s)
      Hisashi Shimakoshi, Kenichi Sasaki, Yusuke Iseki, Yoshio Hisaeda
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 16 Issue: 05n06 Pages: 530-536

    • DOI

      10.1142/s1088424612500551

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Presentation] Photochemical Oxygen Activation by Molybdenum Porphycene Complex2012

    • Author(s)
      Hisaeda, Y
    • Organizer
      7th International Conference on Porphyrins and Phthalocyanines(ICPP-7)
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2012 Final Research Report
  • [Presentation] Bioinsspired Catalysts with Vitamin B_12Enzyme Functions2012

    • Author(s)
      Hisaeda, Y
    • Organizer
      XXIVth IUPAC Symposium on Photochemistry
    • Place of Presentation
      Coimbra, Portugal
    • Related Report
      2012 Final Research Report
  • [Presentation] Bioinspired Catalysts with Photosensitizers2012

    • Author(s)
      Hisaeda, Y
    • Organizer
      The International Symposium on Preparative Chemistry of Advanced Materials-2012
    • Place of Presentation
      Shenyang, China
    • Related Report
      2012 Final Research Report
  • [Presentation] 光で動くバイオインスパイアード触媒--物質変換と環境浄化への挑戦--2012

    • Author(s)
      久枝良雄
    • Organizer
      熊本大学理学部 特別講演
    • Place of Presentation
      熊本
    • Related Report
      2012 Final Research Report
  • [Presentation] 酵素に学ぶ触媒設計:バイオインスパイアード触媒物質変換と環境浄化への挑戦2012

    • Author(s)
      久枝良雄
    • Organizer
      広島大学理学部 特別講演
    • Place of Presentation
      広島
    • Related Report
      2012 Final Research Report
  • [Presentation] Photochemical Oxygen Activation by Molybdenum Porphycene Complex2012

    • Author(s)
      Yoshio Hisaeda
    • Organizer
      第7回ポルフィリンおよびフタロシアニンに関する国際会議(ICPP-7)
    • Place of Presentation
      韓国・済州国際コンベンションセンター
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Bioinspired catalytic reactions with photosensitizers2012

    • Author(s)
      Yoshio Hisaeda
    • Organizer
      第24回国際応用化学連合 光化学シンポジウム(XXIV IUPAC)
    • Place of Presentation
      ポルトガル・コインブラ大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Bioinspired Catalysts with Vitamin B12 Derivative and Photosensitizer2012

    • Author(s)
      Yoshio Hisaeda
    • Organizer
      9th JCSMCC(第9回日中クラスター会議)
    • Place of Presentation
      ヒルトン福岡シーホークホテル
    • Related Report
      2012 Annual Research Report
  • [Presentation] Bioinspired Catalysts with Photosensitizers2012

    • Author(s)
      Yoshio Hisaeda
    • Organizer
      The International Symposium on Preparative Chemistry of Advanced Materials-2012
    • Place of Presentation
      中国・瀋陽・遼寧大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Bioinspired Catalysts with Vitamin B12 Function2012

    • Author(s)
      Yoshio Hisaeda
    • Organizer
      第12回国際有機化学京都会議(IKCOC-12)
    • Place of Presentation
      京都市・リーガロイヤルホテル京都
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.kyushu-u.ac.jp/~hisaeda/

    • Related Report
      2012 Final Research Report
  • [Remarks] 久枝研究室 HISAEDA's Laboratory

    • URL

      http://www.chem.kyushu-u.ac.jp/~hisaeda/

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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