| Project/Area Number |
24655135
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional materials chemistry
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| Research Institution | Institute for Molecular Science |
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Principal Investigator |
MASAOKA Shigeyuki 分子科学研究所, 生命・錯体分子科学研究領域, 准教授 (20404048)
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| Co-Investigator(Renkei-kenkyūsha) |
KONDO Mio 分子科学研究所, 生命・錯体分子科学研究領域, 助教 (20619168)
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| Research Collaborator |
YOSHIDA Masaki
NAKAMURA Go
OKAMURA Masaya
ITOH Takahiro
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 金属錯体 / 再生可能エネルギー / 超分子 / 二次元集積 / 多電子移動反応 |
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| Outline of Final Research Achievements |
Artificial photosynthesis is a solar energy conversion technology that mimics natural photosynthesis, and considered to be one of the next big breakthroughs in energy. In this work, we have investigated the development of two-dimensional reaction fields for artificial photosynthesis via self-assembly of metal complexes. Two approaches have been performed: (i) self-assembly of catalytic active metal complexes into lipid bilayer membranes, and (ii) self-assembly of catalytic active metal complexes with intermolecular pi-pi interaction sites. In both approaches, target two-dimensional structures have been successfully developed and their catalytic activities for various multi-electron transfer reactions have been evaluated.
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