| Project/Area Number |
24655138
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Environmental chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
KONDO Teruyuki 京都大学, 先端医工学研究ユニット, 教授 (20211914)
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| Co-Investigator(Renkei-kenkyūsha) |
WADA Kenji 香川大学, 医学部, 教授 (10243049)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | 二酸化炭素 / 均一系触媒 / ケテン / ギ酸アミド / 一酸化炭素 / フラノン / キナゾリノン / 複素環化合物 / イッテルビウム / アミノベンズアミド / ルテニウム / ロジウム / 付加環化反応 |
|---|
| Research Abstract |
In this study, ruthenium-catalyzed intermolecular [2 + 2 + 1] cocyclization of ketenes, alkynes, and carbon monoxide to 2-furanones has been developed. In addition, 4(3H)-quinazolinones were obtained in high yield by catalytic N-heterocyclization of 2-aminobenzamides with formamides. It is considered that both reactions develop into the new reactions, in which carbon dioxide may be used as an effective carbon resource in the future.
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