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Development of an Environmentally Friendly Process for Direct Synthesis of Phenol

Research Project

Project/Area Number 24655144
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Environmental chemistry
Research InstitutionShibaura Institute of Technology

Principal Investigator

TAJIMA Toshiki  芝浦工業大学, 工学部, 准教授 (50361770)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords有機工業化学 / グリーンケミストリー
Research Abstract

In order to develop an environmentally friendly process for direct synthesis of phenol, anodic oxidation of benzene in the presence of water was investigated using the concept of site isolation. However, the desired phenol was not obtained at all. On the other hand, it was found that anodic oxidation of benzene in 1,1,1,3,3,3-hexafluoro-2-propanol generates the corresponding polyphenylene films on the anode surface.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (9 results)

All 2014 2013 Other

All Presentation (9 results)

  • [Presentation] ポリフェニレン膜の電解合成とその光学特性2014

    • Author(s)
      安藤拓海,吉井広人,田嶋稔樹
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Electropolymerization of Benzene in Hexafluoro-2-propanol2013

    • Author(s)
      Hiroto Yoshii, Takumi Ando, Toshiki Tajima
    • Organizer
      The 4th German-Japanese Symposium on Electrosynthesis
    • Place of Presentation
      京都大学
    • Year and Date
      2013-12-03
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] ヘキサフルオロイソプロパノール中でのポリフェニレンの電解合成2013

    • Author(s)
      吉井広人,安藤拓海,田嶋稔樹
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2013-09-28
    • Related Report
      2013 Final Research Report
  • [Presentation] ヘキサフルオロイソプロパノール中でのベンゼンの電解重合における支持塩の影響2013

    • Author(s)
      吉井広人,安藤拓海,田嶋稔樹
    • Organizer
      第37回有機電子移動化学討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2013-06-20
    • Related Report
      2013 Final Research Report
  • [Presentation] ヘキサフルオロイソプロパノール中でのベンゼンの電解重合2013

    • Author(s)
      吉井広人,鈴木賢人,田嶋稔樹
    • Organizer
      電気化学第80回大会
    • Place of Presentation
      東北大学
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 耐酸化性溶媒中でのベンゼンの電解重合2013

    • Author(s)
      吉井広人,鈴木賢人,田嶋稔樹
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      立命館大学
    • Year and Date
      2013-03-22
    • Related Report
      2013 Final Research Report
  • [Presentation] ヘキサフルオロイソプロパノール中でのベンゼンの電解重合における支持塩の影響

    • Author(s)
      吉井広人・安藤拓海・田嶋稔樹
    • Organizer
      第37回有機電子移動化学討論会
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] ヘキサフルオロイソプロパノール中でのポリフェニレンの電解合成

    • Author(s)
      吉井広人・安藤拓海・田嶋稔樹
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] ポリフェニレン膜の電解合成とその光学特性

    • Author(s)
      安藤 拓海・吉井 広人・田嶋 稔樹
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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