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Development of self-organized polymers based on pi-stacking between side chains and their application to organic photovoltaics

Research Project

Project/Area Number 24655183
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Organic industrial materials
Research InstitutionOsaka Prefecture University

Principal Investigator

MAEDA Takeshi  大阪府立大学, 工学(系)研究科(研究院), 助教 (90507956)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords自己組織化 / 自己組織化高分子 / 有機電子材料・素子 / 機能性有機材料 / 染料・顔料 / 色素・色材 / 電気・磁気的機能 / 有機薄膜太陽電池 / 機能性色素 / 自己組織化材料 / 高分子構造・物性 / 太陽電池 / 有機半導体 / スクアリリウム / バルクヘテロ接合型太陽電池 / 近赤外
Research Abstract

Design, synthesis, and aggregation of novel polymers bearing functional dye pendant groups were investigated for electron donor materials in organic photovoltaics. Polymers having branched squaraine dyes as pendant groups were successfully obtained and confirmed to form aggregates between pendant dyes. These polymers exhibited panchromatic property originated from the exiton-coupling between two chromophores in branched dyes as well as between branched dyes in side chains. Conventional bulk heterojunction solar cells based on these polymers as electron donor materials showed wide spectrum response, indicating polymers bearing pendant dyes evidently contributed to the photo-electric conversion in cells.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (37 results)

All 2014 2013 2012 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (24 results) Remarks (3 results)

  • [Journal Article] Squaraine Dyes with Pyrylium and Thiopyrylium Components for Harvest of Near Infrared Light in Dye-Sensitized Solar Cells2014

    • Author(s)
      T. Maeda, S. Nitta, H. Nakao, S. Yagi, H. Nakazumi
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 118 Issue: 30 Pages: 16618-16625

    • DOI

      10.1021/jp412553z

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Linearlyπ-extended squaraine dyes enable the spectral response of dye-sensitized solar cells in the NIR region over 800 nm2013

    • Author(s)
      Maeda, T., Arikawa, S., Nakao, H., Yagi, S., Nakazumi H.
    • Journal Title

      New J. Chem

      Volume: 37

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Conformational effect of symmetrical squaraine dyes on the performance of dye-sensitized solar cells2013

    • Author(s)
      Maeda, T., Mineta, S., Fujiwara, H., Nakao, H., Yagi, S., Nakazumi, H.
    • Journal Title

      J. Mater. Chem. A

      Volume: 1

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared-absorbingπ-Extended Squarylium-based Dyes with Dicyanovinylene Substitution for Dye-sensitized Solar Cell Applications2013

    • Author(s)
      Nakao, H., Maeda, T., Nakazumi, H
    • Journal Title

      Chem. Lett

      Volume: 42

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared-absorbing pi-Extended Squarylium-based Dyes with Dicyanovinylene Substitution for Dye-sensitized Solar Cell Applications2013

    • Author(s)
      H. Nakao, T. Maeda, H. Nakazumi
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 1 Pages: 25-27

    • DOI

      10.1246/cl.2013.25

    • NAID

      130004426724

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Linearly pi-extended Squaraine Dyes Enable the Spectral Response of Dye-sensitized Solar Cells in the NIR Region over 800 nm2013

    • Author(s)
      T. Maeda, S. Arikawa, H. Nakao, S. Yagi, H. Nakazumi
    • Journal Title

      New Journal of Chemistry

      Volume: 37 Issue: 3 Pages: 701-708

    • DOI

      10.1039/c2nj40991g

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Conformational Effect of Symmetrical Squaraine Dyes on the Performance of Dye-sensitized Solar Cells2013

    • Author(s)
      T. Maeda, S. Mineta, H. Fujiwara, H. Nakao, S. Yagi, H. Nakazumi
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 1 Issue: 4 Pages: 1303-1309

    • DOI

      10.1039/c2ta00883a

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Squaraine-based Conjugated Polymers with Phenylene Linkers for Bulk Heterojunction Solar Cells2012

    • Author(s)
      Maeda, T., Tsukamoto, T., Seto, A., Yagi, S., Nakazumi, H.
    • Journal Title

      Macromol. Chem. Phys

      Volume: 213

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Squaraine-Based Conjugated Polymers with Phenylene Linkers for Bulk Heterojunction Solar Cells2012

    • Author(s)
      T. Maeda, T. Tsukamoto, A. Seto, S. Yagi, H. Nakazumi
    • Journal Title

      Macromolecular Chemistry and Physics

      Volume: 213 Issue: 24 Pages: 2590-2597

    • DOI

      10.1002/macp.201200382

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Squaraine Dyes with Pyrylium and Thiopyrylium Components for Harvest of Near Infrared Light in Dye-Sensitized Solar Cells

    • Author(s)
      Maeda, T., Nitta, S., Nakao, H., Yagi, S., Nakazumi H.
    • Journal Title

      J. Phys. Chem. C

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] Squarylium Dyes with Branched Structure Applied to Dye-sensitized Solar Cells2013

    • Author(s)
      X. Chen, T. Maeda, S. Yagi, H. Nakazumi
    • Organizer
      85th JSCM Anniversary Conference
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2013-10-25
    • Related Report
      2013 Final Research Report
  • [Presentation] 対称型近赤外吸収スクアリリウム色素の低分子バルクヘテロ接合型太陽電池への応用2013

    • Author(s)
      北川翔一, 前田壮志, 八木繁幸, 中澄博行
    • Organizer
      色材協会創立85周年記念会議
    • Place of Presentation
      タワーホール船堀, 東京都
    • Year and Date
      2013-10-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 種々の複素環を有する新規非対称型スクアリリウム色素の光・電気化学特性と色素増感太陽電池への応用2013

    • Author(s)
      新田翔平, 前田壮志, 八木繁幸, 中澄博行
    • Organizer
      色材協会創立85周年記念会議
    • Place of Presentation
      タワーホール船堀, 東京都
    • Year and Date
      2013-10-24
    • Related Report
      2013 Final Research Report
  • [Presentation] Structure-Property Relationship of Squaraine-Based Dyes for Organic Photovoltaic2013

    • Author(s)
      T. Maeda
    • Organizer
      7th Workshop of Conjugated Oligomers and Polymers from Synthesis to Electronic Function (KOPO2013
    • Place of Presentation
      Zellingen-Retzbach, Germany
    • Year and Date
      2013-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] バルクヘテロ接合型有機太陽電池用の新規カルバゾール架橋ビススクアリリウ系色素の合成およびそのポリマー化2013

    • Author(s)
      吉田圭, 前田壮志, 八木繁幸, 中澄博行
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学, 金沢市
    • Year and Date
      2013-09-12
    • Related Report
      2013 Final Research Report
  • [Presentation] Low Band Gap Polymers Based on Squaraine andπ-conjugated linkers as Electron Donors in Bulk Heterojunction Solar Cells2013

    • Author(s)
      T. Maeda, H. Amitani, T. Tsukamoto, S.Yagi, H. Nakazumi
    • Organizer
      The 11th International Symposium on Functionalπ-Electron Systems
    • Place of Presentation
      Arcachon, France
    • Year and Date
      2013-06-05
    • Related Report
      2013 Final Research Report
  • [Presentation] 種々のスクアリリウム系色素からなるπ共役系高分子の光・電気化学特性2013

    • Author(s)
      網谷仁志, 前田壮志, 八木繁幸, 中澄博行
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館, 京都市
    • Year and Date
      2013-05-30
    • Related Report
      2013 Final Research Report
  • [Presentation] バルクヘテロ接合型太陽電池への応用を指向した対称及び非対称型スクアリリウム色素2013

    • Author(s)
      瀬藤彩加, 前田壮志, 八木繁幸, 中澄博行
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館, 京都市
    • Year and Date
      2013-05-30
    • Related Report
      2013 Final Research Report
  • [Presentation] 色素増感太陽電池への応用を指向した分岐構造を持つパンクロマティックなスクアリリウム系色素2013

    • Author(s)
      宮永恭平, 前田壮志, 八木繁幸, 中澄博行
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学, 草津市
    • Year and Date
      2013-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] Low Band Gap Polymers Based on Squaraine and π-conjugated linkers as Electron Donors in Bulk Heterojunction Solar Cells2013

    • Author(s)
      T. Maeda, H. Amitani, T. Tsukamoto, S.Yagi, H. Nakazumi
    • Organizer
      The 11th International Symposium on Functional π-Electron Systems
    • Place of Presentation
      Arcachon, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structure-Property Relationship of Squaraine-Based Dyes for Organic Photovoltaics2013

    • Author(s)
      T. Maeda
    • Organizer
      7th Workshop of Conjugated Oligomers and Polymers from Synthesis to Electronic Function (KOPO2013)
    • Place of Presentation
      Zellingen-Retzbach, Germany
    • Related Report
      2013 Annual Research Report
  • [Presentation] Squarylium Dyes with Branched Structure Applied to Dye-sensitized Solar Cells2013

    • Author(s)
      X. Chen, T. Maeda, S. Yagi, H. Nakazumi
    • Organizer
      85th JSCM Anniversary Conference
    • Place of Presentation
      タワーホール船堀,東京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] 種々のスクアリリウム系色素からなるπ共役系高分子の光・電気化学特性2013

    • Author(s)
      網谷仁志,前田壮志,八木繁幸,中澄博行
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館,京都市
    • Related Report
      2013 Annual Research Report
  • [Presentation] バルクヘテロ接合型太陽電池への応用を指向した対称及び非対称型スクアリリウム色素2013

    • Author(s)
      瀬藤彩加,前田壮志,八木繁幸,中澄博行
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館,京都市
    • Related Report
      2013 Annual Research Report
  • [Presentation] バルクヘテロ接合型有機太陽電池用の新規カルバゾール架橋ビススクアリリウ系色素の合成およびそのポリマー化2013

    • Author(s)
      吉田 圭,前田壮志,八木繁幸,中澄博行
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学,金沢市
    • Related Report
      2013 Annual Research Report
  • [Presentation] 対称型近赤外吸収スクアリリウム色素の低分子バルクヘテロ接合型太陽電池への応用2013

    • Author(s)
      北川翔一,前田壮志,八木繁幸,中澄博行
    • Organizer
      色材協会創立85周年記念会議
    • Place of Presentation
      タワーホール船堀,東京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] 種々の複素環を有する新規非対称型スクアリリウム色素の光・電気化学特性と色素増感太陽電池への応用2013

    • Author(s)
      新田翔平,前田壮志,八木繁幸,中澄博行
    • Organizer
      色材協会創立85周年記念会議
    • Place of Presentation
      タワーホール船堀,東京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] 色素増感太陽電池への応用を指向した分岐構造を持つパンクロマティックなスクアリリウム系色素2013

    • Author(s)
      宮永恭平,前田壮志,八木繁幸,中澄博行
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学,草津市
    • Related Report
      2012 Research-status Report
  • [Presentation] The Design and Synthesis of Novel Branched Squaryrium Dyes and Their Application to Dye-sensitized Solar Cells2012

    • Author(s)
      K. Miyanaga, T. Maeda, S. Yagi and H. Nakazumi
    • Organizer
      12th International Kyoto Conference on Organic Chemistry (IKCOC 12)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2012-11-13
    • Related Report
      2013 Final Research Report
  • [Presentation] 種々のスクアリリウム発色団を主鎖に有する狭バンドギャップポリマーの合成と有機太陽電池への応用2012

    • Author(s)
      前田壮志, 網谷仁志, 大森拓也, 八木繁幸, 中澄博行
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学, 名古屋市
    • Year and Date
      2012-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] Low Band Gap Polymers Based on Squaraine and Benzodithiophene as Electron Donors in Bulk Heterojunction Solar Cells2012

    • Author(s)
      前田壮志, 大森拓也, 岩田典己, 八木繁幸, 中澄博行
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜, 横浜市
    • Year and Date
      2012-05-30
    • Related Report
      2013 Final Research Report
  • [Presentation] Low Band Gap Polymers Based on Squaraine and Benzodithiophene as Electron Donors in Bulk Heterojunction Solar Cells2012

    • Author(s)
      前田壮志,大森拓也,岩田典己,八木繁幸,中澄博行
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜,横浜市
    • Related Report
      2012 Research-status Report
  • [Presentation] 種々のスクアリリウム発色団を主鎖に有する狭バンドギャップポリマーの合成と有機太陽電池への応用2012

    • Author(s)
      前田壮志,網谷仁志,大森拓也,八木繁幸,中澄博行
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学,名古屋市
    • Related Report
      2012 Research-status Report
  • [Presentation] The Design and Synthesis of Novel Branched Squaryrium Dyes and Their Application to Dye-sensitized Solar Cells2012

    • Author(s)
      K. Miyanaga, T. Maeda, S. Yagi and H. Nakazumi
    • Organizer
      12th International Kyoto Conference on Organic Chemistry (IKCOC 12)
    • Place of Presentation
      リーガロイヤルホテル京都,京都市
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka6/

    • Related Report
      2013 Final Research Report
  • [Remarks] 有機機能化学研究グループHP

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka6/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 有機機能化学研究グループHP

    • URL

      http://www.chem.osakafu-u.ac.jp/ohka/ohka6/index.html

    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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