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Novel strategy to realize high luminance by molecular design of dopant precursor.

Research Project

Project/Area Number 24655189
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

NARUKE Haruo  東京工業大学, 資源化学研究所, 准教授 (40237623)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords量子収率 / 高輝度蛍光体 / 希土類 / アップコンバージョン / 国際情報交換
Outline of Final Research Achievements

Up-conversion phosphors Y2O3:Er,Yb, which convert near-infrared into visible emission, were synthesized from multinuclear lanthanide (Ln) complexes by thermal degradation. This preparation method was employed to control distribution of Er and Yb in the Y2O3 matrix to realize high conversion efficiency. The resultant nano particles with c.a. 50 nm in size exhibited visible luminescence by both 960 nm and 1550 nm excitations. Optimization of the dopant concentration resulted in 2 or 3 times higher luminance than that of samples prepared by conventional methods. Evaluation of luminescence response using a short-pulse laser revealed that composition showing high response differs from the composition showing the highest luminance.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (24 results)

All 2015 2014 2013 2012

All Journal Article (12 results) (of which Peer Reviewed: 12 results,  Open Access: 2 results) Presentation (12 results) (of which Invited: 1 results)

  • [Journal Article] Decisive Interactions between the Heterocyclic Moiety and the Cluster Observed in Polyoxometalate-Surfactant Hybrid Crystals2015

    • Author(s)
      S. Otobe, N. Fujioka, T. Hirano, E. Ishikawa, H. Naruke, K. Fujio and T. Ito
    • Journal Title

      Int. J. Mol. Sci.

      Volume: 16 Issue: 4 Pages: 8505-8516

    • DOI

      10.3390/ijms16048505

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structural Variation in Polyoxomolybdate Hybrid Crystals Comprising Ionic-Liquid Surfactants2014

    • Author(s)
      T. Ito, K. Mikurube, K. Hasegawa, T. Matsumoto, K. Kosaka, H. Naruke, S. Koguchi
    • Journal Title

      Crystals

      Volume: 4 Issue: 1 Pages: 42-52

    • DOI

      10.3390/cryst4010042

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and structural characterization of [CeIV(α2-P2W17O61)2]16- in the solid state and in aqueous solution2013

    • Author(s)
      J. Iijima; H. Naruke
    • Journal Title

      J. Mol. Struct.

      Volume: 1040 Pages: 33-38

    • DOI

      10.1016/j.molstruc.2013.01.067

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hybrid Layered Crystal Comprising Polyoxometalate and Surfactant Synthesized from Reduced Mo-Blue Species2013

    • Author(s)
      K. Mikurube, K. Hasegawa, H. Naruke, T. Ito
    • Journal Title

      J. Chem., 2013

      Volume: Article ID 208075 Issue: 1 Pages: 6-6

    • DOI

      10.1155/2013/208075

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Polyoxomolybdate-Surfactan t Layered Crystals Derived from Long-Tailed Alkylamine and Ionic-Liquid2013

    • Author(s)
      T. Ito, R. Ide, K. Kosaka, S. Hasegawa, K. Mikurube, M. Taira, H. Naruke, S. Koguchi
    • Journal Title

      Chem. Lett.

      Volume: 42 Issue: 11 Pages: 1400-1402

    • DOI

      10.1246/cl.130683

    • NAID

      130004426819

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rubidium pentaaqua(L-serine)cobalt(II) hexahydrogenhexamolybdocobaltate(III) L-serine monosolvate decahydrate2013

    • Author(s)
      J. Iijima, H. Naruke, H. Takiyama
    • Journal Title

      Acta Crystallogr.

      Volume: E69 Issue: 11 Pages: m612-m613

    • DOI

      10.1107/s1600536813028304

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Isolation of enantiopure crystals and spectroscopic properties of a chiral Er-containing polyoxotungstate [Er(α2-P2W17O61)2]17-2012

    • Author(s)
      J. Iijima, H. Naruke, and T. Sanji
    • Journal Title

      Chem. Lett.

      Volume: 41 Pages: 295-297

    • NAID

      130004426533

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of lanthanide decatungstate [LnIII/IV(W5O18)2]8-/9- (Ln= CeIV/III, EuIII, and ErIII) thin-films using a spin-coating from aqueous solutions2012

    • Author(s)
      Y. Fujita, N. Ishihara, K. Fukaya, A. Srifa, and H. Naruke
    • Journal Title

      J. Alloys and Comp.

      Volume: 519 Pages: 136-139

    • DOI

      10.1016/j.jallcom.2011.12.140

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Polyoxotungstate-Surfactant Layered Crystal toward Conductive Inorganic-Organic Hybrid2012

    • Author(s)
      T. Ito, N. Fujimoto, S. Uchida, J. Iijima, H. Naruke, N. Mizuno
    • Journal Title

      Crystals

      Volume: 2 Issue: 2 Pages: 362-373

    • DOI

      10.3390/cryst2020362

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Polyoxovanadate-Surfactant Hybrid Layered Crystal Containing One-Dimensional Infinite Cluster Chain2012

    • Author(s)
      T. Ito, M. Taira, K. Fukumoto, K. Yamamoto, H. Naruke, and K. Tomita
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 85 Pages: 1222-1224

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Luminescence properties of a Nd(III) coumarin derivative complex immobilized in a poly(methylmethacrylate) matrix2012

    • Author(s)
      M. Getsova, V. Kircheva, J. Zaharieva, I. Manolov, H. Naruke, and M. Milanova
    • Journal Title

      Journal of Optoelectronics and Advanced Materials

      Volume: 14 Pages: 685-692

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hybrid layered crystals composed of polyoxoalkoxymetalates and pyridinium surfactants2012

    • Author(s)
      T. Ito, K. Mikurube, M. Taira, H. Yoshioka, and H. Naruke
    • Journal Title

      Polyoxometalate Chemistry

      Volume: 1 Pages: 1-5

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 一欠損型 Keggin 構造を含むサンドイッチ型希土類ポリ酸のエナンチオ選択的単離 -キラリティ制御とラセミ化機構-2015

    • Author(s)
      飯島淳,成毛治朗
    • Organizer
      第 32 回希土類討論会
    • Place of Presentation
      かごしま県民交流センター
    • Year and Date
      2015-05-21 – 2015-05-22
    • Related Report
      2014 Annual Research Report
  • [Presentation] 樹状高分子を鋳型とした量子サイズ金属酸化物クラスターの合成とその基礎物性2015

    • Author(s)
      猪股雄介,アルブレヒト建,成毛治朗,山元公寿
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学理工学部 船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] デカバナジン酸‐双頭型界面活性剤ハイブリッド層状結晶における構造制御2015

    • Author(s)
      田祥生,平良みなこ,成毛治朗,伊藤建
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学理工学部 船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ケギン型ポリ酸とヘテロ環式界面活性剤を用いた無機-有機ハイブリッド層状結晶の合成と結晶構造2015

    • Author(s)
      乙部嵯稀,成毛治朗,藤尾克彦,伊藤建
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学理工学部 船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] フェニルアゾメチンデンドリマーを鋳型に用いた酸化バナジウム(V2O5)ナノ粒子の創製2015

    • Author(s)
      五関高寛,アルブレヒト建,成毛治朗,山元公寿
    • Organizer
      日本化学会第95春季年会(2015)
    • Place of Presentation
      日本大学理工学部 船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 光利用効率の増幅による光触媒環境浄化機能の高度化2014

    • Author(s)
      殷イン, 呉暁勇, 李慧慧, 董強, 成毛治朗, 佐藤次雄
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] フェニルアゾメチンデンドリマーをナノリアクターとした酸化バナジウム (V) ナノ粒子の創製2014

    • Author(s)
      五関高寛・アルブレヒト 建・成毛治朗・山元公寿
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 希土類多核クラスターを用いるアップコンバージョン蛍光体の調製と発光特性2013

    • Author(s)
      成毛治朗
    • Organizer
      第 30 回希土類討論会
    • Place of Presentation
      九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] 希土類多核クラスターを用いるアップコンバージョン蛍光体の調製と発光特性2013

    • Author(s)
      成毛治朗
    • Organizer
      第30回希土類討論会
    • Place of Presentation
      北九州国際会議場(福岡)
    • Related Report
      2012 Research-status Report
  • [Presentation] 希土類を含むポリタングステン酸のキラリティ制御2012

    • Author(s)
      成毛治朗、飯島 淳
    • Organizer
      錯体討論会第62回討論会
    • Place of Presentation
      富山大学(富山)
    • Related Report
      2012 Research-status Report
  • [Presentation] 希土類デカタングステン酸塩コート膜の構造と光学的評価2012

    • Author(s)
      藤田侑介、成毛治朗
    • Organizer
      第29回希土類討論会
    • Place of Presentation
      北海道大学(北海道)
    • Related Report
      2012 Research-status Report
  • [Presentation] アップコンバージョン蛍光体の基礎と開発状況2012

    • Author(s)
      成毛治朗
    • Organizer
      クリーンエネルギー研究推進事業太陽エネルギー利用関連技術分科会
    • Place of Presentation
      三重県工業研究所(三重)
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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