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Foundation of pore size estimation with positronium lifetime and its application

Research Project

Project/Area Number 24655201
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

HYODO Toshio  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 特定教授 (90012484)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords陽電子 / ポジトロニウム / 多孔性材料 / サイズ評価 / シリカエアロゲル / 多孔性物質 / 空孔サイズ
Research Abstract

A shape-free model to be used for the estimation of the pore size has been developed. A basic model in classical picture is modified by introducing a parameter corresponding to an effective size of the positronium (Ps). This parameter is adjusted so that the model merges smoothly with the well-established modified Tao-Eldrup model.
The present model has been applied to silica aerogel, which consists of a three dimensional random network of silica (SiO2) nano-particles. A well-known unresolved issue with this material is that the pore size estimated with standard methods gives macroscopic density inconsistent with that directly measured. In contrast, the quantity estimated with the present model agrees very well with that directly measured. This verifies that the present method gives reliable value for the size of large and complex vacant volume for which the other methods cannot give reliable estimation.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (8 results)

All 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results) (of which Invited: 2 results) Remarks (1 results)

  • [Journal Article] A simple shape-free model for pore-size estimation with positron annihilation lifetime spectroscopy2013

    • Author(s)
      K.Wada, T.Hyodo
    • Journal Title

      J. Phys, : Conf. Series

      Volume: Vol.443 Pages: 12003-1

    • DOI

      10.1088/1742-6596/443/1/012003

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] A simple shape-free model for pore-size estimation with positron annihilation lifetime spectroscopy2013

    • Author(s)
      K. Wada and T. Hyodo
    • Journal Title

      Journal of Physics: Conference Series

      Volume: -

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] A classical-picture- based model for pore-size estimation with PALS analysis2012

    • Author(s)
      K. Wada, T. Hyodo
    • Organizer
      First China-Japan Joint Workshop on Positron Science
    • Place of Presentation
      Wuhan, China
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] A simple shape-free model for pore-size estimation with positron annihilation lifetime spectroscopy2012

    • Author(s)
      K. Wada, T. Hyodo
    • Organizer
      16th International Conference on Positron Annihilation
    • Place of Presentation
      Bristol, U.K
    • Related Report
      2013 Final Research Report
  • [Presentation] ポジトロニウムの寿命測定による空孔サイズ評価の新しいモデル2012

    • Author(s)
      和田健, 兵頭俊夫
    • Organizer
      第49回アイソトープ・放射線研究発表会
    • Place of Presentation
      東京大学
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] A classical-picture-based model for pore-size estimation with PALS analysis2012

    • Author(s)
      K. Wada and T. Hyodo
    • Organizer
      First China–Japan Joint Workshop on Positron Science
    • Place of Presentation
      Wuhan, China
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] A simple shape-free model for pore-size estimation with positron annihilation lifetime spectroscopy2012

    • Author(s)
      K. Wada and T. Hyodo
    • Organizer
      16th International Conference on Positron Annihilation
    • Place of Presentation
      Bristol, U. K.
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://pfwww.kek.jp/slowpos/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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