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Preparation of Anisotropic Hydrogel Particles

Research Project

Project/Area Number 24655206
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionShinshu University

Principal Investigator

SUZUKI Daisuke  信州大学, 繊維学部, 准教授 (90547019)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords高分子微粒子 / 非等方性 / ゲル / 刺激応答性 / 異種ゲル微粒子混合 / 凝集体 / 異符号電荷微粒子 / ピッカリングエマルション
Research Abstract

We report on the preparation of anisotropic hydrogel particles. The hydrogel particles were prepared by aqueous free radical precipitation polymerization using acrylamide-derivatives and crosslinkers. Using the hydrogel particles, anisotropic hydrogel particles were prepared at air/water, oil/water, or solid/water interfaces. We revealed that the obtained hydrogel particles were assembled into chains under the certain conditions. To confirm that the phenomenon is due to the structure of the hydrogel particles, cationic and anionic microgels were mixed in aqueous solution. The oppositely charged hydrogel particles also showed particle-chains. We tried to prepare several types of anisotropic hydrogel particles at the interfaces.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (8 results)

All 2013 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (6 results)

  • [Journal Article] Control of Colloidal Interactions between Microgels with Stimulus Responsive Properties2013

    • Author(s)
      Yoshitaka Umeda and Daisuke Suzuki
    • Journal Title

      Journal of Polymer Science Part A : Polymer Chemistry

      Volume: 51 Issue: 14 Pages: 3021-3026

    • DOI

      10.1002/pola.26706

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Assembly of Oppositely Charged Microgels at the Air/Water Interfacs2013

    • Author(s)
      Daisuke Suzuki, Koji Horigome
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 117 Issue: 30 Pages: 9073-908

    • DOI

      10.1021/jp4035166

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Presentation] 気液界面を活用したゲル微粒子集積体の構築2013

    • Author(s)
      堀込幸司、鈴木大介
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2013-09-20
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 高分子鎖の形態変化に伴うヒドロゲル微粒子の界面動電現象2013

    • Author(s)
      呉羽拓真、青木大地、佐藤高彰、鈴木大介
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2013-09-13
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] ゲル微粒子の精密な構造改質を目指した多角的評価法の検討2013

    • Author(s)
      梅田佳孝、鈴木大介
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2013-05-31
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of Multifunctional Janus Microgels at Water/Oil Interfaces2013

    • Author(s)
      Yoshitaka Umeda and Daisuke Suzuki
    • Organizer
      62th SPSJ Annual Meeting
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2013-05-30
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of Multifunctional Janus Microgels at Water/Oil Interfaces

    • Author(s)
      Yoshitaka Umeda
    • Organizer
      62th SPSJ Annual Meeting
    • Place of Presentation
      京都国際会館
    • Related Report
      2012 Research-status Report
  • [Presentation] ゲル微粒子の精密な構造改質を目指した多角的評価法の検討

    • Author(s)
      梅田佳孝
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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