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Fabrication of extended-chain crystal nanofibers by electrospinning technique

Research Project

Project/Area Number 24655211
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionToyota Technological Institute

Principal Investigator

YOSHIOKA Taiyo  豊田工業大学, 工学(系)研究科(研究院), 研究員 (90596165)

Co-Investigator(Kenkyū-buntansha) TASHIRO Kohji  豊田工業大学, 工学研究科, 教授 (60171691)
Research Collaborator SCHAPER Andreas K.  (ドイツ)マールブルク大学, 材料科学センター, 研究室長
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords電界紡糸 / ナノファイバー / 繊維構造 / 伸びきり鎖結晶
Research Abstract

Electrospinning has been attracting much attention in various fields regarding nanotechnology, in which the nanofibers with highly oriented inner structure, ultimately the extended-chain crystal (ECC), are required to achieve the best performance of mechanical and physical properties. In this study, a novel stretching technique is proposed and applied to polyethylene (PE), and the resultant fiber structure was investigated. In the technique, an electrostatic stretching-force, created by a parallel-electrode collector system, acts on the wet fibers. First, we developed an appropriate spinning system, which enables to make spinning from high-temperature solution stably and to control the evaporation rate of solvent by controlling the environmental temperature. Electron diffraction analysis revealed the formation of highly oriented fiber structure, which is considered to be composed of the ECC mainly. In addition, we have studied the formation mechanism of such highly oriented structure.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (19 results)

All 2014 2013 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 4 results) Presentation (14 results) (of which Invited: 1 results)

  • [Journal Article] in-house Simultaneous Collection of SAXS, WAXD and Raman Scattering Data from Polymeric Materials2014

    • Author(s)
      Raita Hirose, Taiyo Yoshioka, Hiroko Yamamoto, Kummetha Raghunatha Reddy, Daisuke Tahara, Kensaku Hamada and Kohji Tashiro
    • Journal Title

      J. Appl. Crystallogr

      Volume: 47 Issue: 3 Pages: 922-930

    • DOI

      10.1107/s1600576714006724

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Microscopically-viewed relationship between the chain conformation and ultimate Young's modulus of a series of arylate polyesters with long methylene segments2014

    • Author(s)
      Masafumi Tasaki, Hiroko Yamamoto, Taiyo Yoshioka, Makoto Hanesaka, Tran Hai Ninh, Kohji Tashiro, Hye Jin Jeon, Kwang Bok Choi, Hak Seung Jeong, Hyun Hoon Song, Moon Hor Ree
    • Journal Title

      Polymer

      Volume: 55 Issue: 7 Pages: 1799-1808

    • DOI

      10.1016/j.polymer.2014.01.058

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hierarchical Structural Change in the Stress-Induced Phase Transition of Poly(tetramethylene terephthalate) As Studied by the Simultaneous Measurement of FTIR Spectra and 2D Synchrotron Undulator WAXD/SAXS Data2014

    • Author(s)
      Kohji Tashiro, Hiroko Yamamoto, Taiyo Yoshika, Tran Hai Ninh, Masafumi Tasaki, Shigeru Shimada, Takeshi Nakatani, Hiroyuki Iwamoto, Noboru Ohta, Hiroyasu Masunaga
    • Journal Title

      Macromolecules

      Volume: 47 Issue: 6 Pages: 2052-2061

    • DOI

      10.1021/ma402041r

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal structure analyses of arylate polyesters with long methylene segments and their model compounds on the basis of 2-D X-ray diffractions and infrared progression bands2014

    • Author(s)
      Masafumi Tasaki, Hiroko Yamamoto, Taiyo Yoshioka, Makoto Hanesaka, Tran Hai Ninh, Kohji Tashiro, Hye Jin Jeon, Kwang Bok Choi, Hak Seung Jeong, Hyun Hoon Song, Moon Hor Ree
    • Journal Title

      Polymer

      Volume: 55 Issue: 5 Pages: 1228-1248

    • DOI

      10.1016/j.polymer.2014.01.024

    • Related Report
      2013 Final Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal structure analyses of arylate polyesters with long methylene segments and their model compounds on the basis of 2-D X-ray diffractions and infrared progression bands2014

    • Author(s)
      Masafumi Tasaki, Hiroko Yamamoto, Taiyo Yoshioka, Makoto Hanesaka, Tran Hai Ninh, Kohji Tashiro, Hye Jin Jeon, Kwang Bok Choi, Hak Seung Jeong, Hyun Hoon Song, Moon Hor Ree
    • Journal Title

      Polymer

      Volume: 55 Pages: 1228-1248

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 二重配向ポリビニルアルコール高次構造に著しい影響を及ぼす吸収水の効果2013

    • Author(s)
      吉岡太陽, 田代孝二
    • Organizer
      平成25年度繊維学会秋季研究発表会
    • Place of Presentation
      名古屋
    • Year and Date
      2013-09-06
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 固定端乾湿変化に伴う一軸および二重配向PVAおよび再生シルクフィブロインの可逆的構造変化と応力発現に関する研究2013

    • Author(s)
      吉岡太陽, 田代孝二
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2013-05-30
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 赤外スペクトル・WAXD・SAXS 同時測定に基づくポリエチレン等温結晶化過程におけるメルト-六方晶-斜方晶の構造発展ルート検出2013

    • Author(s)
      田代孝二, 山元博子, 吉岡太陽, 中村晃
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2013-05-30
    • Related Report
      2013 Final Research Report
  • [Presentation] 伸びきり鎖結晶からなる電界紡糸ナノ繊維の作製 : ポリエチレンナノ繊維の配向制御2013

    • Author(s)
      吉岡太陽, 田代孝二, Andreas K. SCHAPER
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2013-05-30
    • Related Report
      2013 Final Research Report
  • [Presentation] 周期的乾湿変化過程での伸縮応力、広角小角X線散乱・時分割同時測定に基づく再生シルクフィブロインおよびポリビニルアルコール配向試料の可逆的応力発現と構造変化の相関解明2013

    • Author(s)
      吉岡太陽, 田代孝二
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 長いメチレン連鎖を有するアリレート型ポリエステルの結晶構造と極限ヤング率との関わり : 結晶弾性率の実験ならびに理論計算に基づく考察2013

    • Author(s)
      田崎政文, 山元博子, 吉岡太陽, 田代孝二
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢
    • Related Report
      2013 Final Research Report
  • [Presentation] 透過赤外、放射光広角小角X 線散乱同時測定に基づくPTMT-PTMOマルチブロック共重合体エラストマーの張力誘起結晶相転移と高次構造変化との相関解明2013

    • Author(s)
      田代孝二, 山元博子, 吉岡太陽, 桜井孝至, 増永啓康
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢
    • Related Report
      2013 Final Research Report
  • [Presentation] Reversible Structure Change and the Related Stress Generation of Uniaxially- or Doubly-Oriented Poly(vinyl alcohol) Induced by Cyclic Humidity Change under Fixed-end Condition2013

    • Author(s)
      Taiyo YOSHIOKA, Kohji TASHIRO
    • Organizer
      Third International Conference : Frontiers in Polymer Science
    • Place of Presentation
      Barcelona (Spain)
    • Related Report
      2013 Final Research Report
  • [Presentation] 長いメチレン連鎖を有するアリレート型ポリエステルの結晶構造と極限ヤング率との関わり:結晶弾性率の実験ならびに理論計算に基づく考察2013

    • Author(s)
      田崎政文, 山元博子, 吉岡太陽, 田代孝二 他
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学(金沢)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 透過赤外、放射光広角小角X線散乱同時測定に基づくPTMT-PTMOマルチブロック共重合体エラストマーの張力誘起結晶相転移と高次構造変化との相関解明2013

    • Author(s)
      田代孝二, 山元博子, 吉岡太陽, 桜井孝至, 増永啓康
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢
    • Related Report
      2013 Annual Research Report
  • [Presentation] Reversible Structure Change and the Related Stress Generation of Uniaxially- or Doubly-Oriented Poly(vinyl alcohol) Induced by Cyclic Humidity Change under Fixed-end Condition2013

    • Author(s)
      Taiyo YOSHIOKA, Kohji TASHIRO
    • Organizer
      Third International Conference: Frontiers in Polymer Science
    • Place of Presentation
      Barcelona (Spain)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 赤外スペクトル・WAXD・SAXS同時測定に基づくポリエチレン等温結晶化過程におけるメルト-六方晶-斜方晶の構造発展ルート検出2013

    • Author(s)
      田代孝二, 山元博子, 吉岡太陽, 中村晃
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      横浜
    • Related Report
      2013 Annual Research Report
  • [Presentation] 伸びきり鎖結晶からなる電界紡糸ナノ繊維の作製: ポリエチレンナノ繊維の配向制御2013

    • Author(s)
      吉岡太陽 (豊田工大)、田代孝二(豊田工大)、Andreas K. SCHAPER(Philipps大学)
    • Organizer
      第61回 高分子学会年次大会
    • Place of Presentation
      京都国際会館
    • Related Report
      2012 Research-status Report
  • [Presentation] 再生シルクフィブロインの配向制御 -湿度応答型アクチュエータへの応用-

    • Author(s)
      吉岡太陽
    • Organizer
      農業生物資源研究所主催 第8回フィブロイン・セリシンの利用研究会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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