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Analysis of phase of water produced by cell reaction with a circumstance close to chemical equilibrium

Research Project

Project/Area Number 24656141
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Thermal engineering
Research InstitutionKyushu University

Principal Investigator

ITO Kohei  九州大学, 工学(系)研究科(研究院), 教授 (10283491)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords物質輸送 / 燃料電池 / 気液状態 / 化学平衡 / 気液相状態
Research Abstract

The phase of production water in polymer electrolyte fuel cell (PEFC) is clarified based on the measurement of open circuit voltage (OCV). The measured OCV is corrected with considering short circuit current and Tafel equation, and the comparison between the OCV thus corrected and theoretical OCV determines the water phase if it is liquid or gas. The corrected OCV shows the same tendency with Nernst equation, where higher temperature and humidity decrease the OCV. Especially, the corrected OCV locates within the theoretical equilibrium voltages between gas and liquid production cases, and it approaches the theoretical one in the liquid production case with the increase of the humidity. This characteristics suggest that higher humidity promote the water production in liquid phase. These obtained results are thought to be worth for an optimization of water management required in PEFC.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (4 results)

All 2014 2013 Other

All Journal Article (1 results) Presentation (3 results)

  • [Journal Article] Experimental analysis of the gas humidity impact on open circuit voltage in PEFC2014

    • Author(s)
      Keisuke Adaniya, Chiaki Mizutani, Yusuke Maeda, Hironori Nakajima, Tatsumi Kitahara, Kohei Ito
    • Journal Title

      Proceedings of WHEC2014

    • Related Report
      2013 Final Research Report
  • [Presentation] Experimental analysis of the gas humidity impact on open circuit voltage in PEFC2014

    • Author(s)
      Keisuke Adaniya
    • Organizer
      20th World Hydrogen Energy Conference 2014
    • Place of Presentation
      Gwangju, Korea
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固体高分子形燃料電池内の生成水の平衡電位による相状態調査2013

    • Author(s)
      安谷屋佳祐、水谷千晶、前田祐介、中島裕典、北原辰巳、伊藤衡平
    • Organizer
      熱工学コンフェレンス2013
    • Place of Presentation
      弘前(図書)
    • Related Report
      2013 Final Research Report
  • [Presentation] 固体高分子形燃料電池内の生成水の平衡 電位による相状態調査

    • Author(s)
      安谷屋佳祐
    • Organizer
      熱工学コンフェレンス2013
    • Place of Presentation
      弘前
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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