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Preparation of no amphiphilic monolayer and orientation control of metal catalyst nanoparticles

Research Project

Project/Area Number 24656199
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Research InstitutionChiba University

Principal Investigator

KUSHIDA Masahito  千葉大学, 工学(系)研究科(研究院), 准教授 (70177989)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords燃料電池 / 金属ナノ粒子 / カーボンナノチューブ / 単分子膜 / 低炭素 / 水素燃料 / 配列制御 / 分子エレクトロニクス / 有機超薄膜作製技術 / 金属触媒 / 両親媒性分子 / 水素エネルギー / 低炭素社会 / 垂直配向カーボンナノチューブ / ラングミュア-ブロジェット膜 / 近接場光学 / 機能性有機超薄膜 / 触媒 / ラングミュアーブロジェット膜
Outline of Final Research Achievements

Independently controlling the number density and diameter of Fe nanoparticles (FeNPs) used as a catalyst for vertically aligned carbon nanotube (VA-CNT) growth is difficult by conventional methods. In this study, mixed solutions of no amphiphilic FeNPs and saturated fatty acid used as filler molecules were prepared to prevent the thermal aggregation of FeNPs and control the number density of VA-CNTs. FeNPs mixed with saturated fatty acid monolayer films were prepared on the water surface and deposited on SiO2/Si substrates by the Langmuir-Blodgett (LB) technique. VA-CNTs were synthesized by a thermal chemical vapor deposition method using acetylene gas. By controlling the ratio of FeNP catalyst to saturated fatty acid as a filler molecule in the LB film and optimizing hydrogen reduction condition, we were able to control the number density and diameter of FeNPs independently.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (32 results)

All 2014 2013 2012 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (25 results) (of which Invited: 1 results) Remarks (3 results)

  • [Journal Article] Carbon Nanotube Growth from Langmuir-Blodgett Film Deposited Fe Nanoparticles with Filler Molecules2014

    • Author(s)
      Naoki Kuriyama, Akihiro Takezawa
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 2S Pages: 02BD08-02BD08

    • DOI

      10.7567/jjap.53.02bd08

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and diameter control of vertically-aligned carbon nanotube growth from Langmuir-Blodgett films deposited Fe3O4@SiO22014

    • Author(s)
      Masaaki Oohashi, Takehiro Sugawara, Kohei Kawasaki, Masahito Kushida
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 2S Pages: 02BD09-02BD09

    • DOI

      10.7567/jjap.53.02bd09

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Control of Fe catalyst nanoparticle density for carbon nanotube growth using Langmuir-Blodgett deposition of mixtures of Fe nanoparticles and arachidic acid2014

    • Author(s)
      Akihiro Takezawa, Ryuta Nara, Masahito Kushida
    • Journal Title

      Thin Solid Films

      Volume: 554 Pages: 69-73

    • DOI

      10.1016/j.tsf.2013.06.076

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Fe3O4/SiO2 core-shell nanoparticle monolayer as catalyst for CNT growth using Langmuir-Blodgett technique2013

    • Author(s)
      Masahito Kushida, Tetsuya Koide, Ippei Osada, Yoshiaki Imaizumi, Kouhei Kawasaki, Takehiro Sugawara
    • Journal Title

      Thin Solid Films

      Volume: 537 Pages: 252-255

    • DOI

      10.1016/j.tsf.2013.04.031

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Synthesis of vertically-aligned carbon nanotubes used Fe nanoparticle Langmuir-Blodgett films on Al2O3/SiO2 substrate2014

    • Author(s)
      Syota Takagiwa, O. Kanasugi, K. Nakamura, Masahito Kushida
    • Organizer
      11th International Conference on Nano-Molecular Electronics (ICNME2014)
    • Place of Presentation
      Kobe, JAPAN
    • Year and Date
      2014-12-17 – 2014-12-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] カーボンナノチューブの燃料電池への応用2014

    • Author(s)
      串田正人
    • Organizer
      2014年第2回千葉大学化学教育研究懇談会
    • Place of Presentation
      千葉大学
    • Year and Date
      2014-12-04
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Vertically-aligned carbon nanotube growth from Langmuir-Blodgett deposited Fe or Fe3O4 nanoparticles with palmitic acid2014

    • Author(s)
      Kentarou Nakamura, Naoki Kuriyama, Shota Takagiwa, Masahito Kushida
    • Organizer
      27th International Microprocesses and Nanotechnology Conference (MNC 2014)
    • Place of Presentation
      Fukuoka, JAPAN
    • Year and Date
      2014-11-04 – 2014-11-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] LB法を応用した垂直配向CNTの作製と成長条件の最適化2014

    • Author(s)
      栗山 直樹, 金杉 治, 大橋 正明, 高際 翔太, 中村 健太郎, 串田正人
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Al2O3/SiO2基板上でのFeナノ粒子-LB膜を用いたPEFC用垂直配向CNTの合成2014

    • Author(s)
      高際 翔太, 栗山 直樹, 大橋 正明, 串田 正人
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fe3O4@SiO2型コアシェル粒子を触媒に用いたカーボンナノチューブの合成と構造評価2014

    • Author(s)
      大橋 正明, 栗山 直樹, 金杉 治, 高際 翔太, 串田 正人
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fe3O4@SiO2型コアシェル粒子を触媒に用いたカーボンナノチューブの直径評価2014

    • Author(s)
      大橋正明, 菅原丈博, 金杉治, 高際翔太, 串田正人
    • Organizer
      第61回応用物理学会関係連合講演会講演予稿集
    • Place of Presentation
      青山学院大学, 神奈川県相模原市
    • Related Report
      2013 Research-status Report
  • [Presentation] FeNPs-silicaNPs混合LB膜によるVA-CNT作製および直径評価2014

    • Author(s)
      金杉治, 栗山直樹, 中村健太郎, 串田正人
    • Organizer
      第61回応用物理学会関係連合講演会講演予稿集
    • Place of Presentation
      青山学院大学, 神奈川県相模原市
    • Related Report
      2013 Research-status Report
  • [Presentation] LB法による垂直配向CNT成長の促進2014

    • Author(s)
      栗山直樹, 竹澤章裕, 大橋正明, 中村健太郎, 串田正人
    • Organizer
      第61回応用物理学会関係連合講演会講演予稿集
    • Place of Presentation
      青山学院大学, 神奈川県相模原市
    • Related Report
      2013 Research-status Report
  • [Presentation] Al2O3/SiO2基板上にFeNPs-C16/CH2Cl2-LB膜を用いたVA-CNT作製2014

    • Author(s)
      高際翔太, 金杉治, 中村健太郎, 串田正人
    • Organizer
      第61回応用物理学会関係連合講演会講演予稿集
    • Place of Presentation
      青山学院大学, 神奈川県相模原市
    • Related Report
      2013 Research-status Report
  • [Presentation] Carbon Nanotube Growth from Langmuir Blodgett Deposited Fe Nanoparticles with Filler Molecules2013

    • Author(s)
      Naoki Kuriyama, Akihiro Takezawa, Osamu Kanasugi, Ryuta Nara, Masahito Kushida
    • Organizer
      The 4th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2013)
    • Place of Presentation
      Kanazawa, JAPAN
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis and diameter control of vertically-aligned carbon nanotube growth from Langmuir-Blodgett deposited Fe3O4@SiO2 core-shell nanoparticles2013

    • Author(s)
      Masaaki Ohashi, Takehiro Sugawara, Kohei Kawasaki, Masahito Kushida
    • Organizer
      The 4th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2013)
    • Place of Presentation
      Kanazawa, JAPAN
    • Related Report
      2013 Research-status Report
  • [Presentation] Fe3O4@SiO2型コアシェル粒子を触媒とした垂直配向CNTの合成におけるシェル厚さの影響2013

    • Author(s)
      菅原丈博, 大橋正明, 金杉治, 栗山直樹, 串田正人
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学, 京都府京田辺市
    • Related Report
      2013 Research-status Report
  • [Presentation] 鉄-シリカナノ粒子混合LB膜による垂直配向CNT本数密度制御2013

    • Author(s)
      金杉治, 竹澤章博, 栗山直樹, 串田正人
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学, 京都府京田辺市
    • Related Report
      2013 Research-status Report
  • [Presentation] Feナノ粒子LB膜を用いた垂直配向カーボンナノチューブ本数密度制御2013

    • Author(s)
      竹澤章裕, 栗山直樹, 金杉治, 串田正人
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学, 京都府京田辺市
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis of vertical aligned carbon nanotubes using Fe3O4@SiO2 type core-shell particles as catalysts2013

    • Author(s)
      Kohei Kawasaki, Takehiro Sugawara, Masaaki Ohashi, and Masahito Kushida
    • Organizer
      第60 回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学、神奈川県厚木市
    • Related Report
      2012 Research-status Report
  • [Presentation] Control of CNTs density using Fe nanoparticle LB film mixed with palmitic acid.2013

    • Author(s)
      Ryuta Nara, Akihiro Takezawa, Naoki Kuriyama, and Masahito Kushida
    • Organizer
      第60 回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学、神奈川県厚木市
    • Related Report
      2012 Research-status Report
  • [Presentation] Diameter control of CNTs grown from Fe3O4@SiO2 core-shell nanoparticles2013

    • Author(s)
      菅原 丈博,川﨑 浩平,大橋正明,串田 正人
    • Organizer
      第60 回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学、神奈川県厚木市
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis of VA-CNTs from FeNPs-C20 LB films and estimation of diameter of VA-CNTs2013

    • Author(s)
      Akihiro Takezawa, Ryuta Nara, Naoki Kuriyama, and Masahito Kushida
    • Organizer
      第60 回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学、神奈川県厚木市
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis and diameter control of CNTs grown from Fe3O4@SiO2 core-shell nanoparticles2012

    • Author(s)
      Takehiro Sugawara*, Kohei Kawasaki, and Masahito Kushida
    • Organizer
      10th International Conference of Nano-Molecular Electronics
    • Place of Presentation
      Kanazawa, JAPAN
    • Related Report
      2012 Research-status Report
  • [Presentation] Number density control of Fe nanoparticles as catalyst for CNT growth using2012

    • Author(s)
      Akihiro Takezawa, Ryuta Nara, and Masahito Kushida
    • Organizer
      10th International Conference of Nano-Molecular Electronics
    • Place of Presentation
      Kanazawa, JAPAN
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis of carbon nanotubes using Fe@nanoporous SiO2 coreshell as catalysts2012

    • Author(s)
      Kohei Kawasaki, Shigeki Hasegawa, Shigeaki Murata, Masahito Kushida
    • Organizer
      第73回応用物理学会秋季学術講演会
    • Place of Presentation
      愛媛大学、松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Density control of CNTs by changing Fe nanoparticle diameter2012

    • Author(s)
      Ryuta Nara, Shigeki Hasegawa, Shigeaki Murata, Masahito Kushida
    • Organizer
      第73回応用物理学会秋季学術講演会
    • Place of Presentation
      愛媛大学、松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Movement of core-particle of Fe@SiO2 core-shell particles2012

    • Author(s)
      Takehiro Sugawara, Masahito Kushida
    • Organizer
      第73回応用物理学会秋季学術講演会
    • Place of Presentation
      愛媛大学、松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Preparation of L・LB film of FeNP/SilicaNP and density control of FeNPs2012

    • Author(s)
      Akihiro Takezawa, Kohei Kawasaki, Ryuta Nara, Masahito Kushida
    • Organizer
      第73回応用物理学会秋季学術講演会
    • Place of Presentation
      愛媛大学、松山大学
    • Related Report
      2012 Research-status Report
  • [Remarks] バイオプロセス化学研究室

    • URL

      http://chem.tf.chiba-u.jp/gacb01/

    • Related Report
      2014 Annual Research Report
  • [Remarks] バイオプロセス化学研究室

    • URL

      http://chem.tf.chiba-u.jp/gacb01/index.html

    • Related Report
      2013 Research-status Report
  • [Remarks] バイオプロセス化学研究室

    • URL

      http://chem.tf.chiba-u.jp/gacb01/

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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