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Study of field effect transistors using transition metal oxides

Research Project

Project/Area Number 24656200
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Electronic materials/Electric materials
Research InstitutionThe University of Tokyo

Principal Investigator

TORIUMI AKIRA  東京大学, 工学(系)研究科(研究院), 教授 (50323530)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords遷移金属酸化物 / TiO2 / HFO2 / FET / VO2 / 金属・絶縁体転移 / 移動度 / 酸化物 / TFT / HFO
Research Abstract

We have achieved electron field effect mobility higher than 10 cm2/Vsec in TiO2 FETs with perfectly cut-off characteristics. In addition, we have observed characteristic enhancement of the photo-conductivity, which has a peak below 1 eV from the TiO2 conduction band edge. The high mobility is directly related to the reduction of characteristic peak. Both are controlled by the annealing condition, particularly ambient. Concerning VO2, it was epitaxially grown on single crystalline TiO2, and VO2 film shows uniform film characteristics without any cracks in case that the thickness is thinner than 10 nm. Furthermore, we found that HfO2 which was grown by Ar-sputtering included a huge amount of Ar inside HfO2, and that Ar had a specific effect on the structural phase transition of HfO2 at a high temperature.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (38 results)

All 2014 2013 2012 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (32 results) Remarks (3 results)

  • [Journal Article] QuantitativeCharacterization of Band-Edge EnergyPositions in High-k Dielectrics byX-ray Photoelectron Spectroscopy2013

    • Author(s)
      Y. Chikata, K. K i ta , T. Nishimura, K.Nagashio, and A. Toriumi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 52 Issue: 2R Pages: 21101-21101

    • DOI

      10.7567/jjap.52.021101

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Counter DipoleLayer Formation in Multilayer High-kGate Stacks2012

    • Author(s)
      S. Hibino, T. Nishimura, K. Nagashio, K. Kita, and A. Toriumi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 51 Issue: 8R Pages: 81303-81303

    • DOI

      10.1143/jjap.51.081303

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Interface Dipole Cancellation in SiO2/High--‐k/SiO2/Si Gate Stacks2012

    • Author(s)
      S. Hibino, et al.
    • Journal Title

      ECS Trans.

      Volume: Vol.50, No.4 Issue: 4 Pages: 159-163

    • DOI

      10.1149/05004.0159ecst

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Mobility Enhancement in TiO2 Channel TFTs by Decreasing In-Gap States in The Film and Mitigating Grain Boundary Adsorption2014

    • Author(s)
      矢嶋赳彬, 小池豪, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      2014年第74回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス(神奈川県)
    • Year and Date
      2014-03-20
    • Related Report
      2013 Final Research Report
  • [Presentation] TiO2チャネルTFTの電界効果移動度に対する表面・粒界吸着効果の重要性2014

    • Author(s)
      矢嶋赳彬, 小池豪, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      2014年第74回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス(神奈川県)
    • Year and Date
      2014-03-20
    • Related Report
      2013 Final Research Report
  • [Presentation] 界面制御に依るVO2極薄膜の相転移温度変調2014

    • Author(s)
      矢嶋赳彬, 二宮裕磨, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      2014年第74回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス(神奈川県)
    • Year and Date
      2014-03-18
    • Related Report
      2013 Final Research Report
  • [Presentation] エピタキシャルVO2薄膜中の転移応力に起因する不均質な電子相ドメイン構造2014

    • Author(s)
      二宮裕磨, 矢嶋赳彬, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      2014年第74回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス(神奈川県)
    • Year and Date
      2014-03-18
    • Related Report
      2013 Final Research Report
  • [Presentation] 界面制御によるVO2薄膜の相転移温度変調2014

    • Author(s)
      矢嶋赳彬、二宮裕磨、西村知紀、長汐晃輔、鳥海明
    • Organizer
      第74回応用物理学会春期学術講演会
    • Place of Presentation
      青山学院大学,神奈川
    • Related Report
      2013 Annual Research Report
  • [Presentation] エピタキシャルVO2薄膜中の転移応力に起因する不均質な電子層ドメイン構造2014

    • Author(s)
      二宮裕磨、矢嶋赳彬、西村知紀、長汐晃輔、鳥海明
    • Organizer
      第74回応用物理学会春期学術講演会
    • Place of Presentation
      青山学院大学,神奈川
    • Related Report
      2013 Annual Research Report
  • [Presentation] Mobility Enhancement in TiO2-Channel TFTs by Decreasing in-gap states in the Film and Mitigating Grain Boundary Adsorption2014

    • Author(s)
      矢嶋赳彬,小池豪,西村知紀,長汐晃輔,鳥海明
    • Organizer
      第74回応用物理学会春期学術講演
    • Place of Presentation
      青山学院大学,神奈川
    • Related Report
      2013 Annual Research Report
  • [Presentation] TiO2チャネルTFTの電界効果移動度に対する表面・粒界吸着効果の重要性2014

    • Author(s)
      矢嶋赳彬,小池豪,西村知紀,長汐晃輔,鳥海明
    • Organizer
      第74回応用物理学会春期学術講演
    • Place of Presentation
      青山学院大学,神奈川
    • Related Report
      2013 Annual Research Report
  • [Presentation] High Electron Mobility (>16 cm2/Vsec) FETs with High On/Off Ratio (>106) and Highly Conductive Films (σ>102 S cm) by Chemical Doping in Very Thin (~20 nm) TiO2 Films on Thermally Grown SiO22013

    • Author(s)
      G. Oike, T. Yajima, T. Nishimura, K. Nagashio, A. Toriumi
    • Organizer
      IEDM 2013
    • Place of Presentation
      Washington DC, USA.
    • Year and Date
      2013-12-10
    • Related Report
      2013 Final Research Report
  • [Presentation] Significant Conductivity Enhancement of TiO2 Films by Both Field Effect and Chemical Doping2013

    • Author(s)
      G. Oike, T. Yajima, T. Nishimura, K. Nagashio and A. Toriumi
    • Organizer
      2013 International Conference on Solid State Devices and Materials (SSDM)
    • Place of Presentation
      Hilton Fukuoka Sea Hawk(Fukuoka)
    • Year and Date
      2013-09-26
    • Related Report
      2013 Final Research Report
  • [Presentation] High-Mobility TiO2-Channel TFTs with Optimized Anatase Microstructures2013

    • Author(s)
      T. Yajima, G. Oike, T. Nishimura, K. Nagashio and A. Toriumi
    • Organizer
      2013 International Conference on Solid State Devices and Materials (SSDM)
    • Place of Presentation
      Hilton Fukuoka Sea Hawk(Fukuoka)
    • Year and Date
      2013-09-26
    • Related Report
      2013 Final Research Report
  • [Presentation] High Mobility Polycrystalline TiO2-Channel Field Effect Transistor2013

    • Author(s)
      T. Yajima, G. Oike, T. Nishimura, K. Nagashio and A. Toriumi
    • Organizer
      Workshop on Oxide Electronics20
    • Place of Presentation
      Singapore
    • Year and Date
      2013-09-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 相選択エッチングによる100nm幅VO2ナノワイヤの作製2013

    • Author(s)
      矢嶋赳彬, 二宮裕磨, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府)
    • Year and Date
      2013-09-16
    • Related Report
      2013 Final Research Report
  • [Presentation] アナターゼ結晶相の微細構造制御によるTiO2チャネルTFTの高移動度化2013

    • Author(s)
      矢嶋赳彬, 小池豪, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      2013年第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 酸素雰囲気熱処理によるTiO2チャネルTFT閾値電圧の大幅減少2013

    • Author(s)
      小池豪, 矢嶋赳彬, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      2013年第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] cubic相HfO2薄膜の室温における安定化機構の検討2013

    • Author(s)
      岩井貴雅, 矢嶋赳彬, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      2013年第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Year and Date
      2013-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Arスパッタによって形成されたHfO2薄膜中のArが結晶化相変態に与える影響2013

    • Author(s)
      岩井貴雅, 矢嶋赳彬, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      ゲートスタック研究会-材料・プロセス・評価の物理-(第18回研究会)
    • Place of Presentation
      ニューウェルシティ湯河原(神奈川県)
    • Year and Date
      2013-01-25
    • Related Report
      2013 Final Research Report
  • [Presentation] TiO2チャネルTFT特性に及ぼす酸素雰囲気熱処理の特異な効果2013

    • Author(s)
      小池豪, 矢嶋赳彬, 西村知紀, 長汐晃輔, 鳥海明
    • Organizer
      ゲートスタック研究会-材料・プロセス・評価の物理-(第18回研究会)
    • Place of Presentation
      ニューウェルシティ湯河原(神奈川県)
    • Year and Date
      2013-01-25
    • Related Report
      2013 Final Research Report
  • [Presentation] Singnificant Conductivity Enhancement of TiO2 Films by Both Field Effect and Chemical Doping2013

    • Author(s)
      G. Oike, T. Yajima, T. Nishimura, K. Nagashio and A. Toriumi
    • Organizer
      International Conference on Solid-state Devices and Materials
    • Place of Presentation
      Hilton Fukuoka Sea Hawk , Fukuoka
    • Related Report
      2013 Annual Research Report
  • [Presentation] High-mobility TiO2-channel TFTs with Optimized Anatase Microstructures2013

    • Author(s)
      T. Yajima, G. Oike, T. Nishimura, K. Nagashio and A. Toriumi
    • Organizer
      International Conference on Solid-state Devices and Materials
    • Place of Presentation
      Hilton Fukuoka Sea Hawk , Fukuoka
    • Related Report
      2013 Annual Research Report
  • [Presentation] 相選択エッチングによる100nm幅VO2ナノワイヤの作製2013

    • Author(s)
      矢嶋赳彬、二宮裕磨、西村知紀、長汐晃輔、鳥海明
    • Organizer
      第74回応用物理学会秋期学術講演会
    • Place of Presentation
      同志社大,京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] High Electron Mobility (>16 cm2/Vsec) FETs with High On/Off Ratio (>106)2013

    • Author(s)
      G. Oike, T. Yajima, T. Nishimura, K. Nagashio and A. Toriumi
    • Organizer
      International Electron Device Meeting (IEDM)
    • Place of Presentation
      Wshington.D.C, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] High mobility Polyrystalline TiO2 Channel Field Effect Transistor2013

    • Author(s)
      T. Yajima, G. Oike, T. Nishimura, K. Nagashio, A. Toriumi
    • Organizer
      Workshop on Oxide Electronics 20 (WOE20)
    • Place of Presentation
      National University, Singapore
    • Related Report
      2013 Annual Research Report
  • [Presentation] Role of Ar on Structual Phase Transformation of Sputtered HfO22012

    • Author(s)
      T. Iwai, Y. Nakajima, T. Nishimura, K. Nagashio, and A. Toriumi
    • Organizer
      2012 International Conference on Solid State Devices and Materials (SSDM)
    • Place of Presentation
      京都国際会館(京都府)
    • Year and Date
      2012-09-27
    • Related Report
      2013 Final Research Report
  • [Presentation] Counter Dipole Layer Formation in SiO2/High-­k/SiO2/Si Gate Stacks2012

    • Author(s)
      S. Hibino, T. Nishimura, K. Nagashio, K. Kita, and A. Toriumi
    • Organizer
      2012 IEEE Silicon Nano electronics Workshop
    • Place of Presentation
      Hilton Hawaiian Village ,Hawaii, U.S.A.
    • Year and Date
      2012-01-10
    • Related Report
      2013 Final Research Report
  • [Presentation] 「アナターゼ結晶相の微細構造制御によるTiO2チャネルTFTの高移動度化」

    • Author(s)
      矢嶋赳彬
    • Organizer
      2013年 第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 「酸素雰囲気熱処理によるTiO2チャネルTFT閾値電圧の大幅減少」

    • Author(s)
      小池豪
    • Organizer
      2013年春季 第60回応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 「cubic相HfO2薄膜の室温における安定化機構の検討」

    • Author(s)
      岩井貴雅
    • Organizer
      2013年 第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 「Arスパッタによって形成されたHfO2薄膜中のArが結晶化相変態に与える影響」

    • Author(s)
      岩井貴雅
    • Organizer
      ゲートスタック研究会-材料・プロセス・評価の物理-(第18回研究会)
    • Place of Presentation
      ニューウェルシティ湯河原(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 「TiO2チャネルTFT特性に及ぼす酸素雰囲気熱処理の特異な効果」

    • Author(s)
      小池豪
    • Organizer
      ゲートスタック研究会-材料・プロセス・評価の物理-(第18回研究会)
    • Place of Presentation
      ニューウェルシティ湯河原(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] "Role of Ar on Structual Phase Transformation of Sputtered HfO2"

    • Author(s)
      T. Iwai
    • Organizer
      2012 International Conference on Solid State Devices and Materials (SSDM)
    • Place of Presentation
      京都国際会館(京都府)
    • Related Report
      2012 Research-status Report
  • [Presentation] "Counter Dipole Layer Formation in SiO2/High‐k/SiO2/Si Gate Stacks"

    • Author(s)
      S.Hibino
    • Organizer
      2012 IEEE Silicon Nanoelectronics Workshop
    • Place of Presentation
      Hilton Hawaiian Village(Hawaii, U.S.A.)
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.adam.t.u-tokyo.ac.jp/top.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 先端デバイス材料工学 鳥海研究室

    • URL

      http://www.adam.t.u-tokyo.ac.jp/top.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 鳥海・長汐研究室 成果発表リスト

    • URL

      http://www.adam.t.u-tokyo.ac.jp/publication.html

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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