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Spontaneous polarization in nanosized ferroelectrics and its size dependence

Research Project

Project/Area Number 24656214
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Electronic materials/Electric materials
Research InstitutionUniversity of Hyogo

Principal Investigator

FUJISAWA Hironori  兵庫県立大学, 工学(系)研究科(研究院), 准教授 (30285340)

Co-Investigator(Renkei-kenkyūsha) SHIMIZU Masaru  兵庫県立大学, 大学院工学研究科, 教授 (30154305)
NAKASHIMA Seiji  兵庫県立大学, 大学院工学研究科, 助教 (80552702)
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsナノ強誘電体 / 自発分極 / サイズ効果 / 圧電定数 / 走査型プローブ顕微鏡 / SPM / 基板拘束 / サイズ依存性
Research Abstract

In order to investigate physical properties of nanosized ferroelectrics, we developed a measurement system based on scanning probe microscopy (SPM), which was capable of detecting electrical charges smaller than 10 fC. By using the SPM system developed, switching charges of lead titanate nanoislands with lateral dimensions of several tens nanometers and heights of several nanometers were successfully measured. The SPM revealed that the switching charge of lead titanate nanoislands was as large as those of thin films. From the size dependence and relationship between spontaneous polarization and piezoelectric coefficient, it was found that the decrease in the spontaneous polarization with the island height was responsible for the decrease in the piezoelectric coefficient.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (28 results)

All 2014 2013 2012 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (27 results) (of which Invited: 2 results)

  • [Journal Article] Size Dependence of Ferroelectric Polarization in PbTiO_3 Nanoislands2012

    • Author(s)
      Hironori Fujisawa, Kosei Yamada, Masashi Igawa, Seiji Nakashima, and Masaru Shimizu
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 51 Issue: 9S1 Pages: 09LA07-09LA07

    • DOI

      10.1143/jjap.51.09la07

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] AFMによるPbTiO_3ナノ島の分極量評価(II)2014

    • Author(s)
      井川将志, 山下貴大, 中嶋誠二, 藤沢浩訓, 清水勝
    • Organizer
      平成26年(2014)第61回応用物理学会春季学術講演会講演予稿集
    • Place of Presentation
      青山学院大学相模原キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] Size dependence of ferroelectric polarization and piezoelectric coefficient in PbTiO_3 nanoislands2014

    • Author(s)
      H. Fujisawa, M. Igawa, S. Nakashima and M. Shimizu
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      Fukuoka University, Fukuoka(発表確定)
    • Related Report
      2013 Final Research Report
  • [Presentation] 低次元強誘電体の作製とその物性2014

    • Author(s)
      藤沢浩訓, 中嶋誠二, 清水勝
    • Organizer
      平成26年(2014)秋季第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学(発表確定)
    • Related Report
      2013 Final Research Report
  • [Presentation] AFMによるPbTiO3ナノ島の分極量評価(II)2014

    • Author(s)
      井川将志,山下貴大,中嶋誠二,藤沢浩訓,清水勝
    • Organizer
      平成26年(2014)第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス(神奈川県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Size dependence of ferroelectric polarization and piezoelectric coefficient in PbTiO3 nanoislands2014

    • Author(s)
      Hironori Fujisawa, Masashi Igawa, Seiji Nakashima and Masaru Shimizu
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      福岡大学(福岡県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] PFMを用いた強誘電体薄膜の面内および鉛直方向の圧電性評価2013

    • Author(s)
      瀬戸翔太, 高田祐介, 中嶋誠二, 藤沢浩訓, 清水勝
    • Organizer
      平成25年(2013)春季第60回応用物理学関係連合講演会講演予稿集
    • Place of Presentation
      神奈川工業大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Size Dependence of Spontaneous Polarization in Nanosized Lead Titanate2013

    • Author(s)
      H. Fujisawa, M. Igawa, S. Nakashima and M. Shimizu
    • Organizer
      The 13th International Meeting on Ferroelectricity (IMF-13) No.0095
    • Place of Presentation
      Jagiellonian University - Auditorium Maximum, Kraków, Poland
    • Related Report
      2013 Final Research Report
  • [Presentation] AFMによるPbTiO_3ナノ島の分極量評価2013

    • Author(s)
      井川将志, 中嶋誠二, 藤沢浩訓, 清水勝
    • Organizer
      平成25年(2013)第74回応用物理学会秋季学術講演会講演予稿集
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] PbTiO_3ナノ島の強誘電分極のサイズ依存性2013

    • Author(s)
      藤沢浩訓, 井川将志, 中嶋誠二, 清水勝
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      波止場会館
    • Related Report
      2013 Final Research Report
  • [Presentation] SIZE DEPENDENCE OF SPONTANEOUS POLARIZATION IN NANOSIZED LEAD TITANATE2013

    • Author(s)
      H. Fujisawa, M. Igawa, S. Nakashima and M. Shimizu
    • Organizer
      The 13th International Meeting on Ferroelectricity (IMF-13)
    • Place of Presentation
      Jagiellonian University (Poland)
    • Related Report
      2013 Annual Research Report
  • [Presentation] AFMによるPbTiO3ナノ島の分極量評価2013

    • Author(s)
      井川将志,中嶋誠二,藤沢浩訓,清水 勝
    • Organizer
      平成25年(2013)第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府)
    • Related Report
      2013 Annual Research Report
  • [Presentation] PbTiO3ナノ島の強誘電分極のサイズ依存性2013

    • Author(s)
      藤沢 浩訓, 井川 将志, 中嶋 誠二, 清水 勝
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜市波止場会館(神奈川県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Evaluation of switching charge density of PbTiO_3 nanoislands by atomic force microscopy2012

    • Author(s)
      Masashi Igawa, Seiji Nakashima, Hironori Fujisawa, and Masaru Shimizu
    • Organizer
      Abs. of The 9th Korea-Japan Conference on Ferroelectrics (KJC-FE09)
    • Place of Presentation
      University of Ulsan
    • Related Report
      2013 Final Research Report
  • [Presentation] Polarization Measurements of PbTiO_3 Nanoislands by Atomic Force Microscopy2012

    • Author(s)
      H. Fujisawa, M. Igawa, K. Yamada, S. Nakashima and M. Shimizu
    • Organizer
      Abs. IUMRS-Int. Conf. Electronic Materials
    • Place of Presentation
      Pacifico Yokohama, Japan(C-3-O24-002)
    • Related Report
      2013 Final Research Report
  • [Presentation] Switchable Polarization in a Single PbTiO_3 Nanoisland2012

    • Author(s)
      Hironori Fujisawa, Masahi Igawa, Seiji Nakashima, Masaru Shimizu
    • Organizer
      Abs. of Mater. Res. Soc. 2012 Fall Meeting
    • Place of Presentation
      Boston, Massachusetts, U.S.A.(AA9.09)
    • Related Report
      2013 Final Research Report
  • [Presentation] 原子間力顕微鏡による単一PbTiO_3ナノ島の分極測定2012

    • Author(s)
      藤沢浩訓, 山田耕生, 井川将志, 中嶋誠二, 清水勝
    • Organizer
      第29回強誘電体応用会議講演予稿集
    • Place of Presentation
      コープイン京都
    • Related Report
      2013 Final Research Report
  • [Presentation] PFMを用いた強誘電体薄膜の圧電変位量の定量評価2012

    • Author(s)
      瀬戸翔太, 中嶋誠二, 藤沢浩訓, 清水勝
    • Organizer
      平成24年(2012)秋季第73回応用物理学会学術講演会講演予稿集
    • Place of Presentation
      愛媛大学
    • Related Report
      2013 Final Research Report
  • [Presentation] AFMを用いたPbTiO_3ナノ島の分極量の評価(II)2012

    • Author(s)
      井川将志, 中嶋誠二, 藤沢浩訓, 清水勝
    • Organizer
      平成24年(2012)秋季第73回応用物理学会学術講演会講演予稿集
    • Place of Presentation
      愛媛大学
    • Related Report
      2013 Final Research Report
  • [Presentation] MOCVD法によるナノサイズ強誘電体の作製とその物性2012

    • Author(s)
      藤沢浩訓, 中嶋誠二, 清水勝
    • Organizer
      第53回真空に関する連合講演会
    • Place of Presentation
      甲南大学ポートアイランドキャンパス(15Aa-6)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Evaluation of switching charge density of PbTiO3 nanoislands by atomic force microscopy

    • Author(s)
      Masashi Igawa, Seiji Nakashima, Hironori Fujisawa, and Masaru Shimizu
    • Organizer
      The 9th Korea-Japan Conference on Ferroelectrics (KJC-FE09)
    • Place of Presentation
      University of Ulsan(韓国)
    • Related Report
      2012 Research-status Report
  • [Presentation] Polarization Measurements of PbTiO3 Nanoislands by Atomic Force Microscopy

    • Author(s)
      H. Fujisawa, M. Igawa, K. Yamada, S. Nakashima and M. Shimizu
    • Organizer
      IUMRS-Int. Conf. Electronic Materials
    • Place of Presentation
      Pacifico Yokohama(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Switchable Polarization in a Single PbTiO3 Nanoisland

    • Author(s)
      Hironori Fujisawa, Masahi Igawa, Seiji Nakashima, Masaru Shimizu
    • Organizer
      Mater. Res. Soc. 2012 Fall Meeting
    • Place of Presentation
      Boston(米国)
    • Related Report
      2012 Research-status Report
  • [Presentation] 原子間力顕微鏡による単一PbTiO3ナノ島の分極測定

    • Author(s)
      藤沢浩訓, 山田耕生, 井川将志, 中 誠二, 清水 勝
    • Organizer
      第29回強誘電体応用会議
    • Place of Presentation
      コープイン京都(京都府)
    • Related Report
      2012 Research-status Report
  • [Presentation] PFMを用いた強誘電体薄膜の圧電変位量の定量評価

    • Author(s)
      瀬戸翔太,中嶋誠二,藤沢浩訓,清水 勝
    • Organizer
      応用物理学会学術講演会
    • Place of Presentation
      愛媛大学(愛媛県)
    • Related Report
      2012 Research-status Report
  • [Presentation] AFMを用いたPbTiO3ナノ島の分極量の評価(II)

    • Author(s)
      井川将志,中嶋誠二,藤沢浩訓,清水 勝
    • Organizer
      応用物理学会学術講演会
    • Place of Presentation
      愛媛大学(愛媛県)
    • Related Report
      2012 Research-status Report
  • [Presentation] PFMを用いた強誘電体薄膜の面内および鉛直方向の圧電性評価

    • Author(s)
      瀬戸翔太,高田祐介,中嶋誠二,藤沢浩訓,清水 勝
    • Organizer
      応用物理学関係連合講演会
    • Place of Presentation
      神奈川工業大学(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] MOCVD法によるナノサイズ強誘電体の作製とその物性

    • Author(s)
      藤沢 浩訓,中嶋 誠二,清水 勝
    • Organizer
      第53回真空に関する連合講演会
    • Place of Presentation
      甲南大学(兵庫県)
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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