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Middle-range order structure of multi-component Li ion conducting oxides

Research Project

Project/Area Number 24656364
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical properties of metals
Research InstitutionTohoku University

Principal Investigator

WASEDA Yoshio  東北大学, 多元物質科学研究所, 名誉教授 (00006058)

Co-Investigator(Kenkyū-buntansha) SHIBATA Hiroyuki  東北大学, 多元物質科学研究所, 教授 (50250824)
SHINODA Kozo  東北大学, 多元物質科学研究所, 准教授 (10311549)
FUJIEDA Shun  東北大学, 多元物質科学研究所, 助教 (60551893)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords金属物性 / ナノ物性 / 固体電解質
Outline of Final Research Achievements

The local structure around germanium of LiGe2(PO4)3 with the glass and the natrium super ionic conductor (NASICON)-type glass ceramic was investigated. While the X-ray absorption near edge structure spectra at the Ge K absorption edge of the glass ceramic indicated a distinct peak with a shoulder at higher energy sides, the glass exhibited a broad spectra. In the radial structure function obtained by Fourier transform of the extended X-ray absorption fine structure oscillation, the Ge-O correlation peak of the glass was observed at the shorter distance in comparison with that of the glass ceramic. These results suggest that the local structure around germanium in the glass is different from that of the glass ceramic composed of the GeO6 octahedral units.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (11 results)

All 2015 2014 2013 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (7 results) Remarks (3 results)

  • [Journal Article] Improvement of electrochemical properties of LiFePO4 fine particles synthesized in ethylene glycol solution due to heat treatment2014

    • Author(s)
      S. Fujieda, K. Shinoda and S. Suzuki
    • Journal Title

      Solid State Ionics

      Volume: 262 Pages: 613-616

    • DOI

      10.1016/j.ssi.2013.11.008

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Presentation] NASICON型LiTixGe2-x(PO4)3ガラスセラミックの作製およびその過程の構造変化2015

    • Author(s)
      山本悠貴友、藤枝 俊、有馬 寛、篠田弘造、杉山和正、鈴木 茂
    • Organizer
      日本金属学会
    • Place of Presentation
      東京
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Liイオン伝導性固体電解質の構造解析2013

    • Author(s)
      小鹿裕希, 藤枝 俊, 篠田弘造, 鈴木 茂, 早稲田嘉夫
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      金沢
    • Related Report
      2013 Research-status Report
  • [Presentation] ガラスおよび結晶状態におけるLiGe2(PO4)3系化合物の構造解析2013

    • Author(s)
      小鹿祐希, 藤枝俊, 篠田弘造, 鈴木茂, 柴田浩幸, 早稲田嘉夫, 有馬寛, 川又透, 杉山和正
    • Organizer
      日本金属学会
    • Place of Presentation
      金沢
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis of Olivine-type LiFePO4 Fine Particles in Polyol Solution and Characterization by X-ray Absorption Spectroscopy2013

    • Author(s)
      Shun Fujieda, Kozo Shinoda, Shigeru Suzuki, Yoshio Waseda
    • Organizer
      International Conference State Ionics
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Liイオン伝導性固体電解質のガラスおよび結晶状態における局所構造の変化2013

    • Author(s)
      小鹿祐希, 藤枝俊, 篠田弘造, 鈴木茂, 早稲田嘉夫
    • Organizer
      日本金属学会
    • Place of Presentation
      東京
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis of olivine-type LiFePO4 fine particles in polyol solution and characterization by X-ray absorption spectroscopy2013

    • Author(s)
      S. Fujieda, K. Shinoda, S. Suzuki, Y. Waseda
    • Organizer
      The 19th International Conference on Solid State Ionics
    • Place of Presentation
      京都
    • Related Report
      2012 Research-status Report
  • [Presentation] Liイオン伝導性固体電解質のガラスおよび結晶状態における構造とイオン伝導率の関係

    • Author(s)
      小鹿裕希, 藤枝 俊, 篠田弘造, 鈴木 茂, 早稲田嘉夫
    • Organizer
      資源・素材学会 東北支部大会
    • Place of Presentation
      仙台
    • Related Report
      2013 Research-status Report
  • [Remarks] 多元物質科学研究所 業績データベース

    • URL

      http://db.tagen.tohoku.ac.jp/php/db/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 多元物質科学研究所 業績データベース

    • URL

      http://db.tagen.tohoku.ac.jp/php/db/

    • Related Report
      2013 Research-status Report
  • [Remarks] 多元物質科学研究所 業績データベース

    • URL

      http://db.tagen.tohoku.ac.jp/php/db/

    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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