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Mechanism of leakage current of ferroelectric thin films based on internal potential

Research Project

Project/Area Number 24656372
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

KIGUCHI Takanori  東北大学, 金属材料研究所, 准教授 (70311660)

Co-Investigator(Kenkyū-buntansha) SATO Kazuhisa  東北大学, 金属材料研究所, 准教授 (70314424)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords強誘電体 / 組織 / マルチフェロイックス / リラクサー / 電子顕微鏡 / 出射波動場 / 波面再構築 / 内部ポテンシャル / マルチフェロイック / TEM / HAADF-STEM / 位相再構成 / 薄膜 / CSD法 / PMN / リーク / 位相
Outline of Final Research Achievements

This study was investigated the effect of processing conditions of BiFeO3 and Pb(Mg1/3Nb2/3)O3 thin films on their microstructure using electron microscopies, the transmission electron microscopy (TEM) and the high-angle annular dark field-scanning transmission electron microscopy (HAADF-STEM). The mechanism of leakage current was also investigated from the point of microstructure. It has been attempted that the analysis of the average internal potential in these thin films using the wave function reconstruction of the focal series of HRTEM images in order to elucidate the electronic structure in these thin films.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (49 results)

All 2015 2014 2013 2012

All Journal Article (18 results) (of which Peer Reviewed: 17 results,  Acknowledgement Compliant: 2 results) Presentation (29 results) (of which Invited: 4 results) Book (2 results)

  • [Journal Article] Effect of Ti concentration on the growth of chemically-ordered regions of Pb(Mg1/3Nb2/3)O3-PbTiO3 epitaxial thin films2015

    • Author(s)
      C. Fan, T. Kiguchi, A. Akama, and T.J. Konno
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 123

    • NAID

      130005085546

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] TEM analysis of the nanostructure of Pb(Mg_<1/3>Nb_<2/3>)O_3 thin films by MOD method2014

    • Author(s)
      Y. Misaka, T. Kiguchi, K. Sato, T. Nishimatsu, T. Yamada, N. Usami, and T.J. Konno
    • Journal Title

      Key Eng. Mater

      Volume: 582 Pages: 19-22

    • DOI

      10.4028/www.scientific.net/kem.582.19

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Aberration-corrected STEM analysis of ordered structure in Pb(Mg1/3Nb2/3)03 thin films2014

    • Author(s)
      C. Fan, T. Kiguchi, T. Yamada, and T.J. Konno
    • Journal Title

      AMTC Lett.

      Volume: 4 Pages: 200-201

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] TEM study for self orientated LaNiO3 film along [001]2014

    • Author(s)
      Naonori Sakamoto, Kotaro Ozawa, Kohei Murakoshi, Tomoya Ohno , Takanori Kiguchi, Takeshi Matsuda, Toyohiko J. Konno, Naoki Wakiya, and Hisao Suzuki
    • Journal Title

      Key Engineering Materials

      Volume: 582 Pages: 185-188

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Columnar grain boundary coherence in yttria-stabilized zirconia thin film: effects on ionic conductivity2014

    • Author(s)
      Takanori Kiguchi, Toyohiko J. Konno, Hiroshi Funakubo, Osamu Sakurai, Kazuo Shinozaki
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 122 Issue: 1421 Pages: 72-77

    • DOI

      10.2109/jcersj2.122.72

    • NAID

      130004950911

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of Annealing Process on the Structure of Mn-Doped BiFeO3 Thin Films2013

    • Author(s)
      M. Mizugai, T. Kiguchi, N. Usami, K. Shinozaki, T.J. Konno
    • Journal Title

      Key Engineering Materials

      Volume: 566 Pages: 155-158

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of excess Pb on epitaxial growth of Pb(Mg<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub> thin films prepared by chemical solution deposition process2013

    • Author(s)
      T. Kiguchi, T. Tsukamoto, C. Fan, M. Nishijima, and T.J. Konno
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 121 Issue: 1416 Pages: 638-643

    • DOI

      10.2109/jcersj2.121.638

    • NAID

      130004480199

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nano-structure around 90° domain wall and elastic interaction with misfit dislocation in PbTiO3 thin film2013

    • Author(s)
      T. Kiguchi, K. Aoyagi, Y. Ehara, H. Funakubo, T. Yamada,N. Usami, T.J. Konno
    • Journal Title

      Key Engineering Materials

      Volume: 566 Pages: 167-170

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Analysis of Lattice Defects in an Epitaxial PbTiO3 Thick Film by Transmission Electron Microscopy2013

    • Author(s)
      K. Aoyagi, T. Kiguchi, Y. Ehara, H. Funakub, and , T. J. Konno
    • Journal Title

      Key Engineering Materials

      Volume: 566 Pages: 171-174

    • Related Report
      2013 Research-status Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Control of Dip Shape in Photonic Nanostructures by Maskless Wet-Etching Process and Its Impact on Optical Properties2013

    • Author(s)
      Yusuke Hoshi, Wugen Pan, Takanori Kiguchi, Kazufumi Ooi, Takeshi Tayagaki, Noritaka Usami
    • Journal Title

      Japanese Journal of Applied Physics RAPID COMMUNICATION

      Volume: 52 Issue: 8R Pages: 080202-080202

    • DOI

      10.7567/jjap.52.080202

    • NAID

      40019757192

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Micro/Crystal structure analysis of CSD derived porous LaNiO<sub>3</sub> electrode films2013

    • Author(s)
      Naonori Sakamoto, Kotaro Ozawa, Tomoya Ohno, Takanori Kiguchi, Takeshi Matsuda, Toyohiko Konno, Naoki Wakiya, and Hisao Suzuki
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 121 Issue: 1416 Pages: 619-622

    • DOI

      10.2109/jcersj2.121.619

    • NAID

      130004480197

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication and electrochemical performance of lithium polymer battery using mesoporous silica/polymer hybrid electrolyte2013

    • Author(s)
      Masanobu Nakayama, Takashi Okajima, Yoshihiro Yamamoto, Shinji Baba, Kaede Iizuka, Masayuki Nogami, Dai Mochizuki, Takanori Kiguchi, and Shigeki Kuroki
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 121 Issue: 1416 Pages: 723-729

    • DOI

      10.2109/jcersj2.121.723

    • NAID

      130004480172

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication and Evaluation of One-axis Oriented Lead Zirconate Titanate Films using Metal-oxide Nanosheet Interface Layer2013

    • Author(s)
      Y. Minemura, K. Nagasaka, T. Kiguchi, T.J. Konno, H. Funakubo, and H. Uchida
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 52 Issue: 9S1 Pages: 09KA04-09KA04

    • DOI

      10.7567/jjap.52.09ka04

    • NAID

      210000142820

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal structure analysis of hydrothermally synthesized epitaxial (K_xNa_<1_x>)NbO_3 films2013

    • Author(s)
      白石貴久, 金子祈之, 榮西弘, 清水荘雄, 黒澤実, 内田寛, 小林健, 木口賢紀, 今野豊彦, 舟窪浩
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 9S1 Pages: 09KA11-09KA11

    • DOI

      10.7567/jjap.52.09ka11

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Direct Observation of Atomic Arrangement around 90° Domain Wall in Lead Titanate Thin Film2013

    • Author(s)
      T. Kiguchi, T.J. Konno, Y. Ehara, T. Yamada, and H. Funakubo
    • Journal Title

      Mater. Res. Soc. Symp. Proc

      Volume: 1515

    • DOI

      10.1557/opl.2013.1094

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Facing Annealing on Crystallization and Decomposition of Pb(Mg1/3Nb2/3)O3 Thin Films Prepared by CSD Technique Using MOD Solution2013

    • Author(s)
      Takanori Kiguchi, Yoshihiro Misaka, Masahiko Nishijima, Naonori Sakamoto, Naoki Wakiya, Hisao Suzuki, and Toyohiko J. Konno
    • Journal Title

      Journal of Ceramics Society Japan

      Volume: 121 Pages: 236-241

    • NAID

      130004950819

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Stress state analysis of stress engineered BaTiO3 thin film by LaNiO3 bottom electrode2013

    • Author(s)
      Kohei MURAKOSHI, Kohei FUKAMACHI, Naonori SAKAMOTO, Tomoya OHNO, Takanori KIGUCHI, Takeshi MATSUDA, Toyohiko KONNO, Naoki WAKIYA and Hisao SUZUKI
    • Journal Title

      Journal of Ceramics Society Japan

      Volume: 121 Pages: 273-277

    • NAID

      130004950818

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] TEM microstructure analysis for stressed Pb(Zr,Ti)O3 thin firms by oxide electrodes2013

    • Author(s)
      K. Ozawa, M Ishizuka, N. Sakamoto, T. Kiguchi, T. Konno, N. Wakiya, S. Hisao
    • Journal Title

      Key Engineering Materials

      Volume: 未定

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Atomic-resolution analysis of structure and morphology of PMN-PT epitaxial thin films2015

    • Author(s)
      Takanori Kiguchi, Cangyu Fan, Akihiro Akama, Takahisa Shiraishi, Toyohiko J. Konno
    • Organizer
      Pacifichem2015
    • Place of Presentation
      ハワイ(ホノルル)
    • Year and Date
      2015-12-15 – 2015-12-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] リラクサー強誘電体薄膜における2相共存組織2015

    • Author(s)
      範 滄宇、木口賢紀、赤間章裕、今野豊彦
    • Organizer
      日本顕微鏡学会第71回学術講演会
    • Place of Presentation
      京都国際会館 (京都府京都市)
    • Year and Date
      2015-05-13 – 2015-05-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] PMN-PT薄膜におけるMPBシフトと構造評価2015

    • Author(s)
      範 滄宇、木口賢紀、赤間章裕、今野豊彦
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山大学(岡山県岡山市)
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] STEM-EELS法によるPMN-PT/STO界面における電子状態分析2014

    • Author(s)
      範 滄宇、木口賢紀、赤間章裕、今野豊彦
    • Organizer
      第34回エレクトロセラミックス研究討論会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2014-10-24 – 2014-10-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pb(Mg1/3Nb2/3)O3薄膜における秩序構造の原子分解能観察2014

    • Author(s)
      範 滄宇、木口賢紀、赤間章裕、今野豊彦
    • Organizer
      材料フェスタin仙台
    • Place of Presentation
      仙台国際センター(宮城県仙台市)
    • Year and Date
      2014-07-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3エピタキシャル薄膜における規則構造の原子分解能観察2014

    • Author(s)
      範 滄宇、木口賢紀、赤間章裕、今野豊彦
    • Organizer
      東北大学金属材料研究所所内講演会(126)
    • Place of Presentation
      東北大学金属材料研究所(宮城県仙台市)
    • Year and Date
      2014-05-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Pb(Mg1/3Nb2/3)O3薄膜における秩序構造の原子分解能観察2014

    • Author(s)
      範 滄宇、木口賢紀、今野豊彦
    • Organizer
      日本顕微鏡学会第70回学術講演会
    • Place of Presentation
      幕張メッセ (千葉県千葉市)
    • Year and Date
      2014-05-11 – 2014-05-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Aberration-corrected STEM analysis of ordered structure in Pb(Mg1/3Nb2/3)03 thin films2014

    • Author(s)
      Cangyu Fan,Takanori Kiguchi, Tomoaki Yamada, and Toyohiko J. Konno
    • Organizer
      AMTC4
    • Place of Presentation
      浜松アクトシティー (静岡県浜松市)
    • Year and Date
      2014-05-08 – 2014-05-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Atomic resolution imaging for Pb-based ferroelectric thin films using aberration-corrected electron microscopy2014

    • Author(s)
      Takanori Kiguchi
    • Organizer
      CMSI/CMRI Workshop for Ferroelectrics and Related Materials
    • Place of Presentation
      仙台
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Pb(Mg1/3Nb2/3)O3薄膜における化学的秩序構造2014

    • Author(s)
      木口賢紀, 範滄宇, 今野豊彦, 安本洵, 長崎正雅, 山田智明
    • Organizer
      日本セラミックス協会第52回セラミックス基礎科学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] Pb(Mg1/3Nb2/3)O3薄膜の原子分解能走査型電子顕微鏡観察2014

    • Author(s)
      範滄宇, 木口賢紀, 今野豊彦, 安本洵, 山田智明, 長崎正雅
    • Organizer
      日本顕微鏡学会 第38回関東支部講演会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] (Hf0.5Zr0.5)O2薄膜の強誘電性評価2014

    • Author(s)
      横内達彦, 清水荘雄, 及川貴弘, 白石貴久, 木口賢紀, 赤間章裕, 今野豊彦, Alexei Gruverman, 舟窪浩
    • Organizer
      第61回応用物理学会関係連合講演会(春期)
    • Place of Presentation
      相模原
    • Related Report
      2013 Research-status Report
  • [Presentation] 雰囲気制御下におけるCoxOy系薄膜の室温エピタキシャル成長と異種積層膜の作製2014

    • Author(s)
      松田晃史, 金子智, 木口賢紀, 吉本護
    • Organizer
      第61回応用物理学会関係連合講演会(春期)
    • Place of Presentation
      相模原
    • Related Report
      2013 Research-status Report
  • [Presentation] PMN-PT薄膜における規則構造の原子分解能観察2014

    • Author(s)
      範滄宇, 木口賢紀, 今野豊彦, 山田智明
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      横浜
    • Related Report
      2013 Research-status Report
  • [Presentation] Atomic-Resolution STEM Analysis of Hetero-Nanostructure in Relaxor Thin Films2013

    • Author(s)
      T. Kiguchi, C. Fan, T. Tsukamoto, J. Yasumoto, T. Yamada, T. Nagasaki, and T.J. Konno
    • Organizer
      The 7th International Conference on the Science And Technology for Advanced Ceramics (STAC-7)
    • Place of Presentation
      横浜
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of Deposition Condition on Epitaxial Growth of BiFeO3 Thin Films by CSD Method2013

    • Author(s)
      T. Kiguchi, M. Nishijima, K. Shinozaki, and T.J. Konno
    • Organizer
      The 7th International Conference on the Science And Technology for Advanced Ceramics (STAC-7)
    • Place of Presentation
      横浜
    • Related Report
      2013 Research-status Report
  • [Presentation] Orientation dependence of clamping effect in tetragonal Pb(Zr0.35Ti0.65)O3 thin films2013

    • Author(s)
      J. Yasumoto, T. Yamada, O. Sakata, Y. Imai, T. Kiguchi, T. J. Konno, Y. Ehara, T. Shiraishi, T. Oikawa, H. Funakubo, M. Yoshino, and T. Nagasaki
    • Organizer
      The 7th International Conference on the Science And Technology for Advanced Ceramics (STAC-7)
    • Place of Presentation
      横浜
    • Related Report
      2013 Research-status Report
  • [Presentation] 鉛系リラクサー薄膜における化学的秩序構造の原子分解能観察2013

    • Author(s)
      木口 賢紀、範 滄宇、塚本 倫一人・今野 豊彦、 安本 洵、長崎 正雅、 山田 智明
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      長野
    • Related Report
      2013 Research-status Report
  • [Presentation] 緩和型強誘電体における化学的秩序構造の原子分解能観察2013

    • Author(s)
      木口賢紀、今野豊彦、範滄宇、塚本倫一人、 山田智明
    • Organizer
      日本金属学会2013年秋期大会
    • Place of Presentation
      金沢
    • Related Report
      2013 Research-status Report
  • [Presentation] 収差補正電子顕微鏡によるPb(Mg1/3Nb2/3)O3薄膜における化学的秩序構造の原子分解能観察2013

    • Author(s)
      範滄宇, 木口賢紀, 今野豊彦, 安本洵, 山田智明, 長崎正雅
    • Organizer
      第33回エレクトロセラミックス研究討論会
    • Place of Presentation
      つくば
    • Related Report
      2013 Research-status Report
  • [Presentation] One-Axis Crystal Oriention of Lead Zirconate Titanate Films on Nanosheet Buffer Layer on Metal Substrates2013

    • Author(s)
      Hiroshi UCHIDA, Yoshiki MINEMURA, Kohei NAGASAKA, Jin Woong KIM, Ken NISHIDA, Takanori KIGUCHI, Toyohiko J. KONNO, and Hiroshi FUNAKUBO
    • Organizer
      US-Japan Seminar on Dielectric and Piezoelectric Materials
    • Place of Presentation
      Raleigh, NC (USA)
    • Related Report
      2013 Research-status Report
  • [Presentation] Pb(Mg1/3Nb2/3)O3エピタキシャル薄膜における化学的秩序構造の成長過程2013

    • Author(s)
      範滄宇, 木口賢紀, 今野豊彦, 山田智明
    • Organizer
      第126回金研所内講演会(2013秋季)
    • Place of Presentation
      仙台
    • Related Report
      2013 Research-status Report
  • [Presentation] MPB 組成近傍Pb(Zr,Ti)O3 エピタキシャル膜のナノ双晶構造2012

    • Author(s)
      木口 賢紀, 青柳 健大, 宇佐美 徳隆, 舟窪 浩, 今野 豊彦
    • Organizer
      第123回金属材料研究所講演会
    • Place of Presentation
      仙台
    • Related Report
      2012 Research-status Report
  • [Presentation] ポストアニール温度がPMN薄膜の化学的秩序領域に及ぼす影響2012

    • Author(s)
      三坂好央、木口賢紀、佐藤和久、西松毅、宇佐美徳隆、今野豊彦、山田智明
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋
    • Related Report
      2012 Research-status Report
  • [Presentation] MOD 法により成膜したPb(Mg1/3Nb2/3)O3 薄膜のナノ構造のTEM 観察2012

    • Author(s)
      三坂好央、木口賢紀、佐藤和久、西松毅、山田智明、宇佐美徳隆、今野豊彦
    • Organizer
      第32回エレクトロセラミックス研究討論会
    • Place of Presentation
      東京
    • Related Report
      2012 Research-status Report
  • [Presentation] Direct Observation of Atomic Arrangement around 90˚ Domain Wall in Lead Titanate Thin Film2012

    • Author(s)
      T. Kiguchi, T.J. Konno, Y. Ehara, T. Yamada, H. Funakubo
    • Organizer
      Materials Research Society 2012 Fall Meeting
    • Place of Presentation
      米国ボストン
    • Related Report
      2012 Research-status Report
  • [Presentation] Domain structures in ferroelectric thin films2012

    • Author(s)
      Takanori Kiguchi, Kenta Aoyagi and Toyohiko J. Konno
    • Organizer
      ICC-IMR - ELyT workshop on materials science
    • Place of Presentation
      仙台
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] TEM analysis of the nanostructure of Pb(Mg1/3Nb2/3)O3 thin films by MOD method2012

    • Author(s)
      Y. Misaka, T. Kiguchi, K. Sato, T. Nishimatsu, T. Yamada, N. Usami, and T.J. Konno
    • Organizer
      Summit of Material Science (第124回金属材料研究所講演会)
    • Place of Presentation
      仙台
    • Related Report
      2012 Research-status Report
  • [Presentation] 高分解能電子顕微鏡の結像原理と強誘電体薄膜への応用2012

    • Author(s)
      木口賢紀
    • Organizer
      第237回応用セラミックス研究所講演会
    • Place of Presentation
      横浜
    • Related Report
      2012 Research-status Report
    • Invited
  • [Book] XAFS/EELSによる 局所構造解析 テクニック2014

    • Author(s)
      木口賢紀 他
    • Total Pages
      240
    • Publisher
      情報機構
    • Related Report
      2014 Annual Research Report
  • [Book] 注目の強誘電体材料(2) 強誘電体薄膜の合成とデバイス開発2014

    • Author(s)
      脇谷尚樹, 篠崎和夫, 木口賢紀,山田智明,水谷惟恭
    • Total Pages
      728
    • Publisher
      TIC
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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